Reductive dearomative arylcarboxylation of indoles with CO2 via visible-light photoredox catalysis

Catalytic reductive coupling of two electrophiles and one C = C bond is usually performed by two electron transfer metal catalysis. Herein, the authors show a visible light photoredox-catalyzed successive single electron transfer leading to dearomative arylcarboxylation of indoles with CO2 and gener...

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Autores principales: Wen-Jun Zhou, Zhe-Hao Wang, Li-Li Liao, Yuan-Xu Jiang, Ke-Gong Cao, Tao Ju, Yiwen Li, Guang-Mei Cao, Da-Gang Yu
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Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/526c62d20baf485497257679efc84290
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spelling oai:doaj.org-article:526c62d20baf485497257679efc842902021-12-02T16:10:47ZReductive dearomative arylcarboxylation of indoles with CO2 via visible-light photoredox catalysis10.1038/s41467-020-17085-92041-1723https://doaj.org/article/526c62d20baf485497257679efc842902020-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-17085-9https://doaj.org/toc/2041-1723Catalytic reductive coupling of two electrophiles and one C = C bond is usually performed by two electron transfer metal catalysis. Herein, the authors show a visible light photoredox-catalyzed successive single electron transfer leading to dearomative arylcarboxylation of indoles with CO2 and generating indoline-3-carboxylic acids.Wen-Jun ZhouZhe-Hao WangLi-Li LiaoYuan-Xu JiangKe-Gong CaoTao JuYiwen LiGuang-Mei CaoDa-Gang YuNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-9 (2020)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Wen-Jun Zhou
Zhe-Hao Wang
Li-Li Liao
Yuan-Xu Jiang
Ke-Gong Cao
Tao Ju
Yiwen Li
Guang-Mei Cao
Da-Gang Yu
Reductive dearomative arylcarboxylation of indoles with CO2 via visible-light photoredox catalysis
description Catalytic reductive coupling of two electrophiles and one C = C bond is usually performed by two electron transfer metal catalysis. Herein, the authors show a visible light photoredox-catalyzed successive single electron transfer leading to dearomative arylcarboxylation of indoles with CO2 and generating indoline-3-carboxylic acids.
format article
author Wen-Jun Zhou
Zhe-Hao Wang
Li-Li Liao
Yuan-Xu Jiang
Ke-Gong Cao
Tao Ju
Yiwen Li
Guang-Mei Cao
Da-Gang Yu
author_facet Wen-Jun Zhou
Zhe-Hao Wang
Li-Li Liao
Yuan-Xu Jiang
Ke-Gong Cao
Tao Ju
Yiwen Li
Guang-Mei Cao
Da-Gang Yu
author_sort Wen-Jun Zhou
title Reductive dearomative arylcarboxylation of indoles with CO2 via visible-light photoredox catalysis
title_short Reductive dearomative arylcarboxylation of indoles with CO2 via visible-light photoredox catalysis
title_full Reductive dearomative arylcarboxylation of indoles with CO2 via visible-light photoredox catalysis
title_fullStr Reductive dearomative arylcarboxylation of indoles with CO2 via visible-light photoredox catalysis
title_full_unstemmed Reductive dearomative arylcarboxylation of indoles with CO2 via visible-light photoredox catalysis
title_sort reductive dearomative arylcarboxylation of indoles with co2 via visible-light photoredox catalysis
publisher Nature Portfolio
publishDate 2020
url https://doaj.org/article/526c62d20baf485497257679efc84290
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