Electronic processes in polyazomethine thin films

This paper is focused on thin films of various aromatic polyazomethines, undoped and doped with iodine and FeCl3, which are expected to be promising materials for organic electronics. Polyazomethine thin films have been fabricated by thermal vacuum evaporation (TVE) and chemical vapor deposition...

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Autores principales: Weszka, J., Cisowski, J.
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Lenguaje:EN
Publicado: D.Ghitu Institute of Electronic Engineering and Nanotechnologies 2009
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Acceso en línea:https://doaj.org/article/58f95b9d563c49a0ba1a632567567888
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spelling oai:doaj.org-article:58f95b9d563c49a0ba1a6325675678882021-11-21T12:05:27ZElectronic processes in polyazomethine thin films2537-63651810-648Xhttps://doaj.org/article/58f95b9d563c49a0ba1a6325675678882009-05-01T00:00:00Zhttps://mjps.nanotech.md/archive/2009/article/4116https://doaj.org/toc/1810-648Xhttps://doaj.org/toc/2537-6365This paper is focused on thin films of various aromatic polyazomethines, undoped and doped with iodine and FeCl3, which are expected to be promising materials for organic electronics. Polyazomethine thin films have been fabricated by thermal vacuum evaporation (TVE) and chemical vapor deposition (CVD) via the polycondensation process. The prepared films, with a typical thickness of the order of 100 nm and smooth surfaces, appear to be considerably amorphous. The measured absorption and photoluminescence (PL) spectra are discussed in terms of the electronic structure of the materials of interest. In particular, the lowenergy spectra, related to transitions between the delocalized states, reveal the presence of the vibronic progression. Additionally, the influence of the polymer chain structure and its conformation on the electronic structure of polyazomethine thin films is considered. Finally, the relationship between the electronic processes occurring in polyazomethine thin films and their potential applications is discussed. Weszka, J.Cisowski, J.D.Ghitu Institute of Electronic Engineering and NanotechnologiesarticlePhysicsQC1-999ElectronicsTK7800-8360ENMoldavian Journal of the Physical Sciences, Vol 8, Iss 2, Pp 221-230 (2009)
institution DOAJ
collection DOAJ
language EN
topic Physics
QC1-999
Electronics
TK7800-8360
spellingShingle Physics
QC1-999
Electronics
TK7800-8360
Weszka, J.
Cisowski, J.
Electronic processes in polyazomethine thin films
description This paper is focused on thin films of various aromatic polyazomethines, undoped and doped with iodine and FeCl3, which are expected to be promising materials for organic electronics. Polyazomethine thin films have been fabricated by thermal vacuum evaporation (TVE) and chemical vapor deposition (CVD) via the polycondensation process. The prepared films, with a typical thickness of the order of 100 nm and smooth surfaces, appear to be considerably amorphous. The measured absorption and photoluminescence (PL) spectra are discussed in terms of the electronic structure of the materials of interest. In particular, the lowenergy spectra, related to transitions between the delocalized states, reveal the presence of the vibronic progression. Additionally, the influence of the polymer chain structure and its conformation on the electronic structure of polyazomethine thin films is considered. Finally, the relationship between the electronic processes occurring in polyazomethine thin films and their potential applications is discussed.
format article
author Weszka, J.
Cisowski, J.
author_facet Weszka, J.
Cisowski, J.
author_sort Weszka, J.
title Electronic processes in polyazomethine thin films
title_short Electronic processes in polyazomethine thin films
title_full Electronic processes in polyazomethine thin films
title_fullStr Electronic processes in polyazomethine thin films
title_full_unstemmed Electronic processes in polyazomethine thin films
title_sort electronic processes in polyazomethine thin films
publisher D.Ghitu Institute of Electronic Engineering and Nanotechnologies
publishDate 2009
url https://doaj.org/article/58f95b9d563c49a0ba1a632567567888
work_keys_str_mv AT weszkaj electronicprocessesinpolyazomethinethinfilms
AT cisowskij electronicprocessesinpolyazomethinethinfilms
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