Dual properties of a hydrogen oxidation Ni-catalyst entrapped within a polymer promote self-defense against oxygen

Bio-inspired Ni-based molecular catalysts are efficient for H2 oxidation, but are suffering from the poor stability in the presence of O2. Here, the authors develop a strategy to boost greatly their stability by dispersing them in a hydrophobic and redox-silent polymer matrix.

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Autores principales:	Alaa A. Oughli, Adrian Ruff, Nilusha Priyadarshani Boralugodage, Patricia Rodríguez-Maciá, Nicolas Plumeré, Wolfgang Lubitz, Wendy J. Shaw, Wolfgang Schuhmann, Olaf Rüdiger
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/5427622b542942a88eba3165c11305a9
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spelling	oai:doaj.org-article:5427622b542942a88eba3165c11305a92021-12-02T16:56:56ZDual properties of a hydrogen oxidation Ni-catalyst entrapped within a polymer promote self-defense against oxygen10.1038/s41467-018-03011-72041-1723https://doaj.org/article/5427622b542942a88eba3165c11305a92018-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-03011-7https://doaj.org/toc/2041-1723Bio-inspired Ni-based molecular catalysts are efficient for H2 oxidation, but are suffering from the poor stability in the presence of O2. Here, the authors develop a strategy to boost greatly their stability by dispersing them in a hydrophobic and redox-silent polymer matrix.Alaa A. OughliAdrian RuffNilusha Priyadarshani BoralugodagePatricia Rodríguez-MaciáNicolas PlumeréWolfgang LubitzWendy J. ShawWolfgang SchuhmannOlaf RüdigerNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-6 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Alaa A. Oughli Adrian Ruff Nilusha Priyadarshani Boralugodage Patricia Rodríguez-Maciá Nicolas Plumeré Wolfgang Lubitz Wendy J. Shaw Wolfgang Schuhmann Olaf Rüdiger Dual properties of a hydrogen oxidation Ni-catalyst entrapped within a polymer promote self-defense against oxygen
description	Bio-inspired Ni-based molecular catalysts are efficient for H2 oxidation, but are suffering from the poor stability in the presence of O2. Here, the authors develop a strategy to boost greatly their stability by dispersing them in a hydrophobic and redox-silent polymer matrix.
format	article
author	Alaa A. Oughli Adrian Ruff Nilusha Priyadarshani Boralugodage Patricia Rodríguez-Maciá Nicolas Plumeré Wolfgang Lubitz Wendy J. Shaw Wolfgang Schuhmann Olaf Rüdiger
author_facet	Alaa A. Oughli Adrian Ruff Nilusha Priyadarshani Boralugodage Patricia Rodríguez-Maciá Nicolas Plumeré Wolfgang Lubitz Wendy J. Shaw Wolfgang Schuhmann Olaf Rüdiger
author_sort	Alaa A. Oughli
title	Dual properties of a hydrogen oxidation Ni-catalyst entrapped within a polymer promote self-defense against oxygen
title_short	Dual properties of a hydrogen oxidation Ni-catalyst entrapped within a polymer promote self-defense against oxygen
title_full	Dual properties of a hydrogen oxidation Ni-catalyst entrapped within a polymer promote self-defense against oxygen
title_fullStr	Dual properties of a hydrogen oxidation Ni-catalyst entrapped within a polymer promote self-defense against oxygen
title_full_unstemmed	Dual properties of a hydrogen oxidation Ni-catalyst entrapped within a polymer promote self-defense against oxygen
title_sort	dual properties of a hydrogen oxidation ni-catalyst entrapped within a polymer promote self-defense against oxygen
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/5427622b542942a88eba3165c11305a9
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Dual properties of a hydrogen oxidation Ni-catalyst entrapped within a polymer promote self-defense against oxygen

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