Pd on poly(1-vinylimidazole) decorated magnetic S-doped grafitic carbon nitride: an efficient catalyst for catalytic reduction of organic dyes

Abstract A novel magnetic catalyst, (SGCN/Fe3O4/PVIs/Pd) was synthesized by growing of poly(1-vinylimidazole) on the surface of ionic liquid decorated magnetic S-doped graphitic carbon nitride, followed by stabilization of palladium nanoparticles. Catalytic activity of the prepared heterogeneous cat...

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Autores principales:	Masoumeh Dorraj, Samahe Sadjadi, Majid M. Heravi
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/5479b266bd1a4666a8589a4a1f9a3b97
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spelling	oai:doaj.org-article:5479b266bd1a4666a8589a4a1f9a3b972021-12-02T18:50:49ZPd on poly(1-vinylimidazole) decorated magnetic S-doped grafitic carbon nitride: an efficient catalyst for catalytic reduction of organic dyes10.1038/s41598-020-70457-52045-2322https://doaj.org/article/5479b266bd1a4666a8589a4a1f9a3b972020-08-01T00:00:00Zhttps://doi.org/10.1038/s41598-020-70457-5https://doaj.org/toc/2045-2322Abstract A novel magnetic catalyst, (SGCN/Fe3O4/PVIs/Pd) was synthesized by growing of poly(1-vinylimidazole) on the surface of ionic liquid decorated magnetic S-doped graphitic carbon nitride, followed by stabilization of palladium nanoparticles. Catalytic activity of the prepared heterogeneous catalyst was explored for the catalytic reduction of hazardous dyes, methyl orange and Rhodamine B, in the presence of NaBH4. Besides, the effects of the reaction variables on the catalytic activity were investigated in detail. The kinetics study established that dye reduction was the first order reaction and the apparent activation energy was calculated to be 72.63 kJ/mol and 68.35 kJ/mol1 for methyl orange and Rhodamine B dyes, respectively. Moreover, ΔS# and ΔH# values for methyl orange were found to be − 33.67 J/mol K and 68.39 kJ/mol respectively. These values for Rhodamine B were − 45.62 J/mol K and 65.92 kJ/mol. The recycling test verified that the catalyst possessed good stability and reusability, thereby making it a good candidate for the catalytic purposes. Furthermore, a possible catalytic mechanism for dye catalytic reduction over SGCN/Fe3O4/PVIs/Pd was proposed.Masoumeh DorrajSamahe SadjadiMajid M. HeraviNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 10, Iss 1, Pp 1-10 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Masoumeh Dorraj Samahe Sadjadi Majid M. Heravi Pd on poly(1-vinylimidazole) decorated magnetic S-doped grafitic carbon nitride: an efficient catalyst for catalytic reduction of organic dyes
description	Abstract A novel magnetic catalyst, (SGCN/Fe3O4/PVIs/Pd) was synthesized by growing of poly(1-vinylimidazole) on the surface of ionic liquid decorated magnetic S-doped graphitic carbon nitride, followed by stabilization of palladium nanoparticles. Catalytic activity of the prepared heterogeneous catalyst was explored for the catalytic reduction of hazardous dyes, methyl orange and Rhodamine B, in the presence of NaBH4. Besides, the effects of the reaction variables on the catalytic activity were investigated in detail. The kinetics study established that dye reduction was the first order reaction and the apparent activation energy was calculated to be 72.63 kJ/mol and 68.35 kJ/mol1 for methyl orange and Rhodamine B dyes, respectively. Moreover, ΔS# and ΔH# values for methyl orange were found to be − 33.67 J/mol K and 68.39 kJ/mol respectively. These values for Rhodamine B were − 45.62 J/mol K and 65.92 kJ/mol. The recycling test verified that the catalyst possessed good stability and reusability, thereby making it a good candidate for the catalytic purposes. Furthermore, a possible catalytic mechanism for dye catalytic reduction over SGCN/Fe3O4/PVIs/Pd was proposed.
format	article
author	Masoumeh Dorraj Samahe Sadjadi Majid M. Heravi
author_facet	Masoumeh Dorraj Samahe Sadjadi Majid M. Heravi
author_sort	Masoumeh Dorraj
title	Pd on poly(1-vinylimidazole) decorated magnetic S-doped grafitic carbon nitride: an efficient catalyst for catalytic reduction of organic dyes
title_short	Pd on poly(1-vinylimidazole) decorated magnetic S-doped grafitic carbon nitride: an efficient catalyst for catalytic reduction of organic dyes
title_full	Pd on poly(1-vinylimidazole) decorated magnetic S-doped grafitic carbon nitride: an efficient catalyst for catalytic reduction of organic dyes
title_fullStr	Pd on poly(1-vinylimidazole) decorated magnetic S-doped grafitic carbon nitride: an efficient catalyst for catalytic reduction of organic dyes
title_full_unstemmed	Pd on poly(1-vinylimidazole) decorated magnetic S-doped grafitic carbon nitride: an efficient catalyst for catalytic reduction of organic dyes
title_sort	pd on poly(1-vinylimidazole) decorated magnetic s-doped grafitic carbon nitride: an efficient catalyst for catalytic reduction of organic dyes
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/5479b266bd1a4666a8589a4a1f9a3b97
work_keys_str_mv	AT masoumehdorraj pdonpoly1vinylimidazoledecoratedmagneticsdopedgrafiticcarbonnitrideanefficientcatalystforcatalyticreductionoforganicdyes AT samahesadjadi pdonpoly1vinylimidazoledecoratedmagneticsdopedgrafiticcarbonnitrideanefficientcatalystforcatalyticreductionoforganicdyes AT majidmheravi pdonpoly1vinylimidazoledecoratedmagneticsdopedgrafiticcarbonnitrideanefficientcatalystforcatalyticreductionoforganicdyes
_version_	1718377503165251584

Pd on poly(1-vinylimidazole) decorated magnetic S-doped grafitic carbon nitride: an efficient catalyst for catalytic reduction of organic dyes

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