Singlet oxygen-mediated selective C–H bond hydroperoxidation of ethereal hydrocarbons

Singlet oxygen is known to react with carbon–carbon double bonds. Here, the authors show the unusual functionalization of α-ethereal C–H bonds mediated by singlet oxygen under mild conditions to afford lactones and hydroperoxide products.

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Autores principales:	Arunachalam Sagadevan, Kuo Chu Hwang, Ming-Der Su
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/598d9d12b2834f1db37eb43519a033a0
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spelling	oai:doaj.org-article:598d9d12b2834f1db37eb43519a033a02021-12-02T14:40:47ZSinglet oxygen-mediated selective C–H bond hydroperoxidation of ethereal hydrocarbons10.1038/s41467-017-01906-52041-1723https://doaj.org/article/598d9d12b2834f1db37eb43519a033a02017-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-01906-5https://doaj.org/toc/2041-1723Singlet oxygen is known to react with carbon–carbon double bonds. Here, the authors show the unusual functionalization of α-ethereal C–H bonds mediated by singlet oxygen under mild conditions to afford lactones and hydroperoxide products.Arunachalam SagadevanKuo Chu HwangMing-Der SuNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-8 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Arunachalam Sagadevan Kuo Chu Hwang Ming-Der Su Singlet oxygen-mediated selective C–H bond hydroperoxidation of ethereal hydrocarbons
description	Singlet oxygen is known to react with carbon–carbon double bonds. Here, the authors show the unusual functionalization of α-ethereal C–H bonds mediated by singlet oxygen under mild conditions to afford lactones and hydroperoxide products.
format	article
author	Arunachalam Sagadevan Kuo Chu Hwang Ming-Der Su
author_facet	Arunachalam Sagadevan Kuo Chu Hwang Ming-Der Su
author_sort	Arunachalam Sagadevan
title	Singlet oxygen-mediated selective C–H bond hydroperoxidation of ethereal hydrocarbons
title_short	Singlet oxygen-mediated selective C–H bond hydroperoxidation of ethereal hydrocarbons
title_full	Singlet oxygen-mediated selective C–H bond hydroperoxidation of ethereal hydrocarbons
title_fullStr	Singlet oxygen-mediated selective C–H bond hydroperoxidation of ethereal hydrocarbons
title_full_unstemmed	Singlet oxygen-mediated selective C–H bond hydroperoxidation of ethereal hydrocarbons
title_sort	singlet oxygen-mediated selective c–h bond hydroperoxidation of ethereal hydrocarbons
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/598d9d12b2834f1db37eb43519a033a0
work_keys_str_mv	AT arunachalamsagadevan singletoxygenmediatedselectivechbondhydroperoxidationofetherealhydrocarbons AT kuochuhwang singletoxygenmediatedselectivechbondhydroperoxidationofetherealhydrocarbons AT mingdersu singletoxygenmediatedselectivechbondhydroperoxidationofetherealhydrocarbons
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Singlet oxygen-mediated selective C–H bond hydroperoxidation of ethereal hydrocarbons

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