Asymmetric azide-alkyne Huisgen cycloaddition on chiral metal surfaces

Mechanistic insight into enantioselective reactions at intrinsically chiral surfaces can be challenging to obtain. Here the catalytic activity of Pd1- and Pd3-terminated PdGa{111} surfaces is shown to differ substantially, with Pd1-terminated surfaces promoting on-surface azide– alkyne cycloaddition...

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Autores principales:	Samuel Stolz, Michael Bauer, Carlo A. Pignedoli, Nils Krane, Max Bommert, Elia Turco, Nicolò Bassi, Amogh Kinikar, Néstor Merino-Dìez, Roland Hany, Harald Brune, Oliver Gröning, Roland Widmer
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/528a3db4d8fe4b848d49880a7de0818f
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spelling	oai:doaj.org-article:528a3db4d8fe4b848d49880a7de0818f2021-12-02T18:03:25ZAsymmetric azide-alkyne Huisgen cycloaddition on chiral metal surfaces10.1038/s42004-021-00488-02399-3669https://doaj.org/article/528a3db4d8fe4b848d49880a7de0818f2021-04-01T00:00:00Zhttps://doi.org/10.1038/s42004-021-00488-0https://doaj.org/toc/2399-3669Mechanistic insight into enantioselective reactions at intrinsically chiral surfaces can be challenging to obtain. Here the catalytic activity of Pd1- and Pd3-terminated PdGa{111} surfaces is shown to differ substantially, with Pd1-terminated surfaces promoting on-surface azide– alkyne cycloadditions enantioand regioselectively.Samuel StolzMichael BauerCarlo A. PignedoliNils KraneMax BommertElia TurcoNicolò BassiAmogh KinikarNéstor Merino-DìezRoland HanyHarald BruneOliver GröningRoland WidmerNature PortfolioarticleChemistryQD1-999ENCommunications Chemistry, Vol 4, Iss 1, Pp 1-7 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Chemistry QD1-999
spellingShingle	Chemistry QD1-999 Samuel Stolz Michael Bauer Carlo A. Pignedoli Nils Krane Max Bommert Elia Turco Nicolò Bassi Amogh Kinikar Néstor Merino-Dìez Roland Hany Harald Brune Oliver Gröning Roland Widmer Asymmetric azide-alkyne Huisgen cycloaddition on chiral metal surfaces
description	Mechanistic insight into enantioselective reactions at intrinsically chiral surfaces can be challenging to obtain. Here the catalytic activity of Pd1- and Pd3-terminated PdGa{111} surfaces is shown to differ substantially, with Pd1-terminated surfaces promoting on-surface azide– alkyne cycloadditions enantioand regioselectively.
format	article
author	Samuel Stolz Michael Bauer Carlo A. Pignedoli Nils Krane Max Bommert Elia Turco Nicolò Bassi Amogh Kinikar Néstor Merino-Dìez Roland Hany Harald Brune Oliver Gröning Roland Widmer
author_facet	Samuel Stolz Michael Bauer Carlo A. Pignedoli Nils Krane Max Bommert Elia Turco Nicolò Bassi Amogh Kinikar Néstor Merino-Dìez Roland Hany Harald Brune Oliver Gröning Roland Widmer
author_sort	Samuel Stolz
title	Asymmetric azide-alkyne Huisgen cycloaddition on chiral metal surfaces
title_short	Asymmetric azide-alkyne Huisgen cycloaddition on chiral metal surfaces
title_full	Asymmetric azide-alkyne Huisgen cycloaddition on chiral metal surfaces
title_fullStr	Asymmetric azide-alkyne Huisgen cycloaddition on chiral metal surfaces
title_full_unstemmed	Asymmetric azide-alkyne Huisgen cycloaddition on chiral metal surfaces
title_sort	asymmetric azide-alkyne huisgen cycloaddition on chiral metal surfaces
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/528a3db4d8fe4b848d49880a7de0818f
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Asymmetric azide-alkyne Huisgen cycloaddition on chiral metal surfaces

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