Selective Hydrogenation of Sucrose into Sugar Alcohols over Supported Raney Nickel-Based Catalysts

Selective hydrogenation of sugars (e.g. sucrose, cellobiose, glucose, fructose, xylose, arabinose) into sugar alcohols (sorbitol, mannitol, xylitol, arabitol) can be achieved by means of supported Raney Ni-based catalysts. Various supporting materials such as the layered structure of clay (e.g. bent...

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Autores principales:	Rodiansono Rodiansono, Maria Dewi Astuti, Dwi Rasy Mujiyanti, Uripto Trisno Santoso
Formato:	article
Lenguaje:	EN
Publicado:	Department of Chemistry, Universitas Gadjah Mada 2019
Materias:	selective hydrogenation sugars sugar alcohols supported Raney Ni acidic co-catalysts Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/5464d4997c57474d9e88551d4e6ca2f5
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spelling	oai:doaj.org-article:5464d4997c57474d9e88551d4e6ca2f52021-12-02T11:45:19ZSelective Hydrogenation of Sucrose into Sugar Alcohols over Supported Raney Nickel-Based Catalysts1411-94202460-157810.22146/ijc.31319https://doaj.org/article/5464d4997c57474d9e88551d4e6ca2f52019-01-01T00:00:00Zhttps://jurnal.ugm.ac.id/ijc/article/view/31319https://doaj.org/toc/1411-9420https://doaj.org/toc/2460-1578Selective hydrogenation of sugars (e.g. sucrose, cellobiose, glucose, fructose, xylose, arabinose) into sugar alcohols (sorbitol, mannitol, xylitol, arabitol) can be achieved by means of supported Raney Ni-based catalysts. Various supporting materials such as the layered structure of clay (e.g. bentonite, taeniolite, smectite), metal oxides (e.g. Nb2O5, ZrO2, Al2O3), and conventional supports (e.g. carbon, silica, zeolite (JRC-SZ1)) were employed to obtain high performance of supported Raney Ni-based catalysts. The conventional Raney Ni, Raney Ni/AlOH, and Ni-NP with relatively high dispersion exhibited superior catalytic activity compared with the various supported Raney Ni catalysts with the conversion of 100% and hexitols selectivity almost ~99%. The H2 treatment of Raney Ni/SMT at a temperature of 473–773 K caused the increase in Ni(111) crystallite sizes as the conversion of sucrose with compromised decreased of hexitols product. The presence of acidic co-catalyst such as SnO, amberlyst-15, JRC-SZ1, JRC-Z5-9OH1 on Raney Ni/AlOH catalyst significantly enhanced the formation of glycerol product even though the conversion of sucrose compromised decreased owing to the partial leaching of Ni metal into the reaction mixture.Rodiansono RodiansonoMaria Dewi AstutiDwi Rasy MujiyantiUripto Trisno SantosoDepartment of Chemistry, Universitas Gadjah Madaarticleselective hydrogenationsugarssugar alcoholssupported Raney Niacidic co-catalystsChemistryQD1-999ENIndonesian Journal of Chemistry, Vol 19, Iss 1, Pp 183-190 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	selective hydrogenation sugars sugar alcohols supported Raney Ni acidic co-catalysts Chemistry QD1-999
spellingShingle	selective hydrogenation sugars sugar alcohols supported Raney Ni acidic co-catalysts Chemistry QD1-999 Rodiansono Rodiansono Maria Dewi Astuti Dwi Rasy Mujiyanti Uripto Trisno Santoso Selective Hydrogenation of Sucrose into Sugar Alcohols over Supported Raney Nickel-Based Catalysts
description	Selective hydrogenation of sugars (e.g. sucrose, cellobiose, glucose, fructose, xylose, arabinose) into sugar alcohols (sorbitol, mannitol, xylitol, arabitol) can be achieved by means of supported Raney Ni-based catalysts. Various supporting materials such as the layered structure of clay (e.g. bentonite, taeniolite, smectite), metal oxides (e.g. Nb2O5, ZrO2, Al2O3), and conventional supports (e.g. carbon, silica, zeolite (JRC-SZ1)) were employed to obtain high performance of supported Raney Ni-based catalysts. The conventional Raney Ni, Raney Ni/AlOH, and Ni-NP with relatively high dispersion exhibited superior catalytic activity compared with the various supported Raney Ni catalysts with the conversion of 100% and hexitols selectivity almost ~99%. The H2 treatment of Raney Ni/SMT at a temperature of 473–773 K caused the increase in Ni(111) crystallite sizes as the conversion of sucrose with compromised decreased of hexitols product. The presence of acidic co-catalyst such as SnO, amberlyst-15, JRC-SZ1, JRC-Z5-9OH1 on Raney Ni/AlOH catalyst significantly enhanced the formation of glycerol product even though the conversion of sucrose compromised decreased owing to the partial leaching of Ni metal into the reaction mixture.
format	article
author	Rodiansono Rodiansono Maria Dewi Astuti Dwi Rasy Mujiyanti Uripto Trisno Santoso
author_facet	Rodiansono Rodiansono Maria Dewi Astuti Dwi Rasy Mujiyanti Uripto Trisno Santoso
author_sort	Rodiansono Rodiansono
title	Selective Hydrogenation of Sucrose into Sugar Alcohols over Supported Raney Nickel-Based Catalysts
title_short	Selective Hydrogenation of Sucrose into Sugar Alcohols over Supported Raney Nickel-Based Catalysts
title_full	Selective Hydrogenation of Sucrose into Sugar Alcohols over Supported Raney Nickel-Based Catalysts
title_fullStr	Selective Hydrogenation of Sucrose into Sugar Alcohols over Supported Raney Nickel-Based Catalysts
title_full_unstemmed	Selective Hydrogenation of Sucrose into Sugar Alcohols over Supported Raney Nickel-Based Catalysts
title_sort	selective hydrogenation of sucrose into sugar alcohols over supported raney nickel-based catalysts
publisher	Department of Chemistry, Universitas Gadjah Mada
publishDate	2019
url	https://doaj.org/article/5464d4997c57474d9e88551d4e6ca2f5
work_keys_str_mv	AT rodiansonorodiansono selectivehydrogenationofsucroseintosugaralcoholsoversupportedraneynickelbasedcatalysts AT mariadewiastuti selectivehydrogenationofsucroseintosugaralcoholsoversupportedraneynickelbasedcatalysts AT dwirasymujiyanti selectivehydrogenationofsucroseintosugaralcoholsoversupportedraneynickelbasedcatalysts AT uriptotrisnosantoso selectivehydrogenationofsucroseintosugaralcoholsoversupportedraneynickelbasedcatalysts
_version_	1718395281349804032

Selective Hydrogenation of Sucrose into Sugar Alcohols over Supported Raney Nickel-Based Catalysts

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