Non-equilibrium metal oxides via reconversion chemistry in lithium-ion batteries

The charging of Fe and Mn oxide anodes in lithium-ion batteries are believed to form rocksalt phases via reconstructive conversion reactions. Here, the authors show that M x O y (M = Fe, Mn) transform into non-native body-centred cubic FeO and zincblende MnO via topotactic displacement-like pathways...

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Autores principales:	Xiao Hua, Phoebe K. Allan, Chen Gong, Philip A. Chater, Ella M. Schmidt, Harry S. Geddes, Alex W. Robertson, Peter G. Bruce, Andrew L. Goodwin
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/580f3f8d7a7a444bb3a1c8e85eb8051c
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spelling	oai:doaj.org-article:580f3f8d7a7a444bb3a1c8e85eb8051c2021-12-02T13:57:44ZNon-equilibrium metal oxides via reconversion chemistry in lithium-ion batteries10.1038/s41467-020-20736-62041-1723https://doaj.org/article/580f3f8d7a7a444bb3a1c8e85eb8051c2021-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-20736-6https://doaj.org/toc/2041-1723The charging of Fe and Mn oxide anodes in lithium-ion batteries are believed to form rocksalt phases via reconstructive conversion reactions. Here, the authors show that M x O y (M = Fe, Mn) transform into non-native body-centred cubic FeO and zincblende MnO via topotactic displacement-like pathways.Xiao HuaPhoebe K. AllanChen GongPhilip A. ChaterElla M. SchmidtHarry S. GeddesAlex W. RobertsonPeter G. BruceAndrew L. GoodwinNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-11 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Xiao Hua Phoebe K. Allan Chen Gong Philip A. Chater Ella M. Schmidt Harry S. Geddes Alex W. Robertson Peter G. Bruce Andrew L. Goodwin Non-equilibrium metal oxides via reconversion chemistry in lithium-ion batteries
description	The charging of Fe and Mn oxide anodes in lithium-ion batteries are believed to form rocksalt phases via reconstructive conversion reactions. Here, the authors show that M x O y (M = Fe, Mn) transform into non-native body-centred cubic FeO and zincblende MnO via topotactic displacement-like pathways.
format	article
author	Xiao Hua Phoebe K. Allan Chen Gong Philip A. Chater Ella M. Schmidt Harry S. Geddes Alex W. Robertson Peter G. Bruce Andrew L. Goodwin
author_facet	Xiao Hua Phoebe K. Allan Chen Gong Philip A. Chater Ella M. Schmidt Harry S. Geddes Alex W. Robertson Peter G. Bruce Andrew L. Goodwin
author_sort	Xiao Hua
title	Non-equilibrium metal oxides via reconversion chemistry in lithium-ion batteries
title_short	Non-equilibrium metal oxides via reconversion chemistry in lithium-ion batteries
title_full	Non-equilibrium metal oxides via reconversion chemistry in lithium-ion batteries
title_fullStr	Non-equilibrium metal oxides via reconversion chemistry in lithium-ion batteries
title_full_unstemmed	Non-equilibrium metal oxides via reconversion chemistry in lithium-ion batteries
title_sort	non-equilibrium metal oxides via reconversion chemistry in lithium-ion batteries
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/580f3f8d7a7a444bb3a1c8e85eb8051c
work_keys_str_mv	AT xiaohua nonequilibriummetaloxidesviareconversionchemistryinlithiumionbatteries AT phoebekallan nonequilibriummetaloxidesviareconversionchemistryinlithiumionbatteries AT chengong nonequilibriummetaloxidesviareconversionchemistryinlithiumionbatteries AT philipachater nonequilibriummetaloxidesviareconversionchemistryinlithiumionbatteries AT ellamschmidt nonequilibriummetaloxidesviareconversionchemistryinlithiumionbatteries AT harrysgeddes nonequilibriummetaloxidesviareconversionchemistryinlithiumionbatteries AT alexwrobertson nonequilibriummetaloxidesviareconversionchemistryinlithiumionbatteries AT petergbruce nonequilibriummetaloxidesviareconversionchemistryinlithiumionbatteries AT andrewlgoodwin nonequilibriummetaloxidesviareconversionchemistryinlithiumionbatteries
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Non-equilibrium metal oxides via reconversion chemistry in lithium-ion batteries

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