High-modulus rotary jet spun co-polyimide nanofibers and their composites

The production of high-modulus and high-strength polymer nanofibers using centrifugal or rotary jet spinning (RJS) was explored. Co-polyimide nanofibers based on 3,3′,4,4′-biphenyl-tetracarboxylic dianhydride (BPDA)/p-phenylenediamine (PDA)/4,4′-oxydianiline (ODA) (BPO) were successfully spun by RJS...

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Autores principales:	James J. Rogalski, Han Zhang, Jian Yao, Cees W. M. Bastiaansen, Ton Peijs
Formato:	article
Lenguaje:	EN
Publicado:	Taylor & Francis Group 2020
Materias:	rotary jet spinning centrifugal spinning nanofibers composites mechanical properties Materials of engineering and construction. Mechanics of materials TA401-492 Polymers and polymer manufacture TP1080-1185
Acceso en línea:	https://doaj.org/article/55ba1ae50bbb4d9d989a85390c6df1c0
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spelling	oai:doaj.org-article:55ba1ae50bbb4d9d989a85390c6df1c02021-12-02T06:40:46ZHigh-modulus rotary jet spun co-polyimide nanofibers and their composites2055-033210.1080/20550324.2019.1687174https://doaj.org/article/55ba1ae50bbb4d9d989a85390c6df1c02020-01-01T00:00:00Zhttp://dx.doi.org/10.1080/20550324.2019.1687174https://doaj.org/toc/2055-0332The production of high-modulus and high-strength polymer nanofibers using centrifugal or rotary jet spinning (RJS) was explored. Co-polyimide nanofibers based on 3,3′,4,4′-biphenyl-tetracarboxylic dianhydride (BPDA)/p-phenylenediamine (PDA)/4,4′-oxydianiline (ODA) (BPO) were successfully spun by RJS from a polyamic acid precursor solution before conversion into highly oriented and chain extended BPO co-polyimide fibers via an imidization step. Fourier transform infrared (FTIR) characterization was used to evaluate the chemical conversion of the fibers. Nanocomposite laminates based on co-polyimide nonwoven fiber mats in epoxy were manufactured for mechanical testing. Analysis using the generalized rule of mixtures resulted in a back-calculated fiber modulus and strength of around 50 and 2 GPa, approaching that of high-performance fibers like Kevlar® 29, and equaling those of co-polyimide fibers obtained via electrospinning, making them the strongest centrifugal spun fibers ever reported.James J. RogalskiHan ZhangJian YaoCees W. M. BastiaansenTon PeijsTaylor & Francis Grouparticlerotary jet spinningcentrifugal spinningnanofiberscompositesmechanical propertiesMaterials of engineering and construction. Mechanics of materialsTA401-492Polymers and polymer manufactureTP1080-1185ENNanocomposites, Vol 6, Iss 1, Pp 1-11 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	rotary jet spinning centrifugal spinning nanofibers composites mechanical properties Materials of engineering and construction. Mechanics of materials TA401-492 Polymers and polymer manufacture TP1080-1185
spellingShingle	rotary jet spinning centrifugal spinning nanofibers composites mechanical properties Materials of engineering and construction. Mechanics of materials TA401-492 Polymers and polymer manufacture TP1080-1185 James J. Rogalski Han Zhang Jian Yao Cees W. M. Bastiaansen Ton Peijs High-modulus rotary jet spun co-polyimide nanofibers and their composites
description	The production of high-modulus and high-strength polymer nanofibers using centrifugal or rotary jet spinning (RJS) was explored. Co-polyimide nanofibers based on 3,3′,4,4′-biphenyl-tetracarboxylic dianhydride (BPDA)/p-phenylenediamine (PDA)/4,4′-oxydianiline (ODA) (BPO) were successfully spun by RJS from a polyamic acid precursor solution before conversion into highly oriented and chain extended BPO co-polyimide fibers via an imidization step. Fourier transform infrared (FTIR) characterization was used to evaluate the chemical conversion of the fibers. Nanocomposite laminates based on co-polyimide nonwoven fiber mats in epoxy were manufactured for mechanical testing. Analysis using the generalized rule of mixtures resulted in a back-calculated fiber modulus and strength of around 50 and 2 GPa, approaching that of high-performance fibers like Kevlar® 29, and equaling those of co-polyimide fibers obtained via electrospinning, making them the strongest centrifugal spun fibers ever reported.
format	article
author	James J. Rogalski Han Zhang Jian Yao Cees W. M. Bastiaansen Ton Peijs
author_facet	James J. Rogalski Han Zhang Jian Yao Cees W. M. Bastiaansen Ton Peijs
author_sort	James J. Rogalski
title	High-modulus rotary jet spun co-polyimide nanofibers and their composites
title_short	High-modulus rotary jet spun co-polyimide nanofibers and their composites
title_full	High-modulus rotary jet spun co-polyimide nanofibers and their composites
title_fullStr	High-modulus rotary jet spun co-polyimide nanofibers and their composites
title_full_unstemmed	High-modulus rotary jet spun co-polyimide nanofibers and their composites
title_sort	high-modulus rotary jet spun co-polyimide nanofibers and their composites
publisher	Taylor & Francis Group
publishDate	2020
url	https://doaj.org/article/55ba1ae50bbb4d9d989a85390c6df1c0
work_keys_str_mv	AT jamesjrogalski highmodulusrotaryjetspuncopolyimidenanofibersandtheircomposites AT hanzhang highmodulusrotaryjetspuncopolyimidenanofibersandtheircomposites AT jianyao highmodulusrotaryjetspuncopolyimidenanofibersandtheircomposites AT ceeswmbastiaansen highmodulusrotaryjetspuncopolyimidenanofibersandtheircomposites AT tonpeijs highmodulusrotaryjetspuncopolyimidenanofibersandtheircomposites
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High-modulus rotary jet spun co-polyimide nanofibers and their composites

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