Radical-mediated C-C cleavage of unstrained cycloketones and DFT study for unusual regioselectivity
C-C bond scission of unstrained cycloketones with high regioselectivity is a challenging synthetic task. Here, the authors show a facile C-C cleavage of cyclohexanones and cyclopentanones with unusual selectivity under mild conditions with the aid of an in situ formed side-chain aryl radical.
Enregistré dans:
| Auteurs principaux: | , , , , , |
|---|---|
| Format: | article |
| Langue: | EN |
| Publié: |
Nature Portfolio
2020
|
| Sujets: | |
| Accès en ligne: | https://doaj.org/article/55051764b1994bef9084f3bc8a817022 |
| Tags: |
Ajouter un tag
Pas de tags, Soyez le premier à ajouter un tag!
|