Nucleophilic arylation with tetraarylphosphonium salts

Carbon based nucleophiles often are synthetically limited by the high basicity/reactivity of the starting materials. Here, the authors show that tetraarylphosphonium salts can be induced to act as C-aryl nucleophiles for the addition to carbonyls and imines.

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Autores principales:	Zuyong Deng, Jin-Hong Lin, Ji-Chang Xiao
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2016
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/522ce9be7ee44a2eab0f0182ecda83ba
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spelling	oai:doaj.org-article:522ce9be7ee44a2eab0f0182ecda83ba2021-12-02T14:39:54ZNucleophilic arylation with tetraarylphosphonium salts10.1038/ncomms103372041-1723https://doaj.org/article/522ce9be7ee44a2eab0f0182ecda83ba2016-01-01T00:00:00Zhttps://doi.org/10.1038/ncomms10337https://doaj.org/toc/2041-1723Carbon based nucleophiles often are synthetically limited by the high basicity/reactivity of the starting materials. Here, the authors show that tetraarylphosphonium salts can be induced to act as C-aryl nucleophiles for the addition to carbonyls and imines.Zuyong DengJin-Hong LinJi-Chang XiaoNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-8 (2016)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Zuyong Deng Jin-Hong Lin Ji-Chang Xiao Nucleophilic arylation with tetraarylphosphonium salts
description	Carbon based nucleophiles often are synthetically limited by the high basicity/reactivity of the starting materials. Here, the authors show that tetraarylphosphonium salts can be induced to act as C-aryl nucleophiles for the addition to carbonyls and imines.
format	article
author	Zuyong Deng Jin-Hong Lin Ji-Chang Xiao
author_facet	Zuyong Deng Jin-Hong Lin Ji-Chang Xiao
author_sort	Zuyong Deng
title	Nucleophilic arylation with tetraarylphosphonium salts
title_short	Nucleophilic arylation with tetraarylphosphonium salts
title_full	Nucleophilic arylation with tetraarylphosphonium salts
title_fullStr	Nucleophilic arylation with tetraarylphosphonium salts
title_full_unstemmed	Nucleophilic arylation with tetraarylphosphonium salts
title_sort	nucleophilic arylation with tetraarylphosphonium salts
publisher	Nature Portfolio
publishDate	2016
url	https://doaj.org/article/522ce9be7ee44a2eab0f0182ecda83ba
work_keys_str_mv	AT zuyongdeng nucleophilicarylationwithtetraarylphosphoniumsalts AT jinhonglin nucleophilicarylationwithtetraarylphosphoniumsalts AT jichangxiao nucleophilicarylationwithtetraarylphosphoniumsalts
_version_	1718390471850459136

Nucleophilic arylation with tetraarylphosphonium salts

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