Peanut Shell Derived Carbon Combined with Nano Cobalt: An Effective Flame Retardant for Epoxy Resin

Biomass-derived carbon has been recognised as a green, economic and promising flame retardant (FR) for polymer matrix. In this paper, it is considered that the two-dimensional (2D) structure of carbonised peanut shells (PS) can lead to a physical barrier effect on polymers. The carbonised sample was...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Jing Liang, Wenhao Yang, Anthony Chun Yin Yuen, Hu Long, Shuilai Qiu, Ivan Miguel De Cachinho Cordeiro, Wei Wang, Timothy Bo Yuan Chen, Yuan Hu, Guan Heng Yeoh
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	peanut shell physical barrier effect carbon catalysis effect flame retardant Organic chemistry QD241-441
Acceso en línea:	https://doaj.org/article/57f46b7f150b48ada85279395913fa19
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:57f46b7f150b48ada85279395913fa19
record_format	dspace
spelling	oai:doaj.org-article:57f46b7f150b48ada85279395913fa192021-11-11T18:37:28ZPeanut Shell Derived Carbon Combined with Nano Cobalt: An Effective Flame Retardant for Epoxy Resin10.3390/molecules262166621420-3049https://doaj.org/article/57f46b7f150b48ada85279395913fa192021-11-01T00:00:00Zhttps://www.mdpi.com/1420-3049/26/21/6662https://doaj.org/toc/1420-3049Biomass-derived carbon has been recognised as a green, economic and promising flame retardant (FR) for polymer matrix. In this paper, it is considered that the two-dimensional (2D) structure of carbonised peanut shells (PS) can lead to a physical barrier effect on polymers. The carbonised sample was prepared by the three facile methods, and firstly adopted as flame retardants for epoxy resin. The results of thermal gravimetric analysis (TGA) and cone calorimeter tests indicate that the carbon combined with nano Cobalt provides the most outstanding thermal stability in the current study. With 3 wt.% addition of the FR, both peak heat release rate (pHRR) and peak smoke production rate (PSPR) decrease by 37.9% and 33.3%, correspondingly. The flame retardancy mechanisms of the FR are further explored by XPS and TG-FTIR. The effectiveness of carbonised PS can be mainly attributed to the physical barrier effect derived by PS’s 2D structure and the catalysis effect from Cobalt, which contribute to form a dense char layer.Jing LiangWenhao YangAnthony Chun Yin YuenHu LongShuilai QiuIvan Miguel De Cachinho CordeiroWei WangTimothy Bo Yuan ChenYuan HuGuan Heng YeohMDPI AGarticlepeanut shellphysical barrier effectcarboncatalysis effectflame retardantOrganic chemistryQD241-441ENMolecules, Vol 26, Iss 6662, p 6662 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	peanut shell physical barrier effect carbon catalysis effect flame retardant Organic chemistry QD241-441
spellingShingle	peanut shell physical barrier effect carbon catalysis effect flame retardant Organic chemistry QD241-441 Jing Liang Wenhao Yang Anthony Chun Yin Yuen Hu Long Shuilai Qiu Ivan Miguel De Cachinho Cordeiro Wei Wang Timothy Bo Yuan Chen Yuan Hu Guan Heng Yeoh Peanut Shell Derived Carbon Combined with Nano Cobalt: An Effective Flame Retardant for Epoxy Resin
description	Biomass-derived carbon has been recognised as a green, economic and promising flame retardant (FR) for polymer matrix. In this paper, it is considered that the two-dimensional (2D) structure of carbonised peanut shells (PS) can lead to a physical barrier effect on polymers. The carbonised sample was prepared by the three facile methods, and firstly adopted as flame retardants for epoxy resin. The results of thermal gravimetric analysis (TGA) and cone calorimeter tests indicate that the carbon combined with nano Cobalt provides the most outstanding thermal stability in the current study. With 3 wt.% addition of the FR, both peak heat release rate (pHRR) and peak smoke production rate (PSPR) decrease by 37.9% and 33.3%, correspondingly. The flame retardancy mechanisms of the FR are further explored by XPS and TG-FTIR. The effectiveness of carbonised PS can be mainly attributed to the physical barrier effect derived by PS’s 2D structure and the catalysis effect from Cobalt, which contribute to form a dense char layer.
format	article
author	Jing Liang Wenhao Yang Anthony Chun Yin Yuen Hu Long Shuilai Qiu Ivan Miguel De Cachinho Cordeiro Wei Wang Timothy Bo Yuan Chen Yuan Hu Guan Heng Yeoh
author_facet	Jing Liang Wenhao Yang Anthony Chun Yin Yuen Hu Long Shuilai Qiu Ivan Miguel De Cachinho Cordeiro Wei Wang Timothy Bo Yuan Chen Yuan Hu Guan Heng Yeoh
author_sort	Jing Liang
title	Peanut Shell Derived Carbon Combined with Nano Cobalt: An Effective Flame Retardant for Epoxy Resin
title_short	Peanut Shell Derived Carbon Combined with Nano Cobalt: An Effective Flame Retardant for Epoxy Resin
title_full	Peanut Shell Derived Carbon Combined with Nano Cobalt: An Effective Flame Retardant for Epoxy Resin
title_fullStr	Peanut Shell Derived Carbon Combined with Nano Cobalt: An Effective Flame Retardant for Epoxy Resin
title_full_unstemmed	Peanut Shell Derived Carbon Combined with Nano Cobalt: An Effective Flame Retardant for Epoxy Resin
title_sort	peanut shell derived carbon combined with nano cobalt: an effective flame retardant for epoxy resin
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/57f46b7f150b48ada85279395913fa19
work_keys_str_mv	AT jingliang peanutshellderivedcarboncombinedwithnanocobaltaneffectiveflameretardantforepoxyresin AT wenhaoyang peanutshellderivedcarboncombinedwithnanocobaltaneffectiveflameretardantforepoxyresin AT anthonychunyinyuen peanutshellderivedcarboncombinedwithnanocobaltaneffectiveflameretardantforepoxyresin AT hulong peanutshellderivedcarboncombinedwithnanocobaltaneffectiveflameretardantforepoxyresin AT shuilaiqiu peanutshellderivedcarboncombinedwithnanocobaltaneffectiveflameretardantforepoxyresin AT ivanmigueldecachinhocordeiro peanutshellderivedcarboncombinedwithnanocobaltaneffectiveflameretardantforepoxyresin AT weiwang peanutshellderivedcarboncombinedwithnanocobaltaneffectiveflameretardantforepoxyresin AT timothyboyuanchen peanutshellderivedcarboncombinedwithnanocobaltaneffectiveflameretardantforepoxyresin AT yuanhu peanutshellderivedcarboncombinedwithnanocobaltaneffectiveflameretardantforepoxyresin AT guanhengyeoh peanutshellderivedcarboncombinedwithnanocobaltaneffectiveflameretardantforepoxyresin
_version_	1718431762781044736

Peanut Shell Derived Carbon Combined with Nano Cobalt: An Effective Flame Retardant for Epoxy Resin

Ejemplares similares