Preparation of Al-3Ga-3In-3Sn Alloy Powder by Coupling Alloying and Ball Milling and Its Application on High-Rate Hydrogen Generation at Room Temperature

High hydro-active Al-3Ga-3In-3Sn alloys were prepared by coupling alloying and mechanical milling methods. NiCl<sub>2</sub> was added to the alloy during ball milling as the catalyst. XRD, SEM, and XAFS were used for the characterization of the hydro-active alloy. The hydrogen generation...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Shuo Wang, Lixiang Zhu, Lichen Zhang, Xiaodong Zhang, Xiaoxuan Wang, Mengchen Ge, Xiaodong Li, Meishuai Zou
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	alloying and ball milling Al alloy powder XAFS hydrogen generation Mining engineering. Metallurgy TN1-997
Acceso en línea:	https://doaj.org/article/5837c267b22f446fb2e038a731dea4d7
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:5837c267b22f446fb2e038a731dea4d7
record_format	dspace
spelling	oai:doaj.org-article:5837c267b22f446fb2e038a731dea4d72021-11-25T18:21:21ZPreparation of Al-3Ga-3In-3Sn Alloy Powder by Coupling Alloying and Ball Milling and Its Application on High-Rate Hydrogen Generation at Room Temperature10.3390/met111117042075-4701https://doaj.org/article/5837c267b22f446fb2e038a731dea4d72021-10-01T00:00:00Zhttps://www.mdpi.com/2075-4701/11/11/1704https://doaj.org/toc/2075-4701High hydro-active Al-3Ga-3In-3Sn alloys were prepared by coupling alloying and mechanical milling methods. NiCl<sub>2</sub> was added to the alloy during ball milling as the catalyst. XRD, SEM, and XAFS were used for the characterization of the hydro-active alloy. The hydrogen generation properties were systematically investigated in tap water at room temperature. The results show that the hydrogen generation rate is 11.02 L∙min<sup>−1</sup>∙g<sup>−1,</sup> and the conversion yield is 90.25% for the Al-3Ga-3In-3Sn-2NiCl<sub>2</sub> composite with a ball milling time of 2 h at room temperature in tap water. The hydrolysis reaction contains the expansion of the Al-based phase into a nano-sized layer and the further hydrolysis reaction of the layered Al phase with water. The activation mechanism was also investigated, and the activation of Al was attributed to the Al-Ni galvanic with the existing Cl<sup>−</sup>, which leads to a faster hydrolysis reaction rate for ball-milled powder with NiCl<sub>2</sub>.Shuo WangLixiang ZhuLichen ZhangXiaodong ZhangXiaoxuan WangMengchen GeXiaodong LiMeishuai ZouMDPI AGarticlealloying and ball millingAl alloy powderXAFShydrogen generationMining engineering. MetallurgyTN1-997ENMetals, Vol 11, Iss 1704, p 1704 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	alloying and ball milling Al alloy powder XAFS hydrogen generation Mining engineering. Metallurgy TN1-997
spellingShingle	alloying and ball milling Al alloy powder XAFS hydrogen generation Mining engineering. Metallurgy TN1-997 Shuo Wang Lixiang Zhu Lichen Zhang Xiaodong Zhang Xiaoxuan Wang Mengchen Ge Xiaodong Li Meishuai Zou Preparation of Al-3Ga-3In-3Sn Alloy Powder by Coupling Alloying and Ball Milling and Its Application on High-Rate Hydrogen Generation at Room Temperature
description	High hydro-active Al-3Ga-3In-3Sn alloys were prepared by coupling alloying and mechanical milling methods. NiCl<sub>2</sub> was added to the alloy during ball milling as the catalyst. XRD, SEM, and XAFS were used for the characterization of the hydro-active alloy. The hydrogen generation properties were systematically investigated in tap water at room temperature. The results show that the hydrogen generation rate is 11.02 L∙min<sup>−1</sup>∙g<sup>−1,</sup> and the conversion yield is 90.25% for the Al-3Ga-3In-3Sn-2NiCl<sub>2</sub> composite with a ball milling time of 2 h at room temperature in tap water. The hydrolysis reaction contains the expansion of the Al-based phase into a nano-sized layer and the further hydrolysis reaction of the layered Al phase with water. The activation mechanism was also investigated, and the activation of Al was attributed to the Al-Ni galvanic with the existing Cl<sup>−</sup>, which leads to a faster hydrolysis reaction rate for ball-milled powder with NiCl<sub>2</sub>.
format	article
author	Shuo Wang Lixiang Zhu Lichen Zhang Xiaodong Zhang Xiaoxuan Wang Mengchen Ge Xiaodong Li Meishuai Zou
author_facet	Shuo Wang Lixiang Zhu Lichen Zhang Xiaodong Zhang Xiaoxuan Wang Mengchen Ge Xiaodong Li Meishuai Zou
author_sort	Shuo Wang
title	Preparation of Al-3Ga-3In-3Sn Alloy Powder by Coupling Alloying and Ball Milling and Its Application on High-Rate Hydrogen Generation at Room Temperature
title_short	Preparation of Al-3Ga-3In-3Sn Alloy Powder by Coupling Alloying and Ball Milling and Its Application on High-Rate Hydrogen Generation at Room Temperature
title_full	Preparation of Al-3Ga-3In-3Sn Alloy Powder by Coupling Alloying and Ball Milling and Its Application on High-Rate Hydrogen Generation at Room Temperature
title_fullStr	Preparation of Al-3Ga-3In-3Sn Alloy Powder by Coupling Alloying and Ball Milling and Its Application on High-Rate Hydrogen Generation at Room Temperature
title_full_unstemmed	Preparation of Al-3Ga-3In-3Sn Alloy Powder by Coupling Alloying and Ball Milling and Its Application on High-Rate Hydrogen Generation at Room Temperature
title_sort	preparation of al-3ga-3in-3sn alloy powder by coupling alloying and ball milling and its application on high-rate hydrogen generation at room temperature
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/5837c267b22f446fb2e038a731dea4d7
work_keys_str_mv	AT shuowang preparationofal3ga3in3snalloypowderbycouplingalloyingandballmillinganditsapplicationonhighratehydrogengenerationatroomtemperature AT lixiangzhu preparationofal3ga3in3snalloypowderbycouplingalloyingandballmillinganditsapplicationonhighratehydrogengenerationatroomtemperature AT lichenzhang preparationofal3ga3in3snalloypowderbycouplingalloyingandballmillinganditsapplicationonhighratehydrogengenerationatroomtemperature AT xiaodongzhang preparationofal3ga3in3snalloypowderbycouplingalloyingandballmillinganditsapplicationonhighratehydrogengenerationatroomtemperature AT xiaoxuanwang preparationofal3ga3in3snalloypowderbycouplingalloyingandballmillinganditsapplicationonhighratehydrogengenerationatroomtemperature AT mengchenge preparationofal3ga3in3snalloypowderbycouplingalloyingandballmillinganditsapplicationonhighratehydrogengenerationatroomtemperature AT xiaodongli preparationofal3ga3in3snalloypowderbycouplingalloyingandballmillinganditsapplicationonhighratehydrogengenerationatroomtemperature AT meishuaizou preparationofal3ga3in3snalloypowderbycouplingalloyingandballmillinganditsapplicationonhighratehydrogengenerationatroomtemperature
_version_	1718411257900433408

Preparation of Al-3Ga-3In-3Sn Alloy Powder by Coupling Alloying and Ball Milling and Its Application on High-Rate Hydrogen Generation at Room Temperature

Ejemplares similares