Electronic processes in polyazomethine thin films
This paper is focused on thin films of various aromatic polyazomethines, undoped and doped with iodine and FeCl3, which are expected to be promising materials for organic electronics. Polyazomethine thin films have been fabricated by thermal vacuum evaporation (TVE) and chemical vapor deposition...
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D.Ghitu Institute of Electronic Engineering and Nanotechnologies
2009
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oai:doaj.org-article:58f95b9d563c49a0ba1a6325675678882021-11-21T12:05:27ZElectronic processes in polyazomethine thin films2537-63651810-648Xhttps://doaj.org/article/58f95b9d563c49a0ba1a6325675678882009-05-01T00:00:00Zhttps://mjps.nanotech.md/archive/2009/article/4116https://doaj.org/toc/1810-648Xhttps://doaj.org/toc/2537-6365This paper is focused on thin films of various aromatic polyazomethines, undoped and doped with iodine and FeCl3, which are expected to be promising materials for organic electronics. Polyazomethine thin films have been fabricated by thermal vacuum evaporation (TVE) and chemical vapor deposition (CVD) via the polycondensation process. The prepared films, with a typical thickness of the order of 100 nm and smooth surfaces, appear to be considerably amorphous. The measured absorption and photoluminescence (PL) spectra are discussed in terms of the electronic structure of the materials of interest. In particular, the lowenergy spectra, related to transitions between the delocalized states, reveal the presence of the vibronic progression. Additionally, the influence of the polymer chain structure and its conformation on the electronic structure of polyazomethine thin films is considered. Finally, the relationship between the electronic processes occurring in polyazomethine thin films and their potential applications is discussed. Weszka, J.Cisowski, J.D.Ghitu Institute of Electronic Engineering and NanotechnologiesarticlePhysicsQC1-999ElectronicsTK7800-8360ENMoldavian Journal of the Physical Sciences, Vol 8, Iss 2, Pp 221-230 (2009) |
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Physics QC1-999 Electronics TK7800-8360 |
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Physics QC1-999 Electronics TK7800-8360 Weszka, J. Cisowski, J. Electronic processes in polyazomethine thin films |
description |
This paper is focused on thin films of various aromatic polyazomethines, undoped and
doped with iodine and FeCl3, which are expected to be promising materials for organic electronics. Polyazomethine thin films have been fabricated by thermal vacuum evaporation
(TVE) and chemical vapor deposition (CVD) via the polycondensation process. The prepared
films, with a typical thickness of the order of 100 nm and smooth surfaces, appear to be considerably amorphous. The measured absorption and photoluminescence (PL) spectra are discussed in terms of the electronic structure of the materials of interest. In particular, the lowenergy spectra, related to transitions between the delocalized states, reveal the presence of the
vibronic progression. Additionally, the influence of the polymer chain structure and its conformation on the electronic structure of polyazomethine thin films is considered. Finally, the
relationship between the electronic processes occurring in polyazomethine thin films and their
potential applications is discussed.
|
format |
article |
author |
Weszka, J. Cisowski, J. |
author_facet |
Weszka, J. Cisowski, J. |
author_sort |
Weszka, J. |
title |
Electronic processes in polyazomethine thin films |
title_short |
Electronic processes in polyazomethine thin films |
title_full |
Electronic processes in polyazomethine thin films |
title_fullStr |
Electronic processes in polyazomethine thin films |
title_full_unstemmed |
Electronic processes in polyazomethine thin films |
title_sort |
electronic processes in polyazomethine thin films |
publisher |
D.Ghitu Institute of Electronic Engineering and Nanotechnologies |
publishDate |
2009 |
url |
https://doaj.org/article/58f95b9d563c49a0ba1a632567567888 |
work_keys_str_mv |
AT weszkaj electronicprocessesinpolyazomethinethinfilms AT cisowskij electronicprocessesinpolyazomethinethinfilms |
_version_ |
1718419246554284032 |