Ni-catalyzed hydroalkylation of olefins with N-sulfonyl amines

Catalytic addition of a carbon chain and a hydrogen across a double bond has often required an added hydride source. Here the authors show a method to add alkanes with an amino functionality to olefins, wherein a nickel catalyst uses the amine itself as the hydride source, obviating an external hydr...

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Autores principales:	Xiao-Biao Yan, Lun Li, Wen-Qiang Wu, Lun Xu, Ke Li, Yu-Cheng Liu, Hang Shi
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/51d394b287604eddae30b3c6dc1821d2
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spelling	oai:doaj.org-article:51d394b287604eddae30b3c6dc1821d22021-12-02T18:07:53ZNi-catalyzed hydroalkylation of olefins with N-sulfonyl amines10.1038/s41467-021-26194-y2041-1723https://doaj.org/article/51d394b287604eddae30b3c6dc1821d22021-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-26194-yhttps://doaj.org/toc/2041-1723Catalytic addition of a carbon chain and a hydrogen across a double bond has often required an added hydride source. Here the authors show a method to add alkanes with an amino functionality to olefins, wherein a nickel catalyst uses the amine itself as the hydride source, obviating an external hydride reagent.Xiao-Biao YanLun LiWen-Qiang WuLun XuKe LiYu-Cheng LiuHang ShiNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-10 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Xiao-Biao Yan Lun Li Wen-Qiang Wu Lun Xu Ke Li Yu-Cheng Liu Hang Shi Ni-catalyzed hydroalkylation of olefins with N-sulfonyl amines
description	Catalytic addition of a carbon chain and a hydrogen across a double bond has often required an added hydride source. Here the authors show a method to add alkanes with an amino functionality to olefins, wherein a nickel catalyst uses the amine itself as the hydride source, obviating an external hydride reagent.
format	article
author	Xiao-Biao Yan Lun Li Wen-Qiang Wu Lun Xu Ke Li Yu-Cheng Liu Hang Shi
author_facet	Xiao-Biao Yan Lun Li Wen-Qiang Wu Lun Xu Ke Li Yu-Cheng Liu Hang Shi
author_sort	Xiao-Biao Yan
title	Ni-catalyzed hydroalkylation of olefins with N-sulfonyl amines
title_short	Ni-catalyzed hydroalkylation of olefins with N-sulfonyl amines
title_full	Ni-catalyzed hydroalkylation of olefins with N-sulfonyl amines
title_fullStr	Ni-catalyzed hydroalkylation of olefins with N-sulfonyl amines
title_full_unstemmed	Ni-catalyzed hydroalkylation of olefins with N-sulfonyl amines
title_sort	ni-catalyzed hydroalkylation of olefins with n-sulfonyl amines
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/51d394b287604eddae30b3c6dc1821d2
work_keys_str_mv	AT xiaobiaoyan nicatalyzedhydroalkylationofolefinswithnsulfonylamines AT lunli nicatalyzedhydroalkylationofolefinswithnsulfonylamines AT wenqiangwu nicatalyzedhydroalkylationofolefinswithnsulfonylamines AT lunxu nicatalyzedhydroalkylationofolefinswithnsulfonylamines AT keli nicatalyzedhydroalkylationofolefinswithnsulfonylamines AT yuchengliu nicatalyzedhydroalkylationofolefinswithnsulfonylamines AT hangshi nicatalyzedhydroalkylationofolefinswithnsulfonylamines
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Ni-catalyzed hydroalkylation of olefins with N-sulfonyl amines

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