Isolation of diborenes and their 90°-twisted diradical congeners

Isolation of diborenes and their 90°-twisted diradical congeners

Attempts to bend and twist multiple bonds in order to alter their reactivities have thus far been met with only modest success. Here, Braunschweig and colleagues isolate double-bond-containing boron-based species and their 90°-twisted diradical analogs, thanks to their stabilization with Lewis basic...

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Autores principales: Julian Böhnke, Theresa Dellermann, Mehmet Ali Celik, Ivo Krummenacher, Rian D. Dewhurst, Serhiy Demeshko, William C. Ewing, Kai Hammond, Merlin Heß, Eckhard Bill, Eileen Welz, Merle I. S. Röhr, Roland Mitrić, Bernd Engels, Franc Meyer, Holger Braunschweig
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Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/58a8fc7cef4c4b33ac6d1678b54a97f7
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spelling oai:doaj.org-article:58a8fc7cef4c4b33ac6d1678b54a97f72021-12-02T17:32:00ZIsolation of diborenes and their 90°-twisted diradical congeners10.1038/s41467-018-02998-32041-1723https://doaj.org/article/58a8fc7cef4c4b33ac6d1678b54a97f72018-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-02998-3https://doaj.org/toc/2041-1723Attempts to bend and twist multiple bonds in order to alter their reactivities have thus far been met with only modest success. Here, Braunschweig and colleagues isolate double-bond-containing boron-based species and their 90°-twisted diradical analogs, thanks to their stabilization with Lewis basic units.Julian BöhnkeTheresa DellermannMehmet Ali CelikIvo KrummenacherRian D. DewhurstSerhiy DemeshkoWilliam C. EwingKai HammondMerlin HeßEckhard BillEileen WelzMerle I. S. RöhrRoland MitrićBernd EngelsFranc MeyerHolger BraunschweigNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-7 (2018)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Julian Böhnke
Theresa Dellermann
Mehmet Ali Celik
Ivo Krummenacher
Rian D. Dewhurst
Serhiy Demeshko
William C. Ewing
Kai Hammond
Merlin Heß
Eckhard Bill
Eileen Welz
Merle I. S. Röhr
Roland Mitrić
Bernd Engels
Franc Meyer
Holger Braunschweig
Isolation of diborenes and their 90°-twisted diradical congeners
description Attempts to bend and twist multiple bonds in order to alter their reactivities have thus far been met with only modest success. Here, Braunschweig and colleagues isolate double-bond-containing boron-based species and their 90°-twisted diradical analogs, thanks to their stabilization with Lewis basic units.
format article
author Julian Böhnke
Theresa Dellermann
Mehmet Ali Celik
Ivo Krummenacher
Rian D. Dewhurst
Serhiy Demeshko
William C. Ewing
Kai Hammond
Merlin Heß
Eckhard Bill
Eileen Welz
Merle I. S. Röhr
Roland Mitrić
Bernd Engels
Franc Meyer
Holger Braunschweig
author_facet Julian Böhnke
Theresa Dellermann
Mehmet Ali Celik
Ivo Krummenacher
Rian D. Dewhurst
Serhiy Demeshko
William C. Ewing
Kai Hammond
Merlin Heß
Eckhard Bill
Eileen Welz
Merle I. S. Röhr
Roland Mitrić
Bernd Engels
Franc Meyer
Holger Braunschweig
author_sort Julian Böhnke
title Isolation of diborenes and their 90°-twisted diradical congeners
title_short Isolation of diborenes and their 90°-twisted diradical congeners
title_full Isolation of diborenes and their 90°-twisted diradical congeners
title_fullStr Isolation of diborenes and their 90°-twisted diradical congeners
title_full_unstemmed Isolation of diborenes and their 90°-twisted diradical congeners
title_sort isolation of diborenes and their 90°-twisted diradical congeners
publisher Nature Portfolio
publishDate 2018
url https://doaj.org/article/58a8fc7cef4c4b33ac6d1678b54a97f7
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