Peroxymonosulfate Activation by Bi<sub>2</sub>WO<sub>6</sub>/BiOCl Heterojunction Nanocomposites under Visible Light for Bisphenol A Degradation
The combination of peroxymonosulfate (PMS) activation and photocatalysis has proven to be effective for organic contaminants treatment. However, the construction of an efficient catalytic material is an important challenge. Herein, novel Bi<sub>2</sub>WO<sub>6</sub>/BiOCl het...
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MDPI AG
2021
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oai:doaj.org-article:57045b2bf23b4d339bf2de0c4c8fb2862021-11-25T18:32:41ZPeroxymonosulfate Activation by Bi<sub>2</sub>WO<sub>6</sub>/BiOCl Heterojunction Nanocomposites under Visible Light for Bisphenol A Degradation10.3390/nano111131302079-4991https://doaj.org/article/57045b2bf23b4d339bf2de0c4c8fb2862021-11-01T00:00:00Zhttps://www.mdpi.com/2079-4991/11/11/3130https://doaj.org/toc/2079-4991The combination of peroxymonosulfate (PMS) activation and photocatalysis has proven to be effective for organic contaminants treatment. However, the construction of an efficient catalytic material is an important challenge. Herein, novel Bi<sub>2</sub>WO<sub>6</sub>/BiOCl heterojunction nanocomposites were successfully designed and fabricated using a facile and effective strategy for bisphenol A (BPA) photodegradation with PMS activation. The well-designed heterojunction with improvement of the contact area and interface microstructure was obtained through in situ growth of the Bi<sub>2</sub>WO<sub>6</sub> on the surface of BiOCl. The Bi<sub>2</sub>WO<sub>6</sub>/BiOCl nanocomposites exhibit excellent catalytic performance in PMS activation for BPA degradation under visible light irradiation. A possible photocatalytic reaction mechanism was systematically revealed. The excellent catalytic performance is mainly attributed to the strong interaction between Bi<sub>2</sub>WO<sub>6</sub> and BiOCl, resulting in an enhanced photoabsorption and a more efficient interfacial charge separation and transfer. This paper provides a novel strategy to design efficient catalytic materials for organic contaminants remediation with PMS activation.Yongkui HuangXiangyang YinPei HeShuangwu KouXiaoting ZhangLei WangPeili LuMDPI AGarticleperoxymonosulfateBiOClBi<sub>2</sub>WO<sub>6</sub>photocatalysisorganic contaminantChemistryQD1-999ENNanomaterials, Vol 11, Iss 3130, p 3130 (2021) |
institution |
DOAJ |
collection |
DOAJ |
language |
EN |
topic |
peroxymonosulfate BiOCl Bi<sub>2</sub>WO<sub>6</sub> photocatalysis organic contaminant Chemistry QD1-999 |
spellingShingle |
peroxymonosulfate BiOCl Bi<sub>2</sub>WO<sub>6</sub> photocatalysis organic contaminant Chemistry QD1-999 Yongkui Huang Xiangyang Yin Pei He Shuangwu Kou Xiaoting Zhang Lei Wang Peili Lu Peroxymonosulfate Activation by Bi<sub>2</sub>WO<sub>6</sub>/BiOCl Heterojunction Nanocomposites under Visible Light for Bisphenol A Degradation |
description |
The combination of peroxymonosulfate (PMS) activation and photocatalysis has proven to be effective for organic contaminants treatment. However, the construction of an efficient catalytic material is an important challenge. Herein, novel Bi<sub>2</sub>WO<sub>6</sub>/BiOCl heterojunction nanocomposites were successfully designed and fabricated using a facile and effective strategy for bisphenol A (BPA) photodegradation with PMS activation. The well-designed heterojunction with improvement of the contact area and interface microstructure was obtained through in situ growth of the Bi<sub>2</sub>WO<sub>6</sub> on the surface of BiOCl. The Bi<sub>2</sub>WO<sub>6</sub>/BiOCl nanocomposites exhibit excellent catalytic performance in PMS activation for BPA degradation under visible light irradiation. A possible photocatalytic reaction mechanism was systematically revealed. The excellent catalytic performance is mainly attributed to the strong interaction between Bi<sub>2</sub>WO<sub>6</sub> and BiOCl, resulting in an enhanced photoabsorption and a more efficient interfacial charge separation and transfer. This paper provides a novel strategy to design efficient catalytic materials for organic contaminants remediation with PMS activation. |
format |
article |
author |
Yongkui Huang Xiangyang Yin Pei He Shuangwu Kou Xiaoting Zhang Lei Wang Peili Lu |
author_facet |
Yongkui Huang Xiangyang Yin Pei He Shuangwu Kou Xiaoting Zhang Lei Wang Peili Lu |
author_sort |
Yongkui Huang |
title |
Peroxymonosulfate Activation by Bi<sub>2</sub>WO<sub>6</sub>/BiOCl Heterojunction Nanocomposites under Visible Light for Bisphenol A Degradation |
title_short |
Peroxymonosulfate Activation by Bi<sub>2</sub>WO<sub>6</sub>/BiOCl Heterojunction Nanocomposites under Visible Light for Bisphenol A Degradation |
title_full |
Peroxymonosulfate Activation by Bi<sub>2</sub>WO<sub>6</sub>/BiOCl Heterojunction Nanocomposites under Visible Light for Bisphenol A Degradation |
title_fullStr |
Peroxymonosulfate Activation by Bi<sub>2</sub>WO<sub>6</sub>/BiOCl Heterojunction Nanocomposites under Visible Light for Bisphenol A Degradation |
title_full_unstemmed |
Peroxymonosulfate Activation by Bi<sub>2</sub>WO<sub>6</sub>/BiOCl Heterojunction Nanocomposites under Visible Light for Bisphenol A Degradation |
title_sort |
peroxymonosulfate activation by bi<sub>2</sub>wo<sub>6</sub>/biocl heterojunction nanocomposites under visible light for bisphenol a degradation |
publisher |
MDPI AG |
publishDate |
2021 |
url |
https://doaj.org/article/57045b2bf23b4d339bf2de0c4c8fb286 |
work_keys_str_mv |
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1718411016751022080 |