Transient metal-centered states mediate isomerization of a photochromic ruthenium-sulfoxide complex

An essential open question in functional transition metal complexes is the relative roles of charge-transfer and metal-centered excited states. Here the authors identify the important role of metal-centered excited states in the linkage photoisomerization of a photochromic Ru-sulfoxide complex.

Guardado en:
Detalles Bibliográficos
Autores principales: Amy A. Cordones, Jae Hyuk Lee, Kiryong Hong, Hana Cho, Komal Garg, Martial Boggio-Pasqua, Jeffrey J. Rack, Nils Huse, Robert W. Schoenlein, Tae Kyu Kim
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
Materias:
Q
Acceso en línea:https://doaj.org/article/5731d4b61cda4b98bf6ab4e0e3b835b2
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
id oai:doaj.org-article:5731d4b61cda4b98bf6ab4e0e3b835b2
record_format dspace
spelling oai:doaj.org-article:5731d4b61cda4b98bf6ab4e0e3b835b22021-12-02T17:32:47ZTransient metal-centered states mediate isomerization of a photochromic ruthenium-sulfoxide complex10.1038/s41467-018-04351-02041-1723https://doaj.org/article/5731d4b61cda4b98bf6ab4e0e3b835b22018-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-04351-0https://doaj.org/toc/2041-1723An essential open question in functional transition metal complexes is the relative roles of charge-transfer and metal-centered excited states. Here the authors identify the important role of metal-centered excited states in the linkage photoisomerization of a photochromic Ru-sulfoxide complex.Amy A. CordonesJae Hyuk LeeKiryong HongHana ChoKomal GargMartial Boggio-PasquaJeffrey J. RackNils HuseRobert W. SchoenleinTae Kyu KimNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-9 (2018)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Amy A. Cordones
Jae Hyuk Lee
Kiryong Hong
Hana Cho
Komal Garg
Martial Boggio-Pasqua
Jeffrey J. Rack
Nils Huse
Robert W. Schoenlein
Tae Kyu Kim
Transient metal-centered states mediate isomerization of a photochromic ruthenium-sulfoxide complex
description An essential open question in functional transition metal complexes is the relative roles of charge-transfer and metal-centered excited states. Here the authors identify the important role of metal-centered excited states in the linkage photoisomerization of a photochromic Ru-sulfoxide complex.
format article
author Amy A. Cordones
Jae Hyuk Lee
Kiryong Hong
Hana Cho
Komal Garg
Martial Boggio-Pasqua
Jeffrey J. Rack
Nils Huse
Robert W. Schoenlein
Tae Kyu Kim
author_facet Amy A. Cordones
Jae Hyuk Lee
Kiryong Hong
Hana Cho
Komal Garg
Martial Boggio-Pasqua
Jeffrey J. Rack
Nils Huse
Robert W. Schoenlein
Tae Kyu Kim
author_sort Amy A. Cordones
title Transient metal-centered states mediate isomerization of a photochromic ruthenium-sulfoxide complex
title_short Transient metal-centered states mediate isomerization of a photochromic ruthenium-sulfoxide complex
title_full Transient metal-centered states mediate isomerization of a photochromic ruthenium-sulfoxide complex
title_fullStr Transient metal-centered states mediate isomerization of a photochromic ruthenium-sulfoxide complex
title_full_unstemmed Transient metal-centered states mediate isomerization of a photochromic ruthenium-sulfoxide complex
title_sort transient metal-centered states mediate isomerization of a photochromic ruthenium-sulfoxide complex
publisher Nature Portfolio
publishDate 2018
url https://doaj.org/article/5731d4b61cda4b98bf6ab4e0e3b835b2
work_keys_str_mv AT amyacordones transientmetalcenteredstatesmediateisomerizationofaphotochromicrutheniumsulfoxidecomplex
AT jaehyuklee transientmetalcenteredstatesmediateisomerizationofaphotochromicrutheniumsulfoxidecomplex
AT kiryonghong transientmetalcenteredstatesmediateisomerizationofaphotochromicrutheniumsulfoxidecomplex
AT hanacho transientmetalcenteredstatesmediateisomerizationofaphotochromicrutheniumsulfoxidecomplex
AT komalgarg transientmetalcenteredstatesmediateisomerizationofaphotochromicrutheniumsulfoxidecomplex
AT martialboggiopasqua transientmetalcenteredstatesmediateisomerizationofaphotochromicrutheniumsulfoxidecomplex
AT jeffreyjrack transientmetalcenteredstatesmediateisomerizationofaphotochromicrutheniumsulfoxidecomplex
AT nilshuse transientmetalcenteredstatesmediateisomerizationofaphotochromicrutheniumsulfoxidecomplex
AT robertwschoenlein transientmetalcenteredstatesmediateisomerizationofaphotochromicrutheniumsulfoxidecomplex
AT taekyukim transientmetalcenteredstatesmediateisomerizationofaphotochromicrutheniumsulfoxidecomplex
_version_ 1718380186052853760