Characterisation of oxygen defects and nitrogen impurities in TiO2 photocatalysts using variable-temperature X-ray powder diffraction

Nitrogen-doped TiO2 exhibits improved photocatalytic water-splitting activity partially due to enhanced oxygen vacancy formation. Here, authors demonstrate the temperature-dependent lattice distortion of oxygen vacancies, and identify the presence of a titanium oxynitride phase in high activity cata...

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Autores principales: Christopher Foo, Yiyang Li, Konstantin Lebedev, Tianyi Chen, Sarah Day, Chiu Tang, Shik Chi Edman Tsang
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/527739ff8fca458ca93cd7ef26fd4b64
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Sumario:Nitrogen-doped TiO2 exhibits improved photocatalytic water-splitting activity partially due to enhanced oxygen vacancy formation. Here, authors demonstrate the temperature-dependent lattice distortion of oxygen vacancies, and identify the presence of a titanium oxynitride phase in high activity catalysts.