Isolation of diborenes and their 90°-twisted diradical congeners

Isolation of diborenes and their 90°-twisted diradical congeners

Attempts to bend and twist multiple bonds in order to alter their reactivities have thus far been met with only modest success. Here, Braunschweig and colleagues isolate double-bond-containing boron-based species and their 90°-twisted diradical analogs, thanks to their stabilization with Lewis basic...

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Auteurs principaux: Julian Böhnke, Theresa Dellermann, Mehmet Ali Celik, Ivo Krummenacher, Rian D. Dewhurst, Serhiy Demeshko, William C. Ewing, Kai Hammond, Merlin Heß, Eckhard Bill, Eileen Welz, Merle I. S. Röhr, Roland Mitrić, Bernd Engels, Franc Meyer, Holger Braunschweig
Format: article
Langue:EN
Publié: Nature Portfolio 2018
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Science
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Accès en ligne:https://doaj.org/article/58a8fc7cef4c4b33ac6d1678b54a97f7
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https://doaj.org/article/58a8fc7cef4c4b33ac6d1678b54a97f7

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