Isolation of diborenes and their 90°-twisted diradical congeners

Attempts to bend and twist multiple bonds in order to alter their reactivities have thus far been met with only modest success. Here, Braunschweig and colleagues isolate double-bond-containing boron-based species and their 90°-twisted diradical analogs, thanks to their stabilization with Lewis basic...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Julian Böhnke, Theresa Dellermann, Mehmet Ali Celik, Ivo Krummenacher, Rian D. Dewhurst, Serhiy Demeshko, William C. Ewing, Kai Hammond, Merlin Heß, Eckhard Bill, Eileen Welz, Merle I. S. Röhr, Roland Mitrić, Bernd Engels, Franc Meyer, Holger Braunschweig
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
Materias:
Q
Acceso en línea:https://doaj.org/article/58a8fc7cef4c4b33ac6d1678b54a97f7
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
Descripción
Sumario:Attempts to bend and twist multiple bonds in order to alter their reactivities have thus far been met with only modest success. Here, Braunschweig and colleagues isolate double-bond-containing boron-based species and their 90°-twisted diradical analogs, thanks to their stabilization with Lewis basic units.