Ni-catalyzed hydroalkylation of olefins with N-sulfonyl amines

Catalytic addition of a carbon chain and a hydrogen across a double bond has often required an added hydride source. Here the authors show a method to add alkanes with an amino functionality to olefins, wherein a nickel catalyst uses the amine itself as the hydride source, obviating an external hydr...

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Autores principales: Xiao-Biao Yan, Lun Li, Wen-Qiang Wu, Lun Xu, Ke Li, Yu-Cheng Liu, Hang Shi
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/51d394b287604eddae30b3c6dc1821d2
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Sumario:Catalytic addition of a carbon chain and a hydrogen across a double bond has often required an added hydride source. Here the authors show a method to add alkanes with an amino functionality to olefins, wherein a nickel catalyst uses the amine itself as the hydride source, obviating an external hydride reagent.