Electrochemical deposition of N-heterocyclic carbene monolayers on metal surfaces

N-heterocyclic carbenes (NHCs) have been widely used for the formation of monolayers but self-assembly methods come with drawbacks such as need for dry environment or using specifically-synthesized precursors. Here, the authors demonstrate an approach for surface-anchoring of NHCs which overcomes th...

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Autores principales:	Einav Amit, Linoy Dery, Shahar Dery, Suhong Kim, Anirban Roy, Qichi Hu, Vitaly Gutkin, Helen Eisenberg, Tamar Stein, Daniel Mandler, F. Dean Toste, Elad Gross
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/552ef45da15b442a8f7cbe98e36e2070
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spelling	oai:doaj.org-article:552ef45da15b442a8f7cbe98e36e20702021-12-02T17:32:12ZElectrochemical deposition of N-heterocyclic carbene monolayers on metal surfaces10.1038/s41467-020-19500-72041-1723https://doaj.org/article/552ef45da15b442a8f7cbe98e36e20702020-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-19500-7https://doaj.org/toc/2041-1723N-heterocyclic carbenes (NHCs) have been widely used for the formation of monolayers but self-assembly methods come with drawbacks such as need for dry environment or using specifically-synthesized precursors. Here, the authors demonstrate an approach for surface-anchoring of NHCs which overcomes these limitations by using electrochemically-assisted deprotonation.Einav AmitLinoy DeryShahar DerySuhong KimAnirban RoyQichi HuVitaly GutkinHelen EisenbergTamar SteinDaniel MandlerF. Dean TosteElad GrossNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-10 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Einav Amit Linoy Dery Shahar Dery Suhong Kim Anirban Roy Qichi Hu Vitaly Gutkin Helen Eisenberg Tamar Stein Daniel Mandler F. Dean Toste Elad Gross Electrochemical deposition of N-heterocyclic carbene monolayers on metal surfaces
description	N-heterocyclic carbenes (NHCs) have been widely used for the formation of monolayers but self-assembly methods come with drawbacks such as need for dry environment or using specifically-synthesized precursors. Here, the authors demonstrate an approach for surface-anchoring of NHCs which overcomes these limitations by using electrochemically-assisted deprotonation.
format	article
author	Einav Amit Linoy Dery Shahar Dery Suhong Kim Anirban Roy Qichi Hu Vitaly Gutkin Helen Eisenberg Tamar Stein Daniel Mandler F. Dean Toste Elad Gross
author_facet	Einav Amit Linoy Dery Shahar Dery Suhong Kim Anirban Roy Qichi Hu Vitaly Gutkin Helen Eisenberg Tamar Stein Daniel Mandler F. Dean Toste Elad Gross
author_sort	Einav Amit
title	Electrochemical deposition of N-heterocyclic carbene monolayers on metal surfaces
title_short	Electrochemical deposition of N-heterocyclic carbene monolayers on metal surfaces
title_full	Electrochemical deposition of N-heterocyclic carbene monolayers on metal surfaces
title_fullStr	Electrochemical deposition of N-heterocyclic carbene monolayers on metal surfaces
title_full_unstemmed	Electrochemical deposition of N-heterocyclic carbene monolayers on metal surfaces
title_sort	electrochemical deposition of n-heterocyclic carbene monolayers on metal surfaces
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/552ef45da15b442a8f7cbe98e36e2070
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Electrochemical deposition of N-heterocyclic carbene monolayers on metal surfaces

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