Dehydrogenative reagent-free annulation of alkenes with diols for the synthesis of saturated O-heterocycles

Dehydrogenative annulation is a valuable approach to heterocycles, however, stoichiometric oxidants are often required. Here, the authors describe the electrochemical dehydrogenative annulation of diols and alkenes to generate dioxanes and dioxepanes under metal- and oxidant-free conditions.

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Autores principales:	Chen-Yan Cai, Hai-Chao Xu
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/598214fe7f9d48c5aee9b007e9d820b5
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spelling	oai:doaj.org-article:598214fe7f9d48c5aee9b007e9d820b52021-12-02T17:32:03ZDehydrogenative reagent-free annulation of alkenes with diols for the synthesis of saturated O-heterocycles10.1038/s41467-018-06020-82041-1723https://doaj.org/article/598214fe7f9d48c5aee9b007e9d820b52018-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-06020-8https://doaj.org/toc/2041-1723Dehydrogenative annulation is a valuable approach to heterocycles, however, stoichiometric oxidants are often required. Here, the authors describe the electrochemical dehydrogenative annulation of diols and alkenes to generate dioxanes and dioxepanes under metal- and oxidant-free conditions.Chen-Yan CaiHai-Chao XuNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-7 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Chen-Yan Cai Hai-Chao Xu Dehydrogenative reagent-free annulation of alkenes with diols for the synthesis of saturated O-heterocycles
description	Dehydrogenative annulation is a valuable approach to heterocycles, however, stoichiometric oxidants are often required. Here, the authors describe the electrochemical dehydrogenative annulation of diols and alkenes to generate dioxanes and dioxepanes under metal- and oxidant-free conditions.
format	article
author	Chen-Yan Cai Hai-Chao Xu
author_facet	Chen-Yan Cai Hai-Chao Xu
author_sort	Chen-Yan Cai
title	Dehydrogenative reagent-free annulation of alkenes with diols for the synthesis of saturated O-heterocycles
title_short	Dehydrogenative reagent-free annulation of alkenes with diols for the synthesis of saturated O-heterocycles
title_full	Dehydrogenative reagent-free annulation of alkenes with diols for the synthesis of saturated O-heterocycles
title_fullStr	Dehydrogenative reagent-free annulation of alkenes with diols for the synthesis of saturated O-heterocycles
title_full_unstemmed	Dehydrogenative reagent-free annulation of alkenes with diols for the synthesis of saturated O-heterocycles
title_sort	dehydrogenative reagent-free annulation of alkenes with diols for the synthesis of saturated o-heterocycles
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/598214fe7f9d48c5aee9b007e9d820b5
work_keys_str_mv	AT chenyancai dehydrogenativereagentfreeannulationofalkeneswithdiolsforthesynthesisofsaturatedoheterocycles AT haichaoxu dehydrogenativereagentfreeannulationofalkeneswithdiolsforthesynthesisofsaturatedoheterocycles
_version_	1718380429784907776

Dehydrogenative reagent-free annulation of alkenes with diols for the synthesis of saturated O-heterocycles

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