Mixed gel electrolytes: Synthesis, characterization, and gas release on PbSb electrode
Mixed gel electrolytes were fabricated chemically at a temperature range of 2–5°C using some additives comparing with traditional electrolytes (1.26 g/cm3 H2SO4). The polyacrylamide (PAM) content is kept constant (0.2 wt%), while the propylene glycol (PPG) and nano fumed silica (NFS) contents varied...
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De Gruyter
2021
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oai:doaj.org-article:544465f0b3be4d3bb0ba2d6094fccb8a2021-12-05T14:10:49ZMixed gel electrolytes: Synthesis, characterization, and gas release on PbSb electrode2191-955010.1515/gps-2021-0033https://doaj.org/article/544465f0b3be4d3bb0ba2d6094fccb8a2021-05-01T00:00:00Zhttps://doi.org/10.1515/gps-2021-0033https://doaj.org/toc/2191-9550Mixed gel electrolytes were fabricated chemically at a temperature range of 2–5°C using some additives comparing with traditional electrolytes (1.26 g/cm3 H2SO4). The polyacrylamide (PAM) content is kept constant (0.2 wt%), while the propylene glycol (PPG) and nano fumed silica (NFS) contents varied. The material characteristics of samples were assessed by physical appearance observation, electrochemical measurements, and physicochemical methods. The results showed that a hard gel without separation of solutions was found in the case using a PAM/PPG/NFS ternary additive (0.2/0.1/0.6 wt%). The morphological structure (<50 nm) of mixed gel electrolytes was in the range of nanometer. The gas release on the PbSb electrode was strongly inhibited (92.2–93.7% for O2 and ∼55% for H2 at the 120th cycle), which will both contributes to reducing the pressure as well as limiting water loss in the sealed lead acid battery, compared with that in the sulfuric acid medium.Thi Binh PhanThi Van Anh NguyenThi Thanh Thuy MaiThi Xuan MaiDuyen Nguyen TheThi Chuyen ViQuy Bui MinhDe Gruyterarticlemixed gel electrolyteadditivesionic conductivitydiffusion coefficientgas releaseChemistryQD1-999ENGreen Processing and Synthesis, Vol 10, Iss 1, Pp 325-335 (2021) |
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mixed gel electrolyte additives ionic conductivity diffusion coefficient gas release Chemistry QD1-999 |
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mixed gel electrolyte additives ionic conductivity diffusion coefficient gas release Chemistry QD1-999 Thi Binh Phan Thi Van Anh Nguyen Thi Thanh Thuy Mai Thi Xuan Mai Duyen Nguyen The Thi Chuyen Vi Quy Bui Minh Mixed gel electrolytes: Synthesis, characterization, and gas release on PbSb electrode |
description |
Mixed gel electrolytes were fabricated chemically at a temperature range of 2–5°C using some additives comparing with traditional electrolytes (1.26 g/cm3 H2SO4). The polyacrylamide (PAM) content is kept constant (0.2 wt%), while the propylene glycol (PPG) and nano fumed silica (NFS) contents varied. The material characteristics of samples were assessed by physical appearance observation, electrochemical measurements, and physicochemical methods. The results showed that a hard gel without separation of solutions was found in the case using a PAM/PPG/NFS ternary additive (0.2/0.1/0.6 wt%). The morphological structure (<50 nm) of mixed gel electrolytes was in the range of nanometer. The gas release on the PbSb electrode was strongly inhibited (92.2–93.7% for O2 and ∼55% for H2 at the 120th cycle), which will both contributes to reducing the pressure as well as limiting water loss in the sealed lead acid battery, compared with that in the sulfuric acid medium. |
format |
article |
author |
Thi Binh Phan Thi Van Anh Nguyen Thi Thanh Thuy Mai Thi Xuan Mai Duyen Nguyen The Thi Chuyen Vi Quy Bui Minh |
author_facet |
Thi Binh Phan Thi Van Anh Nguyen Thi Thanh Thuy Mai Thi Xuan Mai Duyen Nguyen The Thi Chuyen Vi Quy Bui Minh |
author_sort |
Thi Binh Phan |
title |
Mixed gel electrolytes: Synthesis, characterization, and gas release on PbSb electrode |
title_short |
Mixed gel electrolytes: Synthesis, characterization, and gas release on PbSb electrode |
title_full |
Mixed gel electrolytes: Synthesis, characterization, and gas release on PbSb electrode |
title_fullStr |
Mixed gel electrolytes: Synthesis, characterization, and gas release on PbSb electrode |
title_full_unstemmed |
Mixed gel electrolytes: Synthesis, characterization, and gas release on PbSb electrode |
title_sort |
mixed gel electrolytes: synthesis, characterization, and gas release on pbsb electrode |
publisher |
De Gruyter |
publishDate |
2021 |
url |
https://doaj.org/article/544465f0b3be4d3bb0ba2d6094fccb8a |
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