Spatial intimacy of binary active-sites for selective sequential hydrogenation-condensation of nitriles into secondary imines

Precisely controlling the spatial intimacy of multiple active sites in heterogeneous catalysts can significantly affect the selectivity and activity. Here the authors show a binary active site of single atom Pt and Lewis acidic B with spatial intimacy enables a highly selective nitrile-to-secondary...

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Autores principales:	Sai Zhang, Zhaoming Xia, Yong Zou, Mingkai Zhang, Yongquan Qu
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/5540749e36704dbea46aae0bd38dc3ba
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id	oai:doaj.org-article:5540749e36704dbea46aae0bd38dc3ba
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spelling	oai:doaj.org-article:5540749e36704dbea46aae0bd38dc3ba2021-12-02T17:34:38ZSpatial intimacy of binary active-sites for selective sequential hydrogenation-condensation of nitriles into secondary imines10.1038/s41467-021-23705-92041-1723https://doaj.org/article/5540749e36704dbea46aae0bd38dc3ba2021-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-23705-9https://doaj.org/toc/2041-1723Precisely controlling the spatial intimacy of multiple active sites in heterogeneous catalysts can significantly affect the selectivity and activity. Here the authors show a binary active site of single atom Pt and Lewis acidic B with spatial intimacy enables a highly selective nitrile-to-secondary imine transformation.Sai ZhangZhaoming XiaYong ZouMingkai ZhangYongquan QuNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-8 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Sai Zhang Zhaoming Xia Yong Zou Mingkai Zhang Yongquan Qu Spatial intimacy of binary active-sites for selective sequential hydrogenation-condensation of nitriles into secondary imines
description	Precisely controlling the spatial intimacy of multiple active sites in heterogeneous catalysts can significantly affect the selectivity and activity. Here the authors show a binary active site of single atom Pt and Lewis acidic B with spatial intimacy enables a highly selective nitrile-to-secondary imine transformation.
format	article
author	Sai Zhang Zhaoming Xia Yong Zou Mingkai Zhang Yongquan Qu
author_facet	Sai Zhang Zhaoming Xia Yong Zou Mingkai Zhang Yongquan Qu
author_sort	Sai Zhang
title	Spatial intimacy of binary active-sites for selective sequential hydrogenation-condensation of nitriles into secondary imines
title_short	Spatial intimacy of binary active-sites for selective sequential hydrogenation-condensation of nitriles into secondary imines
title_full	Spatial intimacy of binary active-sites for selective sequential hydrogenation-condensation of nitriles into secondary imines
title_fullStr	Spatial intimacy of binary active-sites for selective sequential hydrogenation-condensation of nitriles into secondary imines
title_full_unstemmed	Spatial intimacy of binary active-sites for selective sequential hydrogenation-condensation of nitriles into secondary imines
title_sort	spatial intimacy of binary active-sites for selective sequential hydrogenation-condensation of nitriles into secondary imines
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/5540749e36704dbea46aae0bd38dc3ba
work_keys_str_mv	AT saizhang spatialintimacyofbinaryactivesitesforselectivesequentialhydrogenationcondensationofnitrilesintosecondaryimines AT zhaomingxia spatialintimacyofbinaryactivesitesforselectivesequentialhydrogenationcondensationofnitrilesintosecondaryimines AT yongzou spatialintimacyofbinaryactivesitesforselectivesequentialhydrogenationcondensationofnitrilesintosecondaryimines AT mingkaizhang spatialintimacyofbinaryactivesitesforselectivesequentialhydrogenationcondensationofnitrilesintosecondaryimines AT yongquanqu spatialintimacyofbinaryactivesitesforselectivesequentialhydrogenationcondensationofnitrilesintosecondaryimines
_version_	1718379939789537280

Spatial intimacy of binary active-sites for selective sequential hydrogenation-condensation of nitriles into secondary imines

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