CRYSTAL STRUCTURE OF TRIPHENYLTIN (IV) FORMATE POLYMER, (HCO2SnPh3)n

The title polymer [HCO2Sn(C6H5)3]n was isolated by serendipitous from reaction in ethanol 96 % between bis-(monocyclohexyl ammonium) 2-carboxyethyl hydrogen phosphonate, {(CyNH3)2[CO2CH2CH2PO2(OH)]} and triphenyltin chloride, SnPh3Cl. The polymer crystallizes in the monoclinic space group P21/n wit...

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Autores principales:	MODOU SARR, MOUHAMADOU BIRAME DIOP, AMINATA DIASSE-SARR, AI WANG, ULLRICH ENGLERT
Formato:	article
Lenguaje:	EN
Publicado:	Alma Mater Publishing House "Vasile Alecsandri" University of Bacau 2020
Materias:	infinite chain, trans-trigonal bipyramidal, bidentate formate anions, triphenyltin Technology T Engineering (General). Civil engineering (General) TA1-2040
Acceso en línea:	https://doaj.org/article/531892bf39c34c6e90a3d01681631f79
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spelling	oai:doaj.org-article:531892bf39c34c6e90a3d01681631f792021-12-02T18:36:09ZCRYSTAL STRUCTURE OF TRIPHENYLTIN (IV) FORMATE POLYMER, (HCO2SnPh3)n10.29081/jesr.v26i3.2262068-75592344-4932https://doaj.org/article/531892bf39c34c6e90a3d01681631f792020-07-01T00:00:00Zhttp://www.jesr.ub.ro/1/article/view/226https://doaj.org/toc/2068-7559https://doaj.org/toc/2344-4932 The title polymer [HCO2Sn(C6H5)3]n was isolated by serendipitous from reaction in ethanol 96 % between bis-(monocyclohexyl ammonium) 2-carboxyethyl hydrogen phosphonate, {(CyNH3)2[CO2CH2CH2PO2(OH)]} and triphenyltin chloride, SnPh3Cl. The polymer crystallizes in the monoclinic space group P21/n with Z = 4, a = 14.7091 (18) Å, b = 15.4133 (19) Å, c = 14.7639 (18) Å, β = 94.242 (2)° and V = 3338.0 (7) Å3. The structure consists of an infinite chain propagating along the crystallographic a-axis direction with bidentate formate anions. The O2SnC3 core is organized into a trans-trigonal bipyramidal like-arrangement. MODOU SARRMOUHAMADOU BIRAME DIOPAMINATA DIASSE-SARRAI WANGULLRICH ENGLERTAlma Mater Publishing House "Vasile Alecsandri" University of Bacauarticleinfinite chain, trans-trigonal bipyramidal, bidentate formate anions, triphenyltinTechnologyTEngineering (General). Civil engineering (General)TA1-2040ENJournal of Engineering Studies and Research, Vol 26, Iss 3 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	infinite chain, trans-trigonal bipyramidal, bidentate formate anions, triphenyltin Technology T Engineering (General). Civil engineering (General) TA1-2040
spellingShingle	infinite chain, trans-trigonal bipyramidal, bidentate formate anions, triphenyltin Technology T Engineering (General). Civil engineering (General) TA1-2040 MODOU SARR MOUHAMADOU BIRAME DIOP AMINATA DIASSE-SARR AI WANG ULLRICH ENGLERT CRYSTAL STRUCTURE OF TRIPHENYLTIN (IV) FORMATE POLYMER, (HCO2SnPh3)n
description	The title polymer [HCO2Sn(C6H5)3]n was isolated by serendipitous from reaction in ethanol 96 % between bis-(monocyclohexyl ammonium) 2-carboxyethyl hydrogen phosphonate, {(CyNH3)2[CO2CH2CH2PO2(OH)]} and triphenyltin chloride, SnPh3Cl. The polymer crystallizes in the monoclinic space group P21/n with Z = 4, a = 14.7091 (18) Å, b = 15.4133 (19) Å, c = 14.7639 (18) Å, β = 94.242 (2)° and V = 3338.0 (7) Å3. The structure consists of an infinite chain propagating along the crystallographic a-axis direction with bidentate formate anions. The O2SnC3 core is organized into a trans-trigonal bipyramidal like-arrangement.
format	article
author	MODOU SARR MOUHAMADOU BIRAME DIOP AMINATA DIASSE-SARR AI WANG ULLRICH ENGLERT
author_facet	MODOU SARR MOUHAMADOU BIRAME DIOP AMINATA DIASSE-SARR AI WANG ULLRICH ENGLERT
author_sort	MODOU SARR
title	CRYSTAL STRUCTURE OF TRIPHENYLTIN (IV) FORMATE POLYMER, (HCO2SnPh3)n
title_short	CRYSTAL STRUCTURE OF TRIPHENYLTIN (IV) FORMATE POLYMER, (HCO2SnPh3)n
title_full	CRYSTAL STRUCTURE OF TRIPHENYLTIN (IV) FORMATE POLYMER, (HCO2SnPh3)n
title_fullStr	CRYSTAL STRUCTURE OF TRIPHENYLTIN (IV) FORMATE POLYMER, (HCO2SnPh3)n
title_full_unstemmed	CRYSTAL STRUCTURE OF TRIPHENYLTIN (IV) FORMATE POLYMER, (HCO2SnPh3)n
title_sort	crystal structure of triphenyltin (iv) formate polymer, (hco2snph3)n
publisher	Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
publishDate	2020
url	https://doaj.org/article/531892bf39c34c6e90a3d01681631f79
work_keys_str_mv	AT modousarr crystalstructureoftriphenyltinivformatepolymerhco2snph3n AT mouhamadoubiramediop crystalstructureoftriphenyltinivformatepolymerhco2snph3n AT aminatadiassesarr crystalstructureoftriphenyltinivformatepolymerhco2snph3n AT aiwang crystalstructureoftriphenyltinivformatepolymerhco2snph3n AT ullrichenglert crystalstructureoftriphenyltinivformatepolymerhco2snph3n
_version_	1718377860017684480

CRYSTAL STRUCTURE OF TRIPHENYLTIN (IV) FORMATE POLYMER, (HCO2SnPh3)n

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