SnO nanoparticles on graphene oxide as an effective catalyst for synthesis of lubricating ester oils
In this paper, nanosized SnO was deposited on graphene oxide (GO) by adopting hydrothermal technique to fabricate a new composite material SnO@GO, which was characterized by TEM, BET, XPS, XRD and FE-SEM. The SnO@GO composite exhibits excellent catalytic performance for esterifying fatty acids and t...
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2022
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oai:doaj.org-article:5954d697568a4e53bf6c30b57bb04d262021-11-26T04:24:57ZSnO nanoparticles on graphene oxide as an effective catalyst for synthesis of lubricating ester oils1873-390510.1016/j.catcom.2021.106370https://doaj.org/article/5954d697568a4e53bf6c30b57bb04d262022-02-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S1566736721000935https://doaj.org/toc/1873-3905In this paper, nanosized SnO was deposited on graphene oxide (GO) by adopting hydrothermal technique to fabricate a new composite material SnO@GO, which was characterized by TEM, BET, XPS, XRD and FE-SEM. The SnO@GO composite exhibits excellent catalytic performance for esterifying fatty acids and trimethylolpropane at stoichiometric ratio. The yield of resulting polyol esters could reach 99%. Additionally, the SnO@GO composition can be recycled for 6 cycles without obvious deactivation. The outstanding catalytic performance was attributed by the active Lewis acid of SnO and the increase of specific surface area with the loading of SnO onto GO.Huaigang SuQin ZhaoYanan WangQilong ZhaoCheng JangYongfang NiuWenjing LouYanxing QiElsevierarticleSnO nanoparticlesGraphene oxideEsterificationPolyol esterLubricating ester oilsChemistryQD1-999ENCatalysis Communications, Vol 162, Iss , Pp 106370- (2022) |
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DOAJ |
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SnO nanoparticles Graphene oxide Esterification Polyol ester Lubricating ester oils Chemistry QD1-999 |
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SnO nanoparticles Graphene oxide Esterification Polyol ester Lubricating ester oils Chemistry QD1-999 Huaigang Su Qin Zhao Yanan Wang Qilong Zhao Cheng Jang Yongfang Niu Wenjing Lou Yanxing Qi SnO nanoparticles on graphene oxide as an effective catalyst for synthesis of lubricating ester oils |
description |
In this paper, nanosized SnO was deposited on graphene oxide (GO) by adopting hydrothermal technique to fabricate a new composite material SnO@GO, which was characterized by TEM, BET, XPS, XRD and FE-SEM. The SnO@GO composite exhibits excellent catalytic performance for esterifying fatty acids and trimethylolpropane at stoichiometric ratio. The yield of resulting polyol esters could reach 99%. Additionally, the SnO@GO composition can be recycled for 6 cycles without obvious deactivation. The outstanding catalytic performance was attributed by the active Lewis acid of SnO and the increase of specific surface area with the loading of SnO onto GO. |
format |
article |
author |
Huaigang Su Qin Zhao Yanan Wang Qilong Zhao Cheng Jang Yongfang Niu Wenjing Lou Yanxing Qi |
author_facet |
Huaigang Su Qin Zhao Yanan Wang Qilong Zhao Cheng Jang Yongfang Niu Wenjing Lou Yanxing Qi |
author_sort |
Huaigang Su |
title |
SnO nanoparticles on graphene oxide as an effective catalyst for synthesis of lubricating ester oils |
title_short |
SnO nanoparticles on graphene oxide as an effective catalyst for synthesis of lubricating ester oils |
title_full |
SnO nanoparticles on graphene oxide as an effective catalyst for synthesis of lubricating ester oils |
title_fullStr |
SnO nanoparticles on graphene oxide as an effective catalyst for synthesis of lubricating ester oils |
title_full_unstemmed |
SnO nanoparticles on graphene oxide as an effective catalyst for synthesis of lubricating ester oils |
title_sort |
sno nanoparticles on graphene oxide as an effective catalyst for synthesis of lubricating ester oils |
publisher |
Elsevier |
publishDate |
2022 |
url |
https://doaj.org/article/5954d697568a4e53bf6c30b57bb04d26 |
work_keys_str_mv |
AT huaigangsu snonanoparticlesongrapheneoxideasaneffectivecatalystforsynthesisoflubricatingesteroils AT qinzhao snonanoparticlesongrapheneoxideasaneffectivecatalystforsynthesisoflubricatingesteroils AT yananwang snonanoparticlesongrapheneoxideasaneffectivecatalystforsynthesisoflubricatingesteroils AT qilongzhao snonanoparticlesongrapheneoxideasaneffectivecatalystforsynthesisoflubricatingesteroils AT chengjang snonanoparticlesongrapheneoxideasaneffectivecatalystforsynthesisoflubricatingesteroils AT yongfangniu snonanoparticlesongrapheneoxideasaneffectivecatalystforsynthesisoflubricatingesteroils AT wenjinglou snonanoparticlesongrapheneoxideasaneffectivecatalystforsynthesisoflubricatingesteroils AT yanxingqi snonanoparticlesongrapheneoxideasaneffectivecatalystforsynthesisoflubricatingesteroils |
_version_ |
1718409901959544832 |