Hydrogen migration at restructuring palladium–silver oxide boundaries dramatically enhances reduction rate of silver oxide

Species migration across interfacial boundaries can affect the function of bimetallic catalysts. Here the authors report that palladium oxide drives the reduction of silver oxide by facilitating molecular hydrogen dissociation and migration of hydrogen atoms across the Pd–Ag interface with concurren...

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Autores principales:	Christopher R. O’Connor, Matthijs A. van Spronsen, Tobias Egle, Fang Xu, Heath R. Kersell, Judit Oliver-Meseguer, Mustafa Karatok, Miquel Salmeron, Robert J. Madix, Cynthia M. Friend
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/51db823067134c55acd4f2d43863002c
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spelling	oai:doaj.org-article:51db823067134c55acd4f2d43863002c2021-12-02T17:32:57ZHydrogen migration at restructuring palladium–silver oxide boundaries dramatically enhances reduction rate of silver oxide10.1038/s41467-020-15536-x2041-1723https://doaj.org/article/51db823067134c55acd4f2d43863002c2020-04-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-15536-xhttps://doaj.org/toc/2041-1723Species migration across interfacial boundaries can affect the function of bimetallic catalysts. Here the authors report that palladium oxide drives the reduction of silver oxide by facilitating molecular hydrogen dissociation and migration of hydrogen atoms across the Pd–Ag interface with concurrent surface restructuring.Christopher R. O’ConnorMatthijs A. van SpronsenTobias EgleFang XuHeath R. KersellJudit Oliver-MeseguerMustafa KaratokMiquel SalmeronRobert J. MadixCynthia M. FriendNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-6 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Christopher R. O’Connor Matthijs A. van Spronsen Tobias Egle Fang Xu Heath R. Kersell Judit Oliver-Meseguer Mustafa Karatok Miquel Salmeron Robert J. Madix Cynthia M. Friend Hydrogen migration at restructuring palladium–silver oxide boundaries dramatically enhances reduction rate of silver oxide
description	Species migration across interfacial boundaries can affect the function of bimetallic catalysts. Here the authors report that palladium oxide drives the reduction of silver oxide by facilitating molecular hydrogen dissociation and migration of hydrogen atoms across the Pd–Ag interface with concurrent surface restructuring.
format	article
author	Christopher R. O’Connor Matthijs A. van Spronsen Tobias Egle Fang Xu Heath R. Kersell Judit Oliver-Meseguer Mustafa Karatok Miquel Salmeron Robert J. Madix Cynthia M. Friend
author_facet	Christopher R. O’Connor Matthijs A. van Spronsen Tobias Egle Fang Xu Heath R. Kersell Judit Oliver-Meseguer Mustafa Karatok Miquel Salmeron Robert J. Madix Cynthia M. Friend
author_sort	Christopher R. O’Connor
title	Hydrogen migration at restructuring palladium–silver oxide boundaries dramatically enhances reduction rate of silver oxide
title_short	Hydrogen migration at restructuring palladium–silver oxide boundaries dramatically enhances reduction rate of silver oxide
title_full	Hydrogen migration at restructuring palladium–silver oxide boundaries dramatically enhances reduction rate of silver oxide
title_fullStr	Hydrogen migration at restructuring palladium–silver oxide boundaries dramatically enhances reduction rate of silver oxide
title_full_unstemmed	Hydrogen migration at restructuring palladium–silver oxide boundaries dramatically enhances reduction rate of silver oxide
title_sort	hydrogen migration at restructuring palladium–silver oxide boundaries dramatically enhances reduction rate of silver oxide
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/51db823067134c55acd4f2d43863002c
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Hydrogen migration at restructuring palladium–silver oxide boundaries dramatically enhances reduction rate of silver oxide

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