Adsorption and activation of molecular oxygen over atomic copper(I/II) site on ceria

Precise control over the energy of atomic metal sites is key to unlocking novel reaction pathways. Here, the authors achieve selective oxygen activation by the isolated copper site on ceria, due to its reduced 3d orbital energy via cerium induced electron withdrawing effect.

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Autores principales:	Liqun Kang, Bolun Wang, Qiming Bing, Michal Zalibera, Robert Büchel, Ruoyu Xu, Qiming Wang, Yiyun Liu, Diego Gianolio, Chiu C. Tang, Emma K. Gibson, Mohsen Danaie, Christopher Allen, Ke Wu, Sushila Marlow, Ling-dong Sun, Qian He, Shaoliang Guan, Anton Savitsky, Juan J. Velasco-Vélez, June Callison, Christopher W. M. Kay, Sotiris E. Pratsinis, Wolfgang Lubitz, Jing-yao Liu, Feng Ryan Wang
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/593891f1285948d782bf697a7f1d964b
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spelling	oai:doaj.org-article:593891f1285948d782bf697a7f1d964b2021-12-02T15:08:24ZAdsorption and activation of molecular oxygen over atomic copper(I/II) site on ceria10.1038/s41467-020-17852-82041-1723https://doaj.org/article/593891f1285948d782bf697a7f1d964b2020-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-17852-8https://doaj.org/toc/2041-1723Precise control over the energy of atomic metal sites is key to unlocking novel reaction pathways. Here, the authors achieve selective oxygen activation by the isolated copper site on ceria, due to its reduced 3d orbital energy via cerium induced electron withdrawing effect.Liqun KangBolun WangQiming BingMichal ZaliberaRobert BüchelRuoyu XuQiming WangYiyun LiuDiego GianolioChiu C. TangEmma K. GibsonMohsen DanaieChristopher AllenKe WuSushila MarlowLing-dong SunQian HeShaoliang GuanAnton SavitskyJuan J. Velasco-VélezJune CallisonChristopher W. M. KaySotiris E. PratsinisWolfgang LubitzJing-yao LiuFeng Ryan WangNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-11 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Liqun Kang Bolun Wang Qiming Bing Michal Zalibera Robert Büchel Ruoyu Xu Qiming Wang Yiyun Liu Diego Gianolio Chiu C. Tang Emma K. Gibson Mohsen Danaie Christopher Allen Ke Wu Sushila Marlow Ling-dong Sun Qian He Shaoliang Guan Anton Savitsky Juan J. Velasco-Vélez June Callison Christopher W. M. Kay Sotiris E. Pratsinis Wolfgang Lubitz Jing-yao Liu Feng Ryan Wang Adsorption and activation of molecular oxygen over atomic copper(I/II) site on ceria
description	Precise control over the energy of atomic metal sites is key to unlocking novel reaction pathways. Here, the authors achieve selective oxygen activation by the isolated copper site on ceria, due to its reduced 3d orbital energy via cerium induced electron withdrawing effect.
format	article
author	Liqun Kang Bolun Wang Qiming Bing Michal Zalibera Robert Büchel Ruoyu Xu Qiming Wang Yiyun Liu Diego Gianolio Chiu C. Tang Emma K. Gibson Mohsen Danaie Christopher Allen Ke Wu Sushila Marlow Ling-dong Sun Qian He Shaoliang Guan Anton Savitsky Juan J. Velasco-Vélez June Callison Christopher W. M. Kay Sotiris E. Pratsinis Wolfgang Lubitz Jing-yao Liu Feng Ryan Wang
author_facet	Liqun Kang Bolun Wang Qiming Bing Michal Zalibera Robert Büchel Ruoyu Xu Qiming Wang Yiyun Liu Diego Gianolio Chiu C. Tang Emma K. Gibson Mohsen Danaie Christopher Allen Ke Wu Sushila Marlow Ling-dong Sun Qian He Shaoliang Guan Anton Savitsky Juan J. Velasco-Vélez June Callison Christopher W. M. Kay Sotiris E. Pratsinis Wolfgang Lubitz Jing-yao Liu Feng Ryan Wang
author_sort	Liqun Kang
title	Adsorption and activation of molecular oxygen over atomic copper(I/II) site on ceria
title_short	Adsorption and activation of molecular oxygen over atomic copper(I/II) site on ceria
title_full	Adsorption and activation of molecular oxygen over atomic copper(I/II) site on ceria
title_fullStr	Adsorption and activation of molecular oxygen over atomic copper(I/II) site on ceria
title_full_unstemmed	Adsorption and activation of molecular oxygen over atomic copper(I/II) site on ceria
title_sort	adsorption and activation of molecular oxygen over atomic copper(i/ii) site on ceria
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/593891f1285948d782bf697a7f1d964b
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Adsorption and activation of molecular oxygen over atomic copper(I/II) site on ceria

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