Study on Selected Metal-Organic Framework-Based Catalysts for Cycloaddition Reaction of CO<sub>2</sub> with Epoxides: A Highly Economic Solution for Carbon Capture and Utilization

The level of carbon dioxide in the atmosphere is growing rapidly due to fossil fuel combustion processes, heavy oil, coal, oil shelter, and exhausts from automobiles for energy generation, which lead to depletion of the ozone layer and consequently result in global warming. The realization of a carb...

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Autores principales:	Suleiman Gani Musa, Zulkifli Merican Aljunid Merican, Omid Akbarzadeh
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	cycloaddition epoxides carbon dioxide metal-organic frameworks Organic chemistry QD241-441
Acceso en línea:	https://doaj.org/article/5612d540ddab4e50b31f7639e7e20f75
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spelling	oai:doaj.org-article:5612d540ddab4e50b31f7639e7e20f752021-11-25T18:48:09ZStudy on Selected Metal-Organic Framework-Based Catalysts for Cycloaddition Reaction of CO<sub>2</sub> with Epoxides: A Highly Economic Solution for Carbon Capture and Utilization10.3390/polym132239052073-4360https://doaj.org/article/5612d540ddab4e50b31f7639e7e20f752021-11-01T00:00:00Zhttps://www.mdpi.com/2073-4360/13/22/3905https://doaj.org/toc/2073-4360The level of carbon dioxide in the atmosphere is growing rapidly due to fossil fuel combustion processes, heavy oil, coal, oil shelter, and exhausts from automobiles for energy generation, which lead to depletion of the ozone layer and consequently result in global warming. The realization of a carbon-neutral environment is the main focus of science and academic researchers of today. Several processes were employed to minimize carbon dioxide in the air, some of which include the utilization of non-fossil sources of energy like solar, nuclear, and biomass-based fuels. Consequently, these sources were reported to have a relatively high cost of production and maintenance. The applications of both homogeneous and heterogeneous processes in carbon capture and storage were investigated in recent years and the focus now is on the conversion of CO<sub>2</sub> into useful chemicals and compounds. It was established that CO<sub>2</sub> can undergo cycloaddition reaction with epoxides under the influence of special catalysts to give cyclic carbonates, which can be used as value-added chemicals at a different level of pharmaceutical and industrial applications. Among the various catalysts studied for this reaction, metal-organic frameworks are now on the frontline as a potential catalyst due to their special features and easy synthesis. Several metal-organic framework (MOF)-based catalysts were studied for their application in transforming CO<sub>2</sub> to organic carbonates using epoxides. Here, we report some recent studies of porous MOF materials and an in-depth discussion of two repeatedly used metal-organic frameworks as a catalyst in the conversion of CO<sub>2</sub> to organic carbonates.Suleiman Gani MusaZulkifli Merican Aljunid MericanOmid AkbarzadehMDPI AGarticlecycloadditionepoxidescarbon dioxidemetal-organic frameworksOrganic chemistryQD241-441ENPolymers, Vol 13, Iss 3905, p 3905 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	cycloaddition epoxides carbon dioxide metal-organic frameworks Organic chemistry QD241-441
spellingShingle	cycloaddition epoxides carbon dioxide metal-organic frameworks Organic chemistry QD241-441 Suleiman Gani Musa Zulkifli Merican Aljunid Merican Omid Akbarzadeh Study on Selected Metal-Organic Framework-Based Catalysts for Cycloaddition Reaction of CO<sub>2</sub> with Epoxides: A Highly Economic Solution for Carbon Capture and Utilization
description	The level of carbon dioxide in the atmosphere is growing rapidly due to fossil fuel combustion processes, heavy oil, coal, oil shelter, and exhausts from automobiles for energy generation, which lead to depletion of the ozone layer and consequently result in global warming. The realization of a carbon-neutral environment is the main focus of science and academic researchers of today. Several processes were employed to minimize carbon dioxide in the air, some of which include the utilization of non-fossil sources of energy like solar, nuclear, and biomass-based fuels. Consequently, these sources were reported to have a relatively high cost of production and maintenance. The applications of both homogeneous and heterogeneous processes in carbon capture and storage were investigated in recent years and the focus now is on the conversion of CO<sub>2</sub> into useful chemicals and compounds. It was established that CO<sub>2</sub> can undergo cycloaddition reaction with epoxides under the influence of special catalysts to give cyclic carbonates, which can be used as value-added chemicals at a different level of pharmaceutical and industrial applications. Among the various catalysts studied for this reaction, metal-organic frameworks are now on the frontline as a potential catalyst due to their special features and easy synthesis. Several metal-organic framework (MOF)-based catalysts were studied for their application in transforming CO<sub>2</sub> to organic carbonates using epoxides. Here, we report some recent studies of porous MOF materials and an in-depth discussion of two repeatedly used metal-organic frameworks as a catalyst in the conversion of CO<sub>2</sub> to organic carbonates.
format	article
author	Suleiman Gani Musa Zulkifli Merican Aljunid Merican Omid Akbarzadeh
author_facet	Suleiman Gani Musa Zulkifli Merican Aljunid Merican Omid Akbarzadeh
author_sort	Suleiman Gani Musa
title	Study on Selected Metal-Organic Framework-Based Catalysts for Cycloaddition Reaction of CO<sub>2</sub> with Epoxides: A Highly Economic Solution for Carbon Capture and Utilization
title_short	Study on Selected Metal-Organic Framework-Based Catalysts for Cycloaddition Reaction of CO<sub>2</sub> with Epoxides: A Highly Economic Solution for Carbon Capture and Utilization
title_full	Study on Selected Metal-Organic Framework-Based Catalysts for Cycloaddition Reaction of CO<sub>2</sub> with Epoxides: A Highly Economic Solution for Carbon Capture and Utilization
title_fullStr	Study on Selected Metal-Organic Framework-Based Catalysts for Cycloaddition Reaction of CO<sub>2</sub> with Epoxides: A Highly Economic Solution for Carbon Capture and Utilization
title_full_unstemmed	Study on Selected Metal-Organic Framework-Based Catalysts for Cycloaddition Reaction of CO<sub>2</sub> with Epoxides: A Highly Economic Solution for Carbon Capture and Utilization
title_sort	study on selected metal-organic framework-based catalysts for cycloaddition reaction of co<sub>2</sub> with epoxides: a highly economic solution for carbon capture and utilization
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/5612d540ddab4e50b31f7639e7e20f75
work_keys_str_mv	AT suleimanganimusa studyonselectedmetalorganicframeworkbasedcatalystsforcycloadditionreactionofcosub2subwithepoxidesahighlyeconomicsolutionforcarboncaptureandutilization AT zulkiflimericanaljunidmerican studyonselectedmetalorganicframeworkbasedcatalystsforcycloadditionreactionofcosub2subwithepoxidesahighlyeconomicsolutionforcarboncaptureandutilization AT omidakbarzadeh studyonselectedmetalorganicframeworkbasedcatalystsforcycloadditionreactionofcosub2subwithepoxidesahighlyeconomicsolutionforcarboncaptureandutilization
_version_	1718410712830705664

Study on Selected Metal-Organic Framework-Based Catalysts for Cycloaddition Reaction of CO<sub>2</sub> with Epoxides: A Highly Economic Solution for Carbon Capture and Utilization

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