Petrogenesis of Neoproterozoic Ultramafic Rocks, Wadi Ibib–Wadi Shani, South Eastern Desert, Egypt: Constraints from Whole Rock and Mineral Chemistry

This contribution deals with new geology, petrography, and bulk-rock/mineral chemistry of the poorly studied ultramafics of Wadi Ibib–Wadi Shani (WI–WS) district, South Eastern Desert, Egypt. These ultramafics are dismembered ophiolitic rocks that can be subdivided into serpentinites and serpentiniz...

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Autores principales: El Saeed R. Lasheen, Gehad M. Saleh, Farrage M. Khaleal, Mamdooh Alwetaishi
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Lenguaje:EN
Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:567973c1bead493191285341426aea0e2021-11-25T16:30:44ZPetrogenesis of Neoproterozoic Ultramafic Rocks, Wadi Ibib–Wadi Shani, South Eastern Desert, Egypt: Constraints from Whole Rock and Mineral Chemistry10.3390/app1122105242076-3417https://doaj.org/article/567973c1bead493191285341426aea0e2021-11-01T00:00:00Zhttps://www.mdpi.com/2076-3417/11/22/10524https://doaj.org/toc/2076-3417This contribution deals with new geology, petrography, and bulk-rock/mineral chemistry of the poorly studied ultramafics of Wadi Ibib–Wadi Shani (WI–WS) district, South Eastern Desert, Egypt. These ultramafics are dismembered ophiolitic rocks that can be subdivided into serpentinites and serpentinized peridotites. Primary minerals such as olivine and pyroxene are absent in serpentinites, but relics of them occur in serpentinized peridotites. Pseudomorph after olivine is indicated by common hourglass textures with less mesh, whilst schistose bastites reflect a pyroxene pseudomorph. Chromite can be subdivided into Cr-spinel and Al-spinel. Cr-spinel ranges from chromite to magnesochromite in composition, whereas Al-spinel belongs to the spinel field. Cr-spinel includes YCr (Cr/(Cr+Al+Fe<sup>+3</sup>), YAl (Al/(Al+Cr+Fe<sup>+3</sup>), and YFe<sup>+3</sup> (Fe<sup>+3</sup><b>/</b>(Fe<sup>+3</sup>+Al+Cr), similar to forearc peridotite, whilst Al-spinel is more similar to abyssal peridotite, and may be formed during inanition of subduction processes in proto forearc environments. The main secondary minerals are tremolite, talc, and chlorite—which is subdivided into pycnochlorite and diabantite—and their temperature ranges from 174 to 224 °C. The examined rocks had undergone high partial melting degrees (>25%), as indicated by the Cr# of their unaltered cores (Cr-spinel, >0.6), whole rocks (Al<sub>2</sub>O<sub>3,</sub> SiO<sub>2</sub>, CaO, and MgO), trace and REEs, depleted Na<sub>2</sub>O, Al<sub>2</sub>O<sub>3</sub>, and Cr<sub>2</sub>O<sub>3</sub> of clinopyroxene, and high forsterite content ((Fo = 100 Mg/Mg + Fe), av. 95.23 mol%), consistent with forearc settings.El Saeed R. LasheenGehad M. SalehFarrage M. KhalealMamdooh AlwetaishiMDPI AGarticleserpentinizationelement mobilitypartial meltingforearc affinityTechnologyTEngineering (General). Civil engineering (General)TA1-2040Biology (General)QH301-705.5PhysicsQC1-999ChemistryQD1-999ENApplied Sciences, Vol 11, Iss 10524, p 10524 (2021)
institution DOAJ
collection DOAJ
language EN
topic serpentinization
element mobility
partial melting
forearc affinity
Technology
T
Engineering (General). Civil engineering (General)
TA1-2040
Biology (General)
QH301-705.5
Physics
QC1-999
Chemistry
QD1-999
spellingShingle serpentinization
element mobility
partial melting
forearc affinity
Technology
T
Engineering (General). Civil engineering (General)
TA1-2040
Biology (General)
QH301-705.5
Physics
QC1-999
Chemistry
QD1-999
El Saeed R. Lasheen
Gehad M. Saleh
Farrage M. Khaleal
Mamdooh Alwetaishi
Petrogenesis of Neoproterozoic Ultramafic Rocks, Wadi Ibib–Wadi Shani, South Eastern Desert, Egypt: Constraints from Whole Rock and Mineral Chemistry
description This contribution deals with new geology, petrography, and bulk-rock/mineral chemistry of the poorly studied ultramafics of Wadi Ibib–Wadi Shani (WI–WS) district, South Eastern Desert, Egypt. These ultramafics are dismembered ophiolitic rocks that can be subdivided into serpentinites and serpentinized peridotites. Primary minerals such as olivine and pyroxene are absent in serpentinites, but relics of them occur in serpentinized peridotites. Pseudomorph after olivine is indicated by common hourglass textures with less mesh, whilst schistose bastites reflect a pyroxene pseudomorph. Chromite can be subdivided into Cr-spinel and Al-spinel. Cr-spinel ranges from chromite to magnesochromite in composition, whereas Al-spinel belongs to the spinel field. Cr-spinel includes YCr (Cr/(Cr+Al+Fe<sup>+3</sup>), YAl (Al/(Al+Cr+Fe<sup>+3</sup>), and YFe<sup>+3</sup> (Fe<sup>+3</sup><b>/</b>(Fe<sup>+3</sup>+Al+Cr), similar to forearc peridotite, whilst Al-spinel is more similar to abyssal peridotite, and may be formed during inanition of subduction processes in proto forearc environments. The main secondary minerals are tremolite, talc, and chlorite—which is subdivided into pycnochlorite and diabantite—and their temperature ranges from 174 to 224 °C. The examined rocks had undergone high partial melting degrees (>25%), as indicated by the Cr# of their unaltered cores (Cr-spinel, >0.6), whole rocks (Al<sub>2</sub>O<sub>3,</sub> SiO<sub>2</sub>, CaO, and MgO), trace and REEs, depleted Na<sub>2</sub>O, Al<sub>2</sub>O<sub>3</sub>, and Cr<sub>2</sub>O<sub>3</sub> of clinopyroxene, and high forsterite content ((Fo = 100 Mg/Mg + Fe), av. 95.23 mol%), consistent with forearc settings.
format article
author El Saeed R. Lasheen
Gehad M. Saleh
Farrage M. Khaleal
Mamdooh Alwetaishi
author_facet El Saeed R. Lasheen
Gehad M. Saleh
Farrage M. Khaleal
Mamdooh Alwetaishi
author_sort El Saeed R. Lasheen
title Petrogenesis of Neoproterozoic Ultramafic Rocks, Wadi Ibib–Wadi Shani, South Eastern Desert, Egypt: Constraints from Whole Rock and Mineral Chemistry
title_short Petrogenesis of Neoproterozoic Ultramafic Rocks, Wadi Ibib–Wadi Shani, South Eastern Desert, Egypt: Constraints from Whole Rock and Mineral Chemistry
title_full Petrogenesis of Neoproterozoic Ultramafic Rocks, Wadi Ibib–Wadi Shani, South Eastern Desert, Egypt: Constraints from Whole Rock and Mineral Chemistry
title_fullStr Petrogenesis of Neoproterozoic Ultramafic Rocks, Wadi Ibib–Wadi Shani, South Eastern Desert, Egypt: Constraints from Whole Rock and Mineral Chemistry
title_full_unstemmed Petrogenesis of Neoproterozoic Ultramafic Rocks, Wadi Ibib–Wadi Shani, South Eastern Desert, Egypt: Constraints from Whole Rock and Mineral Chemistry
title_sort petrogenesis of neoproterozoic ultramafic rocks, wadi ibib–wadi shani, south eastern desert, egypt: constraints from whole rock and mineral chemistry
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/567973c1bead493191285341426aea0e
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