Dehydrogenative reagent-free annulation of alkenes with diols for the synthesis of saturated O-heterocycles
Dehydrogenative annulation is a valuable approach to heterocycles, however, stoichiometric oxidants are often required. Here, the authors describe the electrochemical dehydrogenative annulation of diols and alkenes to generate dioxanes and dioxepanes under metal- and oxidant-free conditions.
Guardado en:
Autores principales: | Chen-Yan Cai, Hai-Chao Xu |
---|---|
Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2018
|
Materias: | |
Acceso en línea: | https://doaj.org/article/598214fe7f9d48c5aee9b007e9d820b5 |
Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
Ejemplares similares
-
Enantioselective [3+3] atroposelective annulation catalyzed by N-heterocyclic carbenes
por: Changgui Zhao, et al.
Publicado: (2018) -
Anti-selective [3+2] (Hetero)annulation of non-conjugated alkenes via directed nucleopalladation
por: Hui-Qi Ni, et al.
Publicado: (2020) -
Practical and stereoselective electrocatalytic 1,2-diamination of alkenes
por: Chen-Yan Cai, et al.
Publicado: (2019) -
Copper-catalyzed dehydrogenative γ-C(sp3)-H amination of saturated ketones for synthesis of polysubstituted anilines
por: Rong Hu, et al.
Publicado: (2019) -
Visible light induced alkene aminopyridylation using N-aminopyridinium salts as bifunctional reagents
por: Yonghoon Moon, et al.
Publicado: (2019)