Lewis acid-catalyzed asymmetric reactions of β,γ-unsaturated 2-acyl imidazoles

The investigation of reactivity of β,γ-unsaturated carbonyl compounds is of great synthetic value, especially in asymmetric transformations. Here, the authors report a catalytic asymmetric tandem isomerization/α-Michael addition of β,γ-unsaturated 2-acyl imidazoles in presence of chiral N,N′-dioxide...

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Autores principales:	Tengfei Kang, Liuzhen Hou, Sai Ruan, Weidi Cao, Xiaohua Liu, Xiaoming Feng
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/56eef85e6c18451bb5c7eefe77199ce3
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spelling	oai:doaj.org-article:56eef85e6c18451bb5c7eefe77199ce32021-12-02T14:53:51ZLewis acid-catalyzed asymmetric reactions of β,γ-unsaturated 2-acyl imidazoles10.1038/s41467-020-17681-92041-1723https://doaj.org/article/56eef85e6c18451bb5c7eefe77199ce32020-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-17681-9https://doaj.org/toc/2041-1723The investigation of reactivity of β,γ-unsaturated carbonyl compounds is of great synthetic value, especially in asymmetric transformations. Here, the authors report a catalytic asymmetric tandem isomerization/α-Michael addition of β,γ-unsaturated 2-acyl imidazoles in presence of chiral N,N′-dioxide metal catalysts.Tengfei KangLiuzhen HouSai RuanWeidi CaoXiaohua LiuXiaoming FengNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-10 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Tengfei Kang Liuzhen Hou Sai Ruan Weidi Cao Xiaohua Liu Xiaoming Feng Lewis acid-catalyzed asymmetric reactions of β,γ-unsaturated 2-acyl imidazoles
description	The investigation of reactivity of β,γ-unsaturated carbonyl compounds is of great synthetic value, especially in asymmetric transformations. Here, the authors report a catalytic asymmetric tandem isomerization/α-Michael addition of β,γ-unsaturated 2-acyl imidazoles in presence of chiral N,N′-dioxide metal catalysts.
format	article
author	Tengfei Kang Liuzhen Hou Sai Ruan Weidi Cao Xiaohua Liu Xiaoming Feng
author_facet	Tengfei Kang Liuzhen Hou Sai Ruan Weidi Cao Xiaohua Liu Xiaoming Feng
author_sort	Tengfei Kang
title	Lewis acid-catalyzed asymmetric reactions of β,γ-unsaturated 2-acyl imidazoles
title_short	Lewis acid-catalyzed asymmetric reactions of β,γ-unsaturated 2-acyl imidazoles
title_full	Lewis acid-catalyzed asymmetric reactions of β,γ-unsaturated 2-acyl imidazoles
title_fullStr	Lewis acid-catalyzed asymmetric reactions of β,γ-unsaturated 2-acyl imidazoles
title_full_unstemmed	Lewis acid-catalyzed asymmetric reactions of β,γ-unsaturated 2-acyl imidazoles
title_sort	lewis acid-catalyzed asymmetric reactions of β,γ-unsaturated 2-acyl imidazoles
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/56eef85e6c18451bb5c7eefe77199ce3
work_keys_str_mv	AT tengfeikang lewisacidcatalyzedasymmetricreactionsofbgunsaturated2acylimidazoles AT liuzhenhou lewisacidcatalyzedasymmetricreactionsofbgunsaturated2acylimidazoles AT sairuan lewisacidcatalyzedasymmetricreactionsofbgunsaturated2acylimidazoles AT weidicao lewisacidcatalyzedasymmetricreactionsofbgunsaturated2acylimidazoles AT xiaohualiu lewisacidcatalyzedasymmetricreactionsofbgunsaturated2acylimidazoles AT xiaomingfeng lewisacidcatalyzedasymmetricreactionsofbgunsaturated2acylimidazoles
_version_	1718389384206614528

Lewis acid-catalyzed asymmetric reactions of β,γ-unsaturated 2-acyl imidazoles

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