The Effect of Ethanol on Abnormal Grain Growth in Copper Foils

Single-crystal Cu not only has high electrical and thermal conductivity, but can also be used as a promising platform for the epitaxial growth of two-dimensional materials. Preparing large-area single-crystal Cu foils from polycrystalline foils has emerged as the most promising technique in terms of...

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Autores principales: Zhancheng Li, Yongna Zhang, Yinwu Duan, Deping Huang, Haofei Shi
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Lenguaje:EN
Publicado: MDPI AG 2021
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Acceso en línea:https://doaj.org/article/57dcdc6bae454d66a18cdba9002fda23
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spelling oai:doaj.org-article:57dcdc6bae454d66a18cdba9002fda232021-11-25T18:32:12ZThe Effect of Ethanol on Abnormal Grain Growth in Copper Foils10.3390/nano111130692079-4991https://doaj.org/article/57dcdc6bae454d66a18cdba9002fda232021-11-01T00:00:00Zhttps://www.mdpi.com/2079-4991/11/11/3069https://doaj.org/toc/2079-4991Single-crystal Cu not only has high electrical and thermal conductivity, but can also be used as a promising platform for the epitaxial growth of two-dimensional materials. Preparing large-area single-crystal Cu foils from polycrystalline foils has emerged as the most promising technique in terms of its simplicity and effectiveness. However, the studies on transforming polycrystalline foil into large-area single-crystal foil mainly focus on the influence of annealing temperature and strain energy on the recrystallization process of copper foil, while studies on the effect of annealing atmosphere on abnormal grain growth behavior are relatively rare. It is necessary to carry out more studies on the effect of annealing atmosphere on grain growth behavior to understand the recrystallization mechanism of metal. Here, we found that introduction of ethanol in pure argon annealing atmosphere will cause the abnormal grain growth of copper foil. Moreover, the number of abnormally grown grains can be controlled by the concentration of ethanol in the annealing atmosphere. Using this technology, the number of abnormally grown grains on the copper foil can be controlled to single one. This abnormally grown grain will grow rapidly to decimeter-size by consuming the surrounding small grains. This work provides a new perspective for the understanding of the recrystallization of metals, and a new method for the preparation of large-area single-crystal copper foils.Zhancheng LiYongna ZhangYinwu DuanDeping HuangHaofei ShiMDPI AGarticleabnormal grain growndecimeter-size grainsethanol annealing atmosphererecrystallization of copper foilscontact-free annealingChemistryQD1-999ENNanomaterials, Vol 11, Iss 3069, p 3069 (2021)
institution DOAJ
collection DOAJ
language EN
topic abnormal grain grown
decimeter-size grains
ethanol annealing atmosphere
recrystallization of copper foils
contact-free annealing
Chemistry
QD1-999
spellingShingle abnormal grain grown
decimeter-size grains
ethanol annealing atmosphere
recrystallization of copper foils
contact-free annealing
Chemistry
QD1-999
Zhancheng Li
Yongna Zhang
Yinwu Duan
Deping Huang
Haofei Shi
The Effect of Ethanol on Abnormal Grain Growth in Copper Foils
description Single-crystal Cu not only has high electrical and thermal conductivity, but can also be used as a promising platform for the epitaxial growth of two-dimensional materials. Preparing large-area single-crystal Cu foils from polycrystalline foils has emerged as the most promising technique in terms of its simplicity and effectiveness. However, the studies on transforming polycrystalline foil into large-area single-crystal foil mainly focus on the influence of annealing temperature and strain energy on the recrystallization process of copper foil, while studies on the effect of annealing atmosphere on abnormal grain growth behavior are relatively rare. It is necessary to carry out more studies on the effect of annealing atmosphere on grain growth behavior to understand the recrystallization mechanism of metal. Here, we found that introduction of ethanol in pure argon annealing atmosphere will cause the abnormal grain growth of copper foil. Moreover, the number of abnormally grown grains can be controlled by the concentration of ethanol in the annealing atmosphere. Using this technology, the number of abnormally grown grains on the copper foil can be controlled to single one. This abnormally grown grain will grow rapidly to decimeter-size by consuming the surrounding small grains. This work provides a new perspective for the understanding of the recrystallization of metals, and a new method for the preparation of large-area single-crystal copper foils.
format article
author Zhancheng Li
Yongna Zhang
Yinwu Duan
Deping Huang
Haofei Shi
author_facet Zhancheng Li
Yongna Zhang
Yinwu Duan
Deping Huang
Haofei Shi
author_sort Zhancheng Li
title The Effect of Ethanol on Abnormal Grain Growth in Copper Foils
title_short The Effect of Ethanol on Abnormal Grain Growth in Copper Foils
title_full The Effect of Ethanol on Abnormal Grain Growth in Copper Foils
title_fullStr The Effect of Ethanol on Abnormal Grain Growth in Copper Foils
title_full_unstemmed The Effect of Ethanol on Abnormal Grain Growth in Copper Foils
title_sort effect of ethanol on abnormal grain growth in copper foils
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/57dcdc6bae454d66a18cdba9002fda23
work_keys_str_mv AT zhanchengli theeffectofethanolonabnormalgraingrowthincopperfoils
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