Mixed gel electrolytes: Synthesis, characterization, and gas release on PbSb electrode

Mixed gel electrolytes were fabricated chemically at a temperature range of 2–5°C using some additives comparing with traditional electrolytes (1.26 g/cm3 H2SO4). The polyacrylamide (PAM) content is kept constant (0.2 wt%), while the propylene glycol (PPG) and nano fumed silica (NFS) contents varied...

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Autores principales: Thi Binh Phan, Thi Van Anh Nguyen, Thi Thanh Thuy Mai, Thi Xuan Mai, Duyen Nguyen The, Thi Chuyen Vi, Quy Bui Minh
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Publicado: De Gruyter 2021
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Acceso en línea:https://doaj.org/article/544465f0b3be4d3bb0ba2d6094fccb8a
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spelling oai:doaj.org-article:544465f0b3be4d3bb0ba2d6094fccb8a2021-12-05T14:10:49ZMixed gel electrolytes: Synthesis, characterization, and gas release on PbSb electrode2191-955010.1515/gps-2021-0033https://doaj.org/article/544465f0b3be4d3bb0ba2d6094fccb8a2021-05-01T00:00:00Zhttps://doi.org/10.1515/gps-2021-0033https://doaj.org/toc/2191-9550Mixed gel electrolytes were fabricated chemically at a temperature range of 2–5°C using some additives comparing with traditional electrolytes (1.26 g/cm3 H2SO4). The polyacrylamide (PAM) content is kept constant (0.2 wt%), while the propylene glycol (PPG) and nano fumed silica (NFS) contents varied. The material characteristics of samples were assessed by physical appearance observation, electrochemical measurements, and physicochemical methods. The results showed that a hard gel without separation of solutions was found in the case using a PAM/PPG/NFS ternary additive (0.2/0.1/0.6 wt%). The morphological structure (<50 nm) of mixed gel electrolytes was in the range of nanometer. The gas release on the PbSb electrode was strongly inhibited (92.2–93.7% for O2 and ∼55% for H2 at the 120th cycle), which will both contributes to reducing the pressure as well as limiting water loss in the sealed lead acid battery, compared with that in the sulfuric acid medium.Thi Binh PhanThi Van Anh NguyenThi Thanh Thuy MaiThi Xuan MaiDuyen Nguyen TheThi Chuyen ViQuy Bui MinhDe Gruyterarticlemixed gel electrolyteadditivesionic conductivitydiffusion coefficientgas releaseChemistryQD1-999ENGreen Processing and Synthesis, Vol 10, Iss 1, Pp 325-335 (2021)
institution DOAJ
collection DOAJ
language EN
topic mixed gel electrolyte
additives
ionic conductivity
diffusion coefficient
gas release
Chemistry
QD1-999
spellingShingle mixed gel electrolyte
additives
ionic conductivity
diffusion coefficient
gas release
Chemistry
QD1-999
Thi Binh Phan
Thi Van Anh Nguyen
Thi Thanh Thuy Mai
Thi Xuan Mai
Duyen Nguyen The
Thi Chuyen Vi
Quy Bui Minh
Mixed gel electrolytes: Synthesis, characterization, and gas release on PbSb electrode
description Mixed gel electrolytes were fabricated chemically at a temperature range of 2–5°C using some additives comparing with traditional electrolytes (1.26 g/cm3 H2SO4). The polyacrylamide (PAM) content is kept constant (0.2 wt%), while the propylene glycol (PPG) and nano fumed silica (NFS) contents varied. The material characteristics of samples were assessed by physical appearance observation, electrochemical measurements, and physicochemical methods. The results showed that a hard gel without separation of solutions was found in the case using a PAM/PPG/NFS ternary additive (0.2/0.1/0.6 wt%). The morphological structure (<50 nm) of mixed gel electrolytes was in the range of nanometer. The gas release on the PbSb electrode was strongly inhibited (92.2–93.7% for O2 and ∼55% for H2 at the 120th cycle), which will both contributes to reducing the pressure as well as limiting water loss in the sealed lead acid battery, compared with that in the sulfuric acid medium.
format article
author Thi Binh Phan
Thi Van Anh Nguyen
Thi Thanh Thuy Mai
Thi Xuan Mai
Duyen Nguyen The
Thi Chuyen Vi
Quy Bui Minh
author_facet Thi Binh Phan
Thi Van Anh Nguyen
Thi Thanh Thuy Mai
Thi Xuan Mai
Duyen Nguyen The
Thi Chuyen Vi
Quy Bui Minh
author_sort Thi Binh Phan
title Mixed gel electrolytes: Synthesis, characterization, and gas release on PbSb electrode
title_short Mixed gel electrolytes: Synthesis, characterization, and gas release on PbSb electrode
title_full Mixed gel electrolytes: Synthesis, characterization, and gas release on PbSb electrode
title_fullStr Mixed gel electrolytes: Synthesis, characterization, and gas release on PbSb electrode
title_full_unstemmed Mixed gel electrolytes: Synthesis, characterization, and gas release on PbSb electrode
title_sort mixed gel electrolytes: synthesis, characterization, and gas release on pbsb electrode
publisher De Gruyter
publishDate 2021
url https://doaj.org/article/544465f0b3be4d3bb0ba2d6094fccb8a
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