Removal of Pyridine, Quinoline, and Aniline from Oil by Extraction with Aqueous Solution of (Hydroxy)quinolinium and Benzothiazolium Ionic Liquids in Various Ways
Based on above background, quinolinium, 8-hydroxy-quinolinium, and benzothiazolium ionic liquids, containing the acidic anions of methanesulfonate ([CH<sub>3</sub>SO<sub>3</sub>]<sup>−</sup>), phosphate ([H<sub>2</sub>PO<sub>4</sub>]<sup...
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| Autores principales: | , , , , , |
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| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
MDPI AG
2021
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| Materias: | |
| Acceso en línea: | https://doaj.org/article/557a4768402a4ee7860225725ca42eaa |
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| Sumario: | Based on above background, quinolinium, 8-hydroxy-quinolinium, and benzothiazolium ionic liquids, containing the acidic anions of methanesulfonate ([CH<sub>3</sub>SO<sub>3</sub>]<sup>−</sup>), phosphate ([H<sub>2</sub>PO<sub>4</sub>]<sup>−</sup>), <i>p</i>-toluenesulfonate ([<i>p</i>-TSA]<sup>−</sup>), and bisulfate ([HSO<sub>4</sub>]<sup>−</sup>) were synthesized. After comparison, the aqueous solution of benzothiazole bisulfate [HBth][HSO<sub>4</sub>] was selected as the most ideal extractant for removing pyridine and aniline. Meanwhile, benzothiazole bisulfate [HBth][HSO<sub>4</sub>] solution was found as the best one for removing quinoline from simulated oil. Then, the single stage extraction and two-step extraction were used in the extraction for the simulated oil containing pyridine, quinoline or aniline, and their mixture, respectively. Their denitrogenation performance on their N-removal effect was compared on the basis of structural features, and main extraction conditions were further investigated, including mass ratio of IL to water, mass ratio of IL to oil, and temperature. Furthermore, the extraction process was described by two kinetic equations. Recovery and reuse of IL were realized by back-extraction and liquid-liquid separation, and a related mechanism was speculated, according to all the experimental results. Finally, based on the developed method for preparing complex adsorbent tablets, corresponding immobilized IL was used to remove target objects, by solid phase extraction, in order to extend separation ways, which was more easily recovered after extraction. |
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