Homo- and heterodehydrocoupling of phosphines mediated by alkali metal catalysts
Catalytic transformations involving main group compounds is much less developed than carbon chemistry. Here, the authors report the use of catalytic or stoichiometric tBuOK in presence of a hydrogen acceptor for efficient P–P and P–heteroatom coupling reactions.
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Nature Portfolio
2019
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oai:doaj.org-article:57d392328313400593b7d219507eb1e42021-12-02T14:38:40ZHomo- and heterodehydrocoupling of phosphines mediated by alkali metal catalysts10.1038/s41467-019-09832-42041-1723https://doaj.org/article/57d392328313400593b7d219507eb1e42019-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-09832-4https://doaj.org/toc/2041-1723Catalytic transformations involving main group compounds is much less developed than carbon chemistry. Here, the authors report the use of catalytic or stoichiometric tBuOK in presence of a hydrogen acceptor for efficient P–P and P–heteroatom coupling reactions.Lipeng WuVincent T. AnnibaleHaijun JiaoAdam BrookfieldDavid CollisonIan MannersNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-10 (2019) |
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Science Q Lipeng Wu Vincent T. Annibale Haijun Jiao Adam Brookfield David Collison Ian Manners Homo- and heterodehydrocoupling of phosphines mediated by alkali metal catalysts |
description |
Catalytic transformations involving main group compounds is much less developed than carbon chemistry. Here, the authors report the use of catalytic or stoichiometric tBuOK in presence of a hydrogen acceptor for efficient P–P and P–heteroatom coupling reactions. |
format |
article |
author |
Lipeng Wu Vincent T. Annibale Haijun Jiao Adam Brookfield David Collison Ian Manners |
author_facet |
Lipeng Wu Vincent T. Annibale Haijun Jiao Adam Brookfield David Collison Ian Manners |
author_sort |
Lipeng Wu |
title |
Homo- and heterodehydrocoupling of phosphines mediated by alkali metal catalysts |
title_short |
Homo- and heterodehydrocoupling of phosphines mediated by alkali metal catalysts |
title_full |
Homo- and heterodehydrocoupling of phosphines mediated by alkali metal catalysts |
title_fullStr |
Homo- and heterodehydrocoupling of phosphines mediated by alkali metal catalysts |
title_full_unstemmed |
Homo- and heterodehydrocoupling of phosphines mediated by alkali metal catalysts |
title_sort |
homo- and heterodehydrocoupling of phosphines mediated by alkali metal catalysts |
publisher |
Nature Portfolio |
publishDate |
2019 |
url |
https://doaj.org/article/57d392328313400593b7d219507eb1e4 |
work_keys_str_mv |
AT lipengwu homoandheterodehydrocouplingofphosphinesmediatedbyalkalimetalcatalysts AT vincenttannibale homoandheterodehydrocouplingofphosphinesmediatedbyalkalimetalcatalysts AT haijunjiao homoandheterodehydrocouplingofphosphinesmediatedbyalkalimetalcatalysts AT adambrookfield homoandheterodehydrocouplingofphosphinesmediatedbyalkalimetalcatalysts AT davidcollison homoandheterodehydrocouplingofphosphinesmediatedbyalkalimetalcatalysts AT ianmanners homoandheterodehydrocouplingofphosphinesmediatedbyalkalimetalcatalysts |
_version_ |
1718390895755132928 |