Temperature dependence of adsorption hysteresis in flexible metal organic frameworks

Flexible metal–organic frameworks that undergo structural transformations upon gas sorption show great promise for applications in gas storage and separation, but accurately describing their stepped isotherms and hysteresis remains a challenge. Here, the authors introduce an empirical model to descr...

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Autores principales:	Shamsur Rahman, Arash Arami-Niya, Xiaoxian Yang, Gongkui Xiao, Gang (Kevin) Li, Eric F. May
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/520c138026c74ba0bd49301bcc7ff8e3
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spelling	oai:doaj.org-article:520c138026c74ba0bd49301bcc7ff8e32021-12-02T11:43:48ZTemperature dependence of adsorption hysteresis in flexible metal organic frameworks10.1038/s42004-020-00429-32399-3669https://doaj.org/article/520c138026c74ba0bd49301bcc7ff8e32020-12-01T00:00:00Zhttps://doi.org/10.1038/s42004-020-00429-3https://doaj.org/toc/2399-3669Flexible metal–organic frameworks that undergo structural transformations upon gas sorption show great promise for applications in gas storage and separation, but accurately describing their stepped isotherms and hysteresis remains a challenge. Here, the authors introduce an empirical model to describe hysteretic MOF sorption isotherms and determine their temperature dependence, which is asymptotic at low temperatures.Shamsur RahmanArash Arami-NiyaXiaoxian YangGongkui XiaoGang (Kevin) LiEric F. MayNature PortfolioarticleChemistryQD1-999ENCommunications Chemistry, Vol 3, Iss 1, Pp 1-6 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Chemistry QD1-999
spellingShingle	Chemistry QD1-999 Shamsur Rahman Arash Arami-Niya Xiaoxian Yang Gongkui Xiao Gang (Kevin) Li Eric F. May Temperature dependence of adsorption hysteresis in flexible metal organic frameworks
description	Flexible metal–organic frameworks that undergo structural transformations upon gas sorption show great promise for applications in gas storage and separation, but accurately describing their stepped isotherms and hysteresis remains a challenge. Here, the authors introduce an empirical model to describe hysteretic MOF sorption isotherms and determine their temperature dependence, which is asymptotic at low temperatures.
format	article
author	Shamsur Rahman Arash Arami-Niya Xiaoxian Yang Gongkui Xiao Gang (Kevin) Li Eric F. May
author_facet	Shamsur Rahman Arash Arami-Niya Xiaoxian Yang Gongkui Xiao Gang (Kevin) Li Eric F. May
author_sort	Shamsur Rahman
title	Temperature dependence of adsorption hysteresis in flexible metal organic frameworks
title_short	Temperature dependence of adsorption hysteresis in flexible metal organic frameworks
title_full	Temperature dependence of adsorption hysteresis in flexible metal organic frameworks
title_fullStr	Temperature dependence of adsorption hysteresis in flexible metal organic frameworks
title_full_unstemmed	Temperature dependence of adsorption hysteresis in flexible metal organic frameworks
title_sort	temperature dependence of adsorption hysteresis in flexible metal organic frameworks
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/520c138026c74ba0bd49301bcc7ff8e3
work_keys_str_mv	AT shamsurrahman temperaturedependenceofadsorptionhysteresisinflexiblemetalorganicframeworks AT arasharaminiya temperaturedependenceofadsorptionhysteresisinflexiblemetalorganicframeworks AT xiaoxianyang temperaturedependenceofadsorptionhysteresisinflexiblemetalorganicframeworks AT gongkuixiao temperaturedependenceofadsorptionhysteresisinflexiblemetalorganicframeworks AT gangkevinli temperaturedependenceofadsorptionhysteresisinflexiblemetalorganicframeworks AT ericfmay temperaturedependenceofadsorptionhysteresisinflexiblemetalorganicframeworks
_version_	1718395340913115136

Temperature dependence of adsorption hysteresis in flexible metal organic frameworks

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