Nucleophilic arylation with tetraarylphosphonium salts

Carbon based nucleophiles often are synthetically limited by the high basicity/reactivity of the starting materials. Here, the authors show that tetraarylphosphonium salts can be induced to act as C-aryl nucleophiles for the addition to carbonyls and imines.

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Autores principales: Zuyong Deng, Jin-Hong Lin, Ji-Chang Xiao
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2016
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Acceso en línea:https://doaj.org/article/522ce9be7ee44a2eab0f0182ecda83ba
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