Synthesis and Characterization of some divalent transition metal complexes with acid hydrazone ligand

Complexes with the general formula [M(LH)2]X2 where M=Mn(II),Co(II),Ni(II) and Cu(II) LH= 4-acetylpyridine benzoyl hydrazone and X=chloride ion were synthesized. The structures were confirmed by IR spectroscopy, and characterized by elemental analyses, UV-vis, 1H.n.m.r 13C-n.m.r, and conducti...

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Autores principales:	Bayan Faiq, Bayan Omer Ahmad
Formato:	article
Lenguaje:	EN
Publicado:	Salahaddin University-Erbil 2021
Materias:	acid hydrazone; complexes; synthesis. Technology T Science Q
Acceso en línea:	https://doaj.org/article/535bcaf86aeb45e2a6daa92322d8dec6
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spelling	oai:doaj.org-article:535bcaf86aeb45e2a6daa92322d8dec62021-11-07T06:23:31ZSynthesis and Characterization of some divalent transition metal complexes with acid hydrazone ligand10.21271/ZJPAS.33.5.102218-02302412-3986https://doaj.org/article/535bcaf86aeb45e2a6daa92322d8dec62021-10-01T00:00:00Zhttps://zancojournals.su.edu.krd/index.php/JPAS/article/view/4032https://doaj.org/toc/2218-0230https://doaj.org/toc/2412-3986 Complexes with the general formula [M(LH)2]X2 where M=Mn(II),Co(II),Ni(II) and Cu(II) LH= 4-acetylpyridine benzoyl hydrazone and X=chloride ion were synthesized. The structures were confirmed by IR spectroscopy, and characterized by elemental analyses, UV-vis, 1H.n.m.r 13C-n.m.r, and conductivity measurements. Molar conductance values in DMSO indicate that all complexes are electrolytes with mole ratio (1:2) and chloride ions not participate in coordination to central metal ion except Mn complex. The ligand act as bidentate, they coordinates through azomethine nitrogen (>C=N-) and carbonyl oxygen׳s.Bayan FaiqBayan Omer AhmadSalahaddin University-Erbilarticleacid hydrazone; complexes; synthesis.TechnologyTScienceQENZanco Journal of Pure and Applied Sciences, Vol 33, Iss 5, Pp 85-94 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	acid hydrazone; complexes; synthesis. Technology T Science Q
spellingShingle	acid hydrazone; complexes; synthesis. Technology T Science Q Bayan Faiq Bayan Omer Ahmad Synthesis and Characterization of some divalent transition metal complexes with acid hydrazone ligand
description	Complexes with the general formula [M(LH)2]X2 where M=Mn(II),Co(II),Ni(II) and Cu(II) LH= 4-acetylpyridine benzoyl hydrazone and X=chloride ion were synthesized. The structures were confirmed by IR spectroscopy, and characterized by elemental analyses, UV-vis, 1H.n.m.r 13C-n.m.r, and conductivity measurements. Molar conductance values in DMSO indicate that all complexes are electrolytes with mole ratio (1:2) and chloride ions not participate in coordination to central metal ion except Mn complex. The ligand act as bidentate, they coordinates through azomethine nitrogen (>C=N-) and carbonyl oxygen׳s.
format	article
author	Bayan Faiq Bayan Omer Ahmad
author_facet	Bayan Faiq Bayan Omer Ahmad
author_sort	Bayan Faiq
title	Synthesis and Characterization of some divalent transition metal complexes with acid hydrazone ligand
title_short	Synthesis and Characterization of some divalent transition metal complexes with acid hydrazone ligand
title_full	Synthesis and Characterization of some divalent transition metal complexes with acid hydrazone ligand
title_fullStr	Synthesis and Characterization of some divalent transition metal complexes with acid hydrazone ligand
title_full_unstemmed	Synthesis and Characterization of some divalent transition metal complexes with acid hydrazone ligand
title_sort	synthesis and characterization of some divalent transition metal complexes with acid hydrazone ligand
publisher	Salahaddin University-Erbil
publishDate	2021
url	https://doaj.org/article/535bcaf86aeb45e2a6daa92322d8dec6
work_keys_str_mv	AT bayanfaiq synthesisandcharacterizationofsomedivalenttransitionmetalcomplexeswithacidhydrazoneligand AT bayanomerahmad synthesisandcharacterizationofsomedivalenttransitionmetalcomplexeswithacidhydrazoneligand
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Synthesis and Characterization of some divalent transition metal complexes with acid hydrazone ligand

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