A curved host and second guest cooperatively inhibit the dynamic motion of corannulene

A curved host and second guest cooperatively inhibit the dynamic motion of corannulene

The preparation of artificial host–guest systems that display dynamic adaptation during guest binding is challenging. Here the authors report a chiral self-assembled tetrahedral cage featuring curved walls that reconfigures stereochemically to fit fullerene guests, regulates corannulene inversion, a...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Yang Yang, Tanya K. Ronson, Zifei Lu, Jieyu Zheng, Nicolas Vanthuyne, Alexandre Martinez, Jonathan R. Nitschke
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
Materias:
Science
Q
Acceso en línea:https://doaj.org/article/58ba96d18b564c0ea748396ceb96ec3a
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
id oai:doaj.org-article:58ba96d18b564c0ea748396ceb96ec3a
record_format dspace
spelling oai:doaj.org-article:58ba96d18b564c0ea748396ceb96ec3a2021-12-02T14:34:05ZA curved host and second guest cooperatively inhibit the dynamic motion of corannulene10.1038/s41467-021-24344-w2041-1723https://doaj.org/article/58ba96d18b564c0ea748396ceb96ec3a2021-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-24344-whttps://doaj.org/toc/2041-1723The preparation of artificial host–guest systems that display dynamic adaptation during guest binding is challenging. Here the authors report a chiral self-assembled tetrahedral cage featuring curved walls that reconfigures stereochemically to fit fullerene guests, regulates corannulene inversion, and enables the determination of co-guest enantiomeric excess by NMR spectroscopy.Yang YangTanya K. RonsonZifei LuJieyu ZhengNicolas VanthuyneAlexandre MartinezJonathan R. NitschkeNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-8 (2021)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Yang Yang
Tanya K. Ronson
Zifei Lu
Jieyu Zheng
Nicolas Vanthuyne
Alexandre Martinez
Jonathan R. Nitschke
A curved host and second guest cooperatively inhibit the dynamic motion of corannulene
description The preparation of artificial host–guest systems that display dynamic adaptation during guest binding is challenging. Here the authors report a chiral self-assembled tetrahedral cage featuring curved walls that reconfigures stereochemically to fit fullerene guests, regulates corannulene inversion, and enables the determination of co-guest enantiomeric excess by NMR spectroscopy.
format article
author Yang Yang
Tanya K. Ronson
Zifei Lu
Jieyu Zheng
Nicolas Vanthuyne
Alexandre Martinez
Jonathan R. Nitschke
author_facet Yang Yang
Tanya K. Ronson
Zifei Lu
Jieyu Zheng
Nicolas Vanthuyne
Alexandre Martinez
Jonathan R. Nitschke
author_sort Yang Yang
title A curved host and second guest cooperatively inhibit the dynamic motion of corannulene
title_short A curved host and second guest cooperatively inhibit the dynamic motion of corannulene
title_full A curved host and second guest cooperatively inhibit the dynamic motion of corannulene
title_fullStr A curved host and second guest cooperatively inhibit the dynamic motion of corannulene
title_full_unstemmed A curved host and second guest cooperatively inhibit the dynamic motion of corannulene
title_sort curved host and second guest cooperatively inhibit the dynamic motion of corannulene
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/58ba96d18b564c0ea748396ceb96ec3a
work_keys_str_mv AT yangyang acurvedhostandsecondguestcooperativelyinhibitthedynamicmotionofcorannulene
AT tanyakronson acurvedhostandsecondguestcooperativelyinhibitthedynamicmotionofcorannulene
AT zifeilu acurvedhostandsecondguestcooperativelyinhibitthedynamicmotionofcorannulene
AT jieyuzheng acurvedhostandsecondguestcooperativelyinhibitthedynamicmotionofcorannulene
AT nicolasvanthuyne acurvedhostandsecondguestcooperativelyinhibitthedynamicmotionofcorannulene
AT alexandremartinez acurvedhostandsecondguestcooperativelyinhibitthedynamicmotionofcorannulene
AT jonathanrnitschke acurvedhostandsecondguestcooperativelyinhibitthedynamicmotionofcorannulene
AT yangyang curvedhostandsecondguestcooperativelyinhibitthedynamicmotionofcorannulene
AT tanyakronson curvedhostandsecondguestcooperativelyinhibitthedynamicmotionofcorannulene
AT zifeilu curvedhostandsecondguestcooperativelyinhibitthedynamicmotionofcorannulene
AT jieyuzheng curvedhostandsecondguestcooperativelyinhibitthedynamicmotionofcorannulene
AT nicolasvanthuyne curvedhostandsecondguestcooperativelyinhibitthedynamicmotionofcorannulene
AT alexandremartinez curvedhostandsecondguestcooperativelyinhibitthedynamicmotionofcorannulene
AT jonathanrnitschke curvedhostandsecondguestcooperativelyinhibitthedynamicmotionofcorannulene
_version_ 1718391129686147072

Ejemplares similares