High-resolution tip-enhanced Raman scattering probes sub-molecular density changes

Despite recent advances in simulations of tip-enhanced Raman spectroscopy (TERS) under highly confined fields, a simply physical mechanism has remained elusive. Here, the authors show that single molecule TERS images can be explained by local sub-molecular density changes induced by the confined nea...

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Autores principales: Xing Chen, Pengchong Liu, Zhongwei Hu, Lasse Jensen
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/50cefb86bc9241d99f003504b2b74ac6
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Sumario:Despite recent advances in simulations of tip-enhanced Raman spectroscopy (TERS) under highly confined fields, a simply physical mechanism has remained elusive. Here, the authors show that single molecule TERS images can be explained by local sub-molecular density changes induced by the confined near-field during the Raman process.