Pd(II)-catalysed meta-C–H functionalizations of benzoic acid derivatives

While directed ortho-metalation is a well-established protocol, meta-functionalisation of aromatic groups is more challenging. Here, the authors report a directed meta-C-H functionalisation of benzoic acid derivatives, using a nitrile-based sulfonamide directing group.

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Autores principales:	Shangda Li, Lei Cai, Huafang Ji, Long Yang, Gang Li
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2016
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/5141b73389aa4bc68608e8dbb1e40d06
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spelling	oai:doaj.org-article:5141b73389aa4bc68608e8dbb1e40d062021-12-02T16:57:59ZPd(II)-catalysed meta-C–H functionalizations of benzoic acid derivatives10.1038/ncomms104432041-1723https://doaj.org/article/5141b73389aa4bc68608e8dbb1e40d062016-01-01T00:00:00Zhttps://doi.org/10.1038/ncomms10443https://doaj.org/toc/2041-1723While directed ortho-metalation is a well-established protocol, meta-functionalisation of aromatic groups is more challenging. Here, the authors report a directed meta-C-H functionalisation of benzoic acid derivatives, using a nitrile-based sulfonamide directing group.Shangda LiLei CaiHuafang JiLong YangGang LiNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-8 (2016)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Shangda Li Lei Cai Huafang Ji Long Yang Gang Li Pd(II)-catalysed meta-C–H functionalizations of benzoic acid derivatives
description	While directed ortho-metalation is a well-established protocol, meta-functionalisation of aromatic groups is more challenging. Here, the authors report a directed meta-C-H functionalisation of benzoic acid derivatives, using a nitrile-based sulfonamide directing group.
format	article
author	Shangda Li Lei Cai Huafang Ji Long Yang Gang Li
author_facet	Shangda Li Lei Cai Huafang Ji Long Yang Gang Li
author_sort	Shangda Li
title	Pd(II)-catalysed meta-C–H functionalizations of benzoic acid derivatives
title_short	Pd(II)-catalysed meta-C–H functionalizations of benzoic acid derivatives
title_full	Pd(II)-catalysed meta-C–H functionalizations of benzoic acid derivatives
title_fullStr	Pd(II)-catalysed meta-C–H functionalizations of benzoic acid derivatives
title_full_unstemmed	Pd(II)-catalysed meta-C–H functionalizations of benzoic acid derivatives
title_sort	pd(ii)-catalysed meta-c–h functionalizations of benzoic acid derivatives
publisher	Nature Portfolio
publishDate	2016
url	https://doaj.org/article/5141b73389aa4bc68608e8dbb1e40d06
work_keys_str_mv	AT shangdali pdiicatalysedmetachfunctionalizationsofbenzoicacidderivatives AT leicai pdiicatalysedmetachfunctionalizationsofbenzoicacidderivatives AT huafangji pdiicatalysedmetachfunctionalizationsofbenzoicacidderivatives AT longyang pdiicatalysedmetachfunctionalizationsofbenzoicacidderivatives AT gangli pdiicatalysedmetachfunctionalizationsofbenzoicacidderivatives
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Pd(II)-catalysed meta-C–H functionalizations of benzoic acid derivatives

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