Transient metal-centered states mediate isomerization of a photochromic ruthenium-sulfoxide complex
An essential open question in functional transition metal complexes is the relative roles of charge-transfer and metal-centered excited states. Here the authors identify the important role of metal-centered excited states in the linkage photoisomerization of a photochromic Ru-sulfoxide complex.
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Nature Portfolio
2018
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oai:doaj.org-article:5731d4b61cda4b98bf6ab4e0e3b835b22021-12-02T17:32:47ZTransient metal-centered states mediate isomerization of a photochromic ruthenium-sulfoxide complex10.1038/s41467-018-04351-02041-1723https://doaj.org/article/5731d4b61cda4b98bf6ab4e0e3b835b22018-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-04351-0https://doaj.org/toc/2041-1723An essential open question in functional transition metal complexes is the relative roles of charge-transfer and metal-centered excited states. Here the authors identify the important role of metal-centered excited states in the linkage photoisomerization of a photochromic Ru-sulfoxide complex.Amy A. CordonesJae Hyuk LeeKiryong HongHana ChoKomal GargMartial Boggio-PasquaJeffrey J. RackNils HuseRobert W. SchoenleinTae Kyu KimNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-9 (2018) |
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Science Q Amy A. Cordones Jae Hyuk Lee Kiryong Hong Hana Cho Komal Garg Martial Boggio-Pasqua Jeffrey J. Rack Nils Huse Robert W. Schoenlein Tae Kyu Kim Transient metal-centered states mediate isomerization of a photochromic ruthenium-sulfoxide complex |
description |
An essential open question in functional transition metal complexes is the relative roles of charge-transfer and metal-centered excited states. Here the authors identify the important role of metal-centered excited states in the linkage photoisomerization of a photochromic Ru-sulfoxide complex. |
format |
article |
author |
Amy A. Cordones Jae Hyuk Lee Kiryong Hong Hana Cho Komal Garg Martial Boggio-Pasqua Jeffrey J. Rack Nils Huse Robert W. Schoenlein Tae Kyu Kim |
author_facet |
Amy A. Cordones Jae Hyuk Lee Kiryong Hong Hana Cho Komal Garg Martial Boggio-Pasqua Jeffrey J. Rack Nils Huse Robert W. Schoenlein Tae Kyu Kim |
author_sort |
Amy A. Cordones |
title |
Transient metal-centered states mediate isomerization of a photochromic ruthenium-sulfoxide complex |
title_short |
Transient metal-centered states mediate isomerization of a photochromic ruthenium-sulfoxide complex |
title_full |
Transient metal-centered states mediate isomerization of a photochromic ruthenium-sulfoxide complex |
title_fullStr |
Transient metal-centered states mediate isomerization of a photochromic ruthenium-sulfoxide complex |
title_full_unstemmed |
Transient metal-centered states mediate isomerization of a photochromic ruthenium-sulfoxide complex |
title_sort |
transient metal-centered states mediate isomerization of a photochromic ruthenium-sulfoxide complex |
publisher |
Nature Portfolio |
publishDate |
2018 |
url |
https://doaj.org/article/5731d4b61cda4b98bf6ab4e0e3b835b2 |
work_keys_str_mv |
AT amyacordones transientmetalcenteredstatesmediateisomerizationofaphotochromicrutheniumsulfoxidecomplex AT jaehyuklee transientmetalcenteredstatesmediateisomerizationofaphotochromicrutheniumsulfoxidecomplex AT kiryonghong transientmetalcenteredstatesmediateisomerizationofaphotochromicrutheniumsulfoxidecomplex AT hanacho transientmetalcenteredstatesmediateisomerizationofaphotochromicrutheniumsulfoxidecomplex AT komalgarg transientmetalcenteredstatesmediateisomerizationofaphotochromicrutheniumsulfoxidecomplex AT martialboggiopasqua transientmetalcenteredstatesmediateisomerizationofaphotochromicrutheniumsulfoxidecomplex AT jeffreyjrack transientmetalcenteredstatesmediateisomerizationofaphotochromicrutheniumsulfoxidecomplex AT nilshuse transientmetalcenteredstatesmediateisomerizationofaphotochromicrutheniumsulfoxidecomplex AT robertwschoenlein transientmetalcenteredstatesmediateisomerizationofaphotochromicrutheniumsulfoxidecomplex AT taekyukim transientmetalcenteredstatesmediateisomerizationofaphotochromicrutheniumsulfoxidecomplex |
_version_ |
1718380186052853760 |