X-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound
The previously reported Mn0–MgII bonded heterobimetallic compound [L†Mn–Mg(MesNacnac)] (L† = −N(Ar†)(SiPri3), Ar† = C6H2{C(H)Ph2}2Pri-2,6,4; MesNacnac = [(MesNCMe)2CH]−; Mes = mesityl) forms an adduct complex, [L†Mn–Mg(THF)(MesNacnac)], when dissolved in THF. Adventitious water is shown to be reduce...
Guardado en:
Autores principales: | , , |
---|---|
Formato: | article |
Lenguaje: | EN |
Publicado: |
De Gruyter
2021
|
Materias: | |
Acceso en línea: | https://doaj.org/article/59f18db3070a4860bb256032950db45d |
Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
id |
oai:doaj.org-article:59f18db3070a4860bb256032950db45d |
---|---|
record_format |
dspace |
spelling |
oai:doaj.org-article:59f18db3070a4860bb256032950db45d2021-12-05T14:10:56ZX-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound0792-12412191-021910.1515/mgmc-2021-0027https://doaj.org/article/59f18db3070a4860bb256032950db45d2021-10-01T00:00:00Zhttps://doi.org/10.1515/mgmc-2021-0027https://doaj.org/toc/0792-1241https://doaj.org/toc/2191-0219The previously reported Mn0–MgII bonded heterobimetallic compound [L†Mn–Mg(MesNacnac)] (L† = −N(Ar†)(SiPri3), Ar† = C6H2{C(H)Ph2}2Pri-2,6,4; MesNacnac = [(MesNCMe)2CH]−; Mes = mesityl) forms an adduct complex, [L†Mn–Mg(THF)(MesNacnac)], when dissolved in THF. Adventitious water is shown to be reduced by [L†Mn–Mg(MesNacnac)] to give the hydroxide bridged heterobimetallic, [L†Mn(μ-OH)2Mg(MesNacnac)]. The Mn0–MgII bonded heterobimtallic reductively disproportionates CO2, affording the carbonate bridged species, [{L†Mn(μ-CO3)Mg(THF) (MesNacnac)}2], in the presence of THF. The three new compounds have been crystallographically characterized.Hicks JamieJuckel MartinJones CameronDe Gruyterarticleheterobimetallicmagnesiummanganesemetal-metal bondcarbonateChemistryQD1-999ENMain Group Metal Chemistry, Vol 44, Iss 1, Pp 250-255 (2021) |
institution |
DOAJ |
collection |
DOAJ |
language |
EN |
topic |
heterobimetallic magnesium manganese metal-metal bond carbonate Chemistry QD1-999 |
spellingShingle |
heterobimetallic magnesium manganese metal-metal bond carbonate Chemistry QD1-999 Hicks Jamie Juckel Martin Jones Cameron X-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound |
description |
The previously reported Mn0–MgII bonded heterobimetallic compound [L†Mn–Mg(MesNacnac)] (L† = −N(Ar†)(SiPri3), Ar† = C6H2{C(H)Ph2}2Pri-2,6,4; MesNacnac = [(MesNCMe)2CH]−; Mes = mesityl) forms an adduct complex, [L†Mn–Mg(THF)(MesNacnac)], when dissolved in THF. Adventitious water is shown to be reduced by [L†Mn–Mg(MesNacnac)] to give the hydroxide bridged heterobimetallic, [L†Mn(μ-OH)2Mg(MesNacnac)]. The Mn0–MgII bonded heterobimtallic reductively disproportionates CO2, affording the carbonate bridged species, [{L†Mn(μ-CO3)Mg(THF) (MesNacnac)}2], in the presence of THF. The three new compounds have been crystallographically characterized. |
format |
article |
author |
Hicks Jamie Juckel Martin Jones Cameron |
author_facet |
Hicks Jamie Juckel Martin Jones Cameron |
author_sort |
Hicks Jamie |
title |
X-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound |
title_short |
X-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound |
title_full |
X-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound |
title_fullStr |
X-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound |
title_full_unstemmed |
X-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound |
title_sort |
x-ray crystal structures of carbonate and hydroxide bridged mnii/mgii heterobimetallic complexes formed by reduction of co2 or h2o by a mn0–mgii bonded compound |
publisher |
De Gruyter |
publishDate |
2021 |
url |
https://doaj.org/article/59f18db3070a4860bb256032950db45d |
work_keys_str_mv |
AT hicksjamie xraycrystalstructuresofcarbonateandhydroxidebridgedmniimgiiheterobimetalliccomplexesformedbyreductionofco2orh2obyamn0mgiibondedcompound AT juckelmartin xraycrystalstructuresofcarbonateandhydroxidebridgedmniimgiiheterobimetalliccomplexesformedbyreductionofco2orh2obyamn0mgiibondedcompound AT jonescameron xraycrystalstructuresofcarbonateandhydroxidebridgedmniimgiiheterobimetalliccomplexesformedbyreductionofco2orh2obyamn0mgiibondedcompound |
_version_ |
1718371537213456384 |