Dynamic emission Stokes shift and liquid-like dielectric solvation of band edge carriers in lead-halide perovskites

Lead halide perovskites have unique electronic properties that depend on the crystal’s anharmonicity. Dielectric solvation theories, developed for molecules dissolved in polar liquids, are shown here to reproduce the temperature behavior of carrier solvation in the electronic spectra, implying stron...

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Bibliographic Details
Main Authors: Yinsheng Guo, Omer Yaffe, Trevor D. Hull, Jonathan S. Owen, David R. Reichman, Louis E. Brus
Format: article
Language:EN
Published: Nature Portfolio 2019
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Online Access:https://doaj.org/article/508b7e6e41074241bc6b82ceaa3d02bb
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