Peroxymonosulfate Activation by Bi<sub>2</sub>WO<sub>6</sub>/BiOCl Heterojunction Nanocomposites under Visible Light for Bisphenol A Degradation

The combination of peroxymonosulfate (PMS) activation and photocatalysis has proven to be effective for organic contaminants treatment. However, the construction of an efficient catalytic material is an important challenge. Herein, novel Bi<sub>2</sub>WO<sub>6</sub>/BiOCl het...

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Autores principales: Yongkui Huang, Xiangyang Yin, Pei He, Shuangwu Kou, Xiaoting Zhang, Lei Wang, Peili Lu
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Lenguaje:EN
Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:57045b2bf23b4d339bf2de0c4c8fb2862021-11-25T18:32:41ZPeroxymonosulfate Activation by Bi<sub>2</sub>WO<sub>6</sub>/BiOCl Heterojunction Nanocomposites under Visible Light for Bisphenol A Degradation10.3390/nano111131302079-4991https://doaj.org/article/57045b2bf23b4d339bf2de0c4c8fb2862021-11-01T00:00:00Zhttps://www.mdpi.com/2079-4991/11/11/3130https://doaj.org/toc/2079-4991The combination of peroxymonosulfate (PMS) activation and photocatalysis has proven to be effective for organic contaminants treatment. However, the construction of an efficient catalytic material is an important challenge. Herein, novel Bi<sub>2</sub>WO<sub>6</sub>/BiOCl heterojunction nanocomposites were successfully designed and fabricated using a facile and effective strategy for bisphenol A (BPA) photodegradation with PMS activation. The well-designed heterojunction with improvement of the contact area and interface microstructure was obtained through in situ growth of the Bi<sub>2</sub>WO<sub>6</sub> on the surface of BiOCl. The Bi<sub>2</sub>WO<sub>6</sub>/BiOCl nanocomposites exhibit excellent catalytic performance in PMS activation for BPA degradation under visible light irradiation. A possible photocatalytic reaction mechanism was systematically revealed. The excellent catalytic performance is mainly attributed to the strong interaction between Bi<sub>2</sub>WO<sub>6</sub> and BiOCl, resulting in an enhanced photoabsorption and a more efficient interfacial charge separation and transfer. This paper provides a novel strategy to design efficient catalytic materials for organic contaminants remediation with PMS activation.Yongkui HuangXiangyang YinPei HeShuangwu KouXiaoting ZhangLei WangPeili LuMDPI AGarticleperoxymonosulfateBiOClBi<sub>2</sub>WO<sub>6</sub>photocatalysisorganic contaminantChemistryQD1-999ENNanomaterials, Vol 11, Iss 3130, p 3130 (2021)
institution DOAJ
collection DOAJ
language EN
topic peroxymonosulfate
BiOCl
Bi<sub>2</sub>WO<sub>6</sub>
photocatalysis
organic contaminant
Chemistry
QD1-999
spellingShingle peroxymonosulfate
BiOCl
Bi<sub>2</sub>WO<sub>6</sub>
photocatalysis
organic contaminant
Chemistry
QD1-999
Yongkui Huang
Xiangyang Yin
Pei He
Shuangwu Kou
Xiaoting Zhang
Lei Wang
Peili Lu
Peroxymonosulfate Activation by Bi<sub>2</sub>WO<sub>6</sub>/BiOCl Heterojunction Nanocomposites under Visible Light for Bisphenol A Degradation
description The combination of peroxymonosulfate (PMS) activation and photocatalysis has proven to be effective for organic contaminants treatment. However, the construction of an efficient catalytic material is an important challenge. Herein, novel Bi<sub>2</sub>WO<sub>6</sub>/BiOCl heterojunction nanocomposites were successfully designed and fabricated using a facile and effective strategy for bisphenol A (BPA) photodegradation with PMS activation. The well-designed heterojunction with improvement of the contact area and interface microstructure was obtained through in situ growth of the Bi<sub>2</sub>WO<sub>6</sub> on the surface of BiOCl. The Bi<sub>2</sub>WO<sub>6</sub>/BiOCl nanocomposites exhibit excellent catalytic performance in PMS activation for BPA degradation under visible light irradiation. A possible photocatalytic reaction mechanism was systematically revealed. The excellent catalytic performance is mainly attributed to the strong interaction between Bi<sub>2</sub>WO<sub>6</sub> and BiOCl, resulting in an enhanced photoabsorption and a more efficient interfacial charge separation and transfer. This paper provides a novel strategy to design efficient catalytic materials for organic contaminants remediation with PMS activation.
format article
author Yongkui Huang
Xiangyang Yin
Pei He
Shuangwu Kou
Xiaoting Zhang
Lei Wang
Peili Lu
author_facet Yongkui Huang
Xiangyang Yin
Pei He
Shuangwu Kou
Xiaoting Zhang
Lei Wang
Peili Lu
author_sort Yongkui Huang
title Peroxymonosulfate Activation by Bi<sub>2</sub>WO<sub>6</sub>/BiOCl Heterojunction Nanocomposites under Visible Light for Bisphenol A Degradation
title_short Peroxymonosulfate Activation by Bi<sub>2</sub>WO<sub>6</sub>/BiOCl Heterojunction Nanocomposites under Visible Light for Bisphenol A Degradation
title_full Peroxymonosulfate Activation by Bi<sub>2</sub>WO<sub>6</sub>/BiOCl Heterojunction Nanocomposites under Visible Light for Bisphenol A Degradation
title_fullStr Peroxymonosulfate Activation by Bi<sub>2</sub>WO<sub>6</sub>/BiOCl Heterojunction Nanocomposites under Visible Light for Bisphenol A Degradation
title_full_unstemmed Peroxymonosulfate Activation by Bi<sub>2</sub>WO<sub>6</sub>/BiOCl Heterojunction Nanocomposites under Visible Light for Bisphenol A Degradation
title_sort peroxymonosulfate activation by bi<sub>2</sub>wo<sub>6</sub>/biocl heterojunction nanocomposites under visible light for bisphenol a degradation
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/57045b2bf23b4d339bf2de0c4c8fb286
work_keys_str_mv AT yongkuihuang peroxymonosulfateactivationbybisub2subwosub6subbioclheterojunctionnanocompositesundervisiblelightforbisphenoladegradation
AT xiangyangyin peroxymonosulfateactivationbybisub2subwosub6subbioclheterojunctionnanocompositesundervisiblelightforbisphenoladegradation
AT peihe peroxymonosulfateactivationbybisub2subwosub6subbioclheterojunctionnanocompositesundervisiblelightforbisphenoladegradation
AT shuangwukou peroxymonosulfateactivationbybisub2subwosub6subbioclheterojunctionnanocompositesundervisiblelightforbisphenoladegradation
AT xiaotingzhang peroxymonosulfateactivationbybisub2subwosub6subbioclheterojunctionnanocompositesundervisiblelightforbisphenoladegradation
AT leiwang peroxymonosulfateactivationbybisub2subwosub6subbioclheterojunctionnanocompositesundervisiblelightforbisphenoladegradation
AT peililu peroxymonosulfateactivationbybisub2subwosub6subbioclheterojunctionnanocompositesundervisiblelightforbisphenoladegradation
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