Coordination behavior of PPh2{C6H4[CH2N(CH2CH2)2O]-2}: Case study CdCl2[PPh2{C6H4[CH2N(CH2CH2)2O]-2}]

The reaction between CdCl2 and PPh2{C6H4 [CH2N(CH2CH2)2O]-2} (1) in a 1:1 molar ratio resulted in the cadmium(II) complex CdCl2[PPh2{C6H4[CH2N(CH2CH2)2O]-2}] (2). The complex 2 was characterized in solution by NMR spectroscopy (1H, 13C, and 31P). Single-crystal X-ray diffraction studies revealed no...

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Autores principales:	Covaci Ancuța, Silvestru Cristian, Silvestru Anca
Formato:	article
Lenguaje:	EN
Publicado:	De Gruyter 2021
Materias:	triarylphosphane ligand cadmium complexes chelating behavior nmr spectroscopy crystal and molecular structure Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/55a226a6ab9a48bebd9afcac152d2cc9
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spelling	oai:doaj.org-article:55a226a6ab9a48bebd9afcac152d2cc92021-12-05T14:10:56ZCoordination behavior of PPh2{C6H4[CH2N(CH2CH2)2O]-2}: Case study CdCl2[PPh2{C6H4[CH2N(CH2CH2)2O]-2}]0792-12412191-021910.1515/mgmc-2021-0029https://doaj.org/article/55a226a6ab9a48bebd9afcac152d2cc92021-11-01T00:00:00Zhttps://doi.org/10.1515/mgmc-2021-0029https://doaj.org/toc/0792-1241https://doaj.org/toc/2191-0219The reaction between CdCl2 and PPh2{C6H4 [CH2N(CH2CH2)2O]-2} (1) in a 1:1 molar ratio resulted in the cadmium(II) complex CdCl2[PPh2{C6H4[CH2N(CH2CH2)2O]-2}] (2). The complex 2 was characterized in solution by NMR spectroscopy (1H, 13C, and 31P). Single-crystal X-ray diffraction studies revealed no intramolecular N→P interaction in 1. The phosphane ligand behaves as a P,N chelating moiety in the cadmium complex 2, thus resulting in a species containing distorted tetrahedral environments around cadmium and phosphorus. Short intermolecular interactions CH‧‧‧π aryl and CH‧‧‧O in 1 and CH‧‧‧π aryl and CH‧‧‧Cl in 2 resulted in supramolecular networks.Covaci AncuțaSilvestru CristianSilvestru AncaDe Gruyterarticletriarylphosphane ligandcadmium complexeschelating behaviornmr spectroscopycrystal and molecular structureChemistryQD1-999ENMain Group Metal Chemistry, Vol 44, Iss 1, Pp 261-266 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	triarylphosphane ligand cadmium complexes chelating behavior nmr spectroscopy crystal and molecular structure Chemistry QD1-999
spellingShingle	triarylphosphane ligand cadmium complexes chelating behavior nmr spectroscopy crystal and molecular structure Chemistry QD1-999 Covaci Ancuța Silvestru Cristian Silvestru Anca Coordination behavior of PPh2{C6H4[CH2N(CH2CH2)2O]-2}: Case study CdCl2[PPh2{C6H4[CH2N(CH2CH2)2O]-2}]
description	The reaction between CdCl2 and PPh2{C6H4 [CH2N(CH2CH2)2O]-2} (1) in a 1:1 molar ratio resulted in the cadmium(II) complex CdCl2[PPh2{C6H4[CH2N(CH2CH2)2O]-2}] (2). The complex 2 was characterized in solution by NMR spectroscopy (1H, 13C, and 31P). Single-crystal X-ray diffraction studies revealed no intramolecular N→P interaction in 1. The phosphane ligand behaves as a P,N chelating moiety in the cadmium complex 2, thus resulting in a species containing distorted tetrahedral environments around cadmium and phosphorus. Short intermolecular interactions CH‧‧‧π aryl and CH‧‧‧O in 1 and CH‧‧‧π aryl and CH‧‧‧Cl in 2 resulted in supramolecular networks.
format	article
author	Covaci Ancuța Silvestru Cristian Silvestru Anca
author_facet	Covaci Ancuța Silvestru Cristian Silvestru Anca
author_sort	Covaci Ancuța
title	Coordination behavior of PPh2{C6H4[CH2N(CH2CH2)2O]-2}: Case study CdCl2[PPh2{C6H4[CH2N(CH2CH2)2O]-2}]
title_short	Coordination behavior of PPh2{C6H4[CH2N(CH2CH2)2O]-2}: Case study CdCl2[PPh2{C6H4[CH2N(CH2CH2)2O]-2}]
title_full	Coordination behavior of PPh2{C6H4[CH2N(CH2CH2)2O]-2}: Case study CdCl2[PPh2{C6H4[CH2N(CH2CH2)2O]-2}]
title_fullStr	Coordination behavior of PPh2{C6H4[CH2N(CH2CH2)2O]-2}: Case study CdCl2[PPh2{C6H4[CH2N(CH2CH2)2O]-2}]
title_full_unstemmed	Coordination behavior of PPh2{C6H4[CH2N(CH2CH2)2O]-2}: Case study CdCl2[PPh2{C6H4[CH2N(CH2CH2)2O]-2}]
title_sort	coordination behavior of pph2{c6h4[ch2n(ch2ch2)2o]-2}: case study cdcl2[pph2{c6h4[ch2n(ch2ch2)2o]-2}]
publisher	De Gruyter
publishDate	2021
url	https://doaj.org/article/55a226a6ab9a48bebd9afcac152d2cc9
work_keys_str_mv	AT covaciancuta coordinationbehaviorofpph2c6h4ch2nch2ch22o2casestudycdcl2pph2c6h4ch2nch2ch22o2 AT silvestrucristian coordinationbehaviorofpph2c6h4ch2nch2ch22o2casestudycdcl2pph2c6h4ch2nch2ch22o2 AT silvestruanca coordinationbehaviorofpph2c6h4ch2nch2ch22o2casestudycdcl2pph2c6h4ch2nch2ch22o2
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Coordination behavior of PPh2{C6H4[CH2N(CH2CH2)2O]-2}: Case study CdCl2[PPh2{C6H4[CH2N(CH2CH2)2O]-2}]

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