Concyclic CH-π arrays for single-axis rotations of a bowl in a tube

The weak and directional CH-π hydrogen bond has rarely been exploited in the design of supramolecular complexes and molecular machinery. Here, the authors construct a bowl-in-tube complex stabilized solely by concyclic CH-π hydrogen bonds, and show that the guest exhibits single-axis rotational moti...

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Autores principales:	Taisuke Matsuno, Masahiro Fujita, Kengo Fukunaga, Sota Sato, Hiroyuki Isobe
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/567ec1132dd348e492905951fb58e343
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spelling	oai:doaj.org-article:567ec1132dd348e492905951fb58e3432021-12-02T14:39:23ZConcyclic CH-π arrays for single-axis rotations of a bowl in a tube10.1038/s41467-018-06270-62041-1723https://doaj.org/article/567ec1132dd348e492905951fb58e3432018-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-06270-6https://doaj.org/toc/2041-1723The weak and directional CH-π hydrogen bond has rarely been exploited in the design of supramolecular complexes and molecular machinery. Here, the authors construct a bowl-in-tube complex stabilized solely by concyclic CH-π hydrogen bonds, and show that the guest exhibits single-axis rotational motion despite tight association with the host.Taisuke MatsunoMasahiro FujitaKengo FukunagaSota SatoHiroyuki IsobeNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Taisuke Matsuno Masahiro Fujita Kengo Fukunaga Sota Sato Hiroyuki Isobe Concyclic CH-π arrays for single-axis rotations of a bowl in a tube
description	The weak and directional CH-π hydrogen bond has rarely been exploited in the design of supramolecular complexes and molecular machinery. Here, the authors construct a bowl-in-tube complex stabilized solely by concyclic CH-π hydrogen bonds, and show that the guest exhibits single-axis rotational motion despite tight association with the host.
format	article
author	Taisuke Matsuno Masahiro Fujita Kengo Fukunaga Sota Sato Hiroyuki Isobe
author_facet	Taisuke Matsuno Masahiro Fujita Kengo Fukunaga Sota Sato Hiroyuki Isobe
author_sort	Taisuke Matsuno
title	Concyclic CH-π arrays for single-axis rotations of a bowl in a tube
title_short	Concyclic CH-π arrays for single-axis rotations of a bowl in a tube
title_full	Concyclic CH-π arrays for single-axis rotations of a bowl in a tube
title_fullStr	Concyclic CH-π arrays for single-axis rotations of a bowl in a tube
title_full_unstemmed	Concyclic CH-π arrays for single-axis rotations of a bowl in a tube
title_sort	concyclic ch-π arrays for single-axis rotations of a bowl in a tube
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/567ec1132dd348e492905951fb58e343
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_version_	1718390654831165440

Concyclic CH-π arrays for single-axis rotations of a bowl in a tube

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