Kinetic Study of Esterification Reaction

The Esterification kinetics of acetic acid with ethanol in the presence of sulfuric acid as a homogenous catalyst was studied with isothermal batch experiments at 50-60°C and at a different molar ratio of ethanol to acetic acid [EtOH/Ac]. Investigation of kinetics of the reaction indicated that the...

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Autores principales:	Haider A. Al-Jendeel, Maha H. Al-Hassani, Nada S. Ahmed Zeki
Formato:	article
Lenguaje:	EN
Publicado:	Al-Khwarizmi College of Engineering – University of Baghdad 2010
Materias:	Esterification ethyl acetate acetic acid kinetics non-ideal systems Chemical engineering TP155-156 Engineering (General). Civil engineering (General) TA1-2040
Acceso en línea:	https://doaj.org/article/568218ddd60b428eb01ea4123948d546
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spelling	oai:doaj.org-article:568218ddd60b428eb01ea4123948d5462021-12-02T09:48:44ZKinetic Study of Esterification Reaction1818-1171https://doaj.org/article/568218ddd60b428eb01ea4123948d5462010-01-01T00:00:00Zhttp://www.iasj.net/iasj?func=fulltext&aId=2335https://doaj.org/toc/1818-1171The Esterification kinetics of acetic acid with ethanol in the presence of sulfuric acid as a homogenous catalyst was studied with isothermal batch experiments at 50-60°C and at a different molar ratio of ethanol to acetic acid [EtOH/Ac]. Investigation of kinetics of the reaction indicated that the low of [EtOH/Ac] molar ratio is favored for esterification reaction, this is due to the reaction is catalyzed by acid. The maximum conversion, approximately 80% was obtained at 60°C for molar ratio of 10 EtOH/Ac. It was found that increasing temperature of the reaction, increases the rate constant and conversion at a certain mole ratio, that is due to the esterification is exothermic. Activity coefficients were calculated using UNIFAC program. Results showed deviation in activation energy in the non-ideal system of about 20% this is due to the polarities of water and ethanol compared to the non-polar ethyl acetate this dissimilarity leading to strong non- ideal behavior. The homogenous reaction has been described with simple power-law model. The chemical equilibrium combustion calculated form the kinetic model in agreement with the measured chemical equilibrium. Haider A. Al-JendeelMaha H. Al-HassaniNada S. Ahmed ZekiAl-Khwarizmi College of Engineering – University of BaghdadarticleEsterificationethyl acetateacetic acidkineticsnon-ideal systemsChemical engineeringTP155-156Engineering (General). Civil engineering (General)TA1-2040ENAl-Khawarizmi Engineering Journal, Vol 6, Iss 2, Pp 33-42 (2010)
institution	DOAJ
collection	DOAJ
language	EN
topic	Esterification ethyl acetate acetic acid kinetics non-ideal systems Chemical engineering TP155-156 Engineering (General). Civil engineering (General) TA1-2040
spellingShingle	Esterification ethyl acetate acetic acid kinetics non-ideal systems Chemical engineering TP155-156 Engineering (General). Civil engineering (General) TA1-2040 Haider A. Al-Jendeel Maha H. Al-Hassani Nada S. Ahmed Zeki Kinetic Study of Esterification Reaction
description	The Esterification kinetics of acetic acid with ethanol in the presence of sulfuric acid as a homogenous catalyst was studied with isothermal batch experiments at 50-60°C and at a different molar ratio of ethanol to acetic acid [EtOH/Ac]. Investigation of kinetics of the reaction indicated that the low of [EtOH/Ac] molar ratio is favored for esterification reaction, this is due to the reaction is catalyzed by acid. The maximum conversion, approximately 80% was obtained at 60°C for molar ratio of 10 EtOH/Ac. It was found that increasing temperature of the reaction, increases the rate constant and conversion at a certain mole ratio, that is due to the esterification is exothermic. Activity coefficients were calculated using UNIFAC program. Results showed deviation in activation energy in the non-ideal system of about 20% this is due to the polarities of water and ethanol compared to the non-polar ethyl acetate this dissimilarity leading to strong non- ideal behavior. The homogenous reaction has been described with simple power-law model. The chemical equilibrium combustion calculated form the kinetic model in agreement with the measured chemical equilibrium.
format	article
author	Haider A. Al-Jendeel Maha H. Al-Hassani Nada S. Ahmed Zeki
author_facet	Haider A. Al-Jendeel Maha H. Al-Hassani Nada S. Ahmed Zeki
author_sort	Haider A. Al-Jendeel
title	Kinetic Study of Esterification Reaction
title_short	Kinetic Study of Esterification Reaction
title_full	Kinetic Study of Esterification Reaction
title_fullStr	Kinetic Study of Esterification Reaction
title_full_unstemmed	Kinetic Study of Esterification Reaction
title_sort	kinetic study of esterification reaction
publisher	Al-Khwarizmi College of Engineering – University of Baghdad
publishDate	2010
url	https://doaj.org/article/568218ddd60b428eb01ea4123948d546
work_keys_str_mv	AT haideraaljendeel kineticstudyofesterificationreaction AT mahahalhassani kineticstudyofesterificationreaction AT nadasahmedzeki kineticstudyofesterificationreaction
_version_	1718398004842463232

Kinetic Study of Esterification Reaction

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