Synthesis of sustainable, lightweight and electrically conductive polymer brushes grafted multi-layer graphene oxide

This work reports the synthesis of poly (monomethyl itaconate) grafted multi-layer graphene oxide (PMMI-g-GO) by atom transfer radical polymerization using activators regenerated by electron transfer (ARGET-ATRP). PMMI-g-GO presents outstanding properties, such as a high electrical conductivity (5.0...

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Autores principales:	Héctor Aguilar-Bolados, Mehrdad Yazdani-Pedram, Eduardo Quinteros-Jara, Quimberly Cuenca-Bracamonte, Raúl Quijada, Javier Carretero-González, Francis Avilés, Miguel A. Lopez-Manchado, Raquel Verdejo
Formato:	article
Lenguaje:	EN
Publicado:	Elsevier 2021
Materias:	Polymer brushes Multi-layer graphene oxide Surface-initiated controlled radical polymerization ARGET-ATRP Sustainable resources Polymers and polymer manufacture TP1080-1185
Acceso en línea:	https://doaj.org/article/515ec333f66a4102896be766239e303c
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spelling	oai:doaj.org-article:515ec333f66a4102896be766239e303c2021-11-24T04:25:44ZSynthesis of sustainable, lightweight and electrically conductive polymer brushes grafted multi-layer graphene oxide0142-941810.1016/j.polymertesting.2020.106986https://doaj.org/article/515ec333f66a4102896be766239e303c2021-01-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S0142941820322157https://doaj.org/toc/0142-9418This work reports the synthesis of poly (monomethyl itaconate) grafted multi-layer graphene oxide (PMMI-g-GO) by atom transfer radical polymerization using activators regenerated by electron transfer (ARGET-ATRP). PMMI-g-GO presents outstanding properties, such as a high electrical conductivity (5.04 S m-1), low number of stacked graphene layers (6) and IG/I2D ratio of 2.05 estimated from Raman spectrum, which indicates the high quality of PMMI-g-GO as a graphenic material. In addition, polymer brushes based on PMMI represent a new green alternative for the development of polymer composite materials, since the monomer used for their production is obtained from a renewable source. Interestingly, the PMMI-g-GO nanomaterial is also capable of storing Li+ ions without the need of using electron conductive additives that are usually employed in the electrode's composition of conventional lithium ion batteries.Héctor Aguilar-BoladosMehrdad Yazdani-PedramEduardo Quinteros-JaraQuimberly Cuenca-BracamonteRaúl QuijadaJavier Carretero-GonzálezFrancis AvilésMiguel A. Lopez-ManchadoRaquel VerdejoElsevierarticlePolymer brushesMulti-layer graphene oxideSurface-initiated controlled radical polymerizationARGET-ATRPSustainable resourcesPolymers and polymer manufactureTP1080-1185ENPolymer Testing, Vol 93, Iss , Pp 106986- (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Polymer brushes Multi-layer graphene oxide Surface-initiated controlled radical polymerization ARGET-ATRP Sustainable resources Polymers and polymer manufacture TP1080-1185
spellingShingle	Polymer brushes Multi-layer graphene oxide Surface-initiated controlled radical polymerization ARGET-ATRP Sustainable resources Polymers and polymer manufacture TP1080-1185 Héctor Aguilar-Bolados Mehrdad Yazdani-Pedram Eduardo Quinteros-Jara Quimberly Cuenca-Bracamonte Raúl Quijada Javier Carretero-González Francis Avilés Miguel A. Lopez-Manchado Raquel Verdejo Synthesis of sustainable, lightweight and electrically conductive polymer brushes grafted multi-layer graphene oxide
description	This work reports the synthesis of poly (monomethyl itaconate) grafted multi-layer graphene oxide (PMMI-g-GO) by atom transfer radical polymerization using activators regenerated by electron transfer (ARGET-ATRP). PMMI-g-GO presents outstanding properties, such as a high electrical conductivity (5.04 S m-1), low number of stacked graphene layers (6) and IG/I2D ratio of 2.05 estimated from Raman spectrum, which indicates the high quality of PMMI-g-GO as a graphenic material. In addition, polymer brushes based on PMMI represent a new green alternative for the development of polymer composite materials, since the monomer used for their production is obtained from a renewable source. Interestingly, the PMMI-g-GO nanomaterial is also capable of storing Li+ ions without the need of using electron conductive additives that are usually employed in the electrode's composition of conventional lithium ion batteries.
format	article
author	Héctor Aguilar-Bolados Mehrdad Yazdani-Pedram Eduardo Quinteros-Jara Quimberly Cuenca-Bracamonte Raúl Quijada Javier Carretero-González Francis Avilés Miguel A. Lopez-Manchado Raquel Verdejo
author_facet	Héctor Aguilar-Bolados Mehrdad Yazdani-Pedram Eduardo Quinteros-Jara Quimberly Cuenca-Bracamonte Raúl Quijada Javier Carretero-González Francis Avilés Miguel A. Lopez-Manchado Raquel Verdejo
author_sort	Héctor Aguilar-Bolados
title	Synthesis of sustainable, lightweight and electrically conductive polymer brushes grafted multi-layer graphene oxide
title_short	Synthesis of sustainable, lightweight and electrically conductive polymer brushes grafted multi-layer graphene oxide
title_full	Synthesis of sustainable, lightweight and electrically conductive polymer brushes grafted multi-layer graphene oxide
title_fullStr	Synthesis of sustainable, lightweight and electrically conductive polymer brushes grafted multi-layer graphene oxide
title_full_unstemmed	Synthesis of sustainable, lightweight and electrically conductive polymer brushes grafted multi-layer graphene oxide
title_sort	synthesis of sustainable, lightweight and electrically conductive polymer brushes grafted multi-layer graphene oxide
publisher	Elsevier
publishDate	2021
url	https://doaj.org/article/515ec333f66a4102896be766239e303c
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_version_	1718415974521110528

Synthesis of sustainable, lightweight and electrically conductive polymer brushes grafted multi-layer graphene oxide

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