X-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound

The previously reported Mn0–MgII bonded heterobimetallic compound [L†Mn–Mg(MesNacnac)] (L† = −N(Ar†)(SiPri3), Ar† = C6H2{C(H)Ph2}2Pri-2,6,4; MesNacnac = [(MesNCMe)2CH]−; Mes = mesityl) forms an adduct complex, [L†Mn–Mg(THF)(MesNacnac)], when dissolved in THF. Adventitious water is shown to be reduce...

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Autores principales:	Hicks Jamie, Juckel Martin, Jones Cameron
Formato:	article
Lenguaje:	EN
Publicado:	De Gruyter 2021
Materias:	heterobimetallic magnesium manganese metal-metal bond carbonate Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/59f18db3070a4860bb256032950db45d
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spelling	oai:doaj.org-article:59f18db3070a4860bb256032950db45d2021-12-05T14:10:56ZX-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound0792-12412191-021910.1515/mgmc-2021-0027https://doaj.org/article/59f18db3070a4860bb256032950db45d2021-10-01T00:00:00Zhttps://doi.org/10.1515/mgmc-2021-0027https://doaj.org/toc/0792-1241https://doaj.org/toc/2191-0219The previously reported Mn0–MgII bonded heterobimetallic compound [L†Mn–Mg(MesNacnac)] (L† = −N(Ar†)(SiPri3), Ar† = C6H2{C(H)Ph2}2Pri-2,6,4; MesNacnac = [(MesNCMe)2CH]−; Mes = mesityl) forms an adduct complex, [L†Mn–Mg(THF)(MesNacnac)], when dissolved in THF. Adventitious water is shown to be reduced by [L†Mn–Mg(MesNacnac)] to give the hydroxide bridged heterobimetallic, [L†Mn(μ-OH)2Mg(MesNacnac)]. The Mn0–MgII bonded heterobimtallic reductively disproportionates CO2, affording the carbonate bridged species, [{L†Mn(μ-CO3)Mg(THF) (MesNacnac)}2], in the presence of THF. The three new compounds have been crystallographically characterized.Hicks JamieJuckel MartinJones CameronDe Gruyterarticleheterobimetallicmagnesiummanganesemetal-metal bondcarbonateChemistryQD1-999ENMain Group Metal Chemistry, Vol 44, Iss 1, Pp 250-255 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	heterobimetallic magnesium manganese metal-metal bond carbonate Chemistry QD1-999
spellingShingle	heterobimetallic magnesium manganese metal-metal bond carbonate Chemistry QD1-999 Hicks Jamie Juckel Martin Jones Cameron X-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound
description	The previously reported Mn0–MgII bonded heterobimetallic compound [L†Mn–Mg(MesNacnac)] (L† = −N(Ar†)(SiPri3), Ar† = C6H2{C(H)Ph2}2Pri-2,6,4; MesNacnac = [(MesNCMe)2CH]−; Mes = mesityl) forms an adduct complex, [L†Mn–Mg(THF)(MesNacnac)], when dissolved in THF. Adventitious water is shown to be reduced by [L†Mn–Mg(MesNacnac)] to give the hydroxide bridged heterobimetallic, [L†Mn(μ-OH)2Mg(MesNacnac)]. The Mn0–MgII bonded heterobimtallic reductively disproportionates CO2, affording the carbonate bridged species, [{L†Mn(μ-CO3)Mg(THF) (MesNacnac)}2], in the presence of THF. The three new compounds have been crystallographically characterized.
format	article
author	Hicks Jamie Juckel Martin Jones Cameron
author_facet	Hicks Jamie Juckel Martin Jones Cameron
author_sort	Hicks Jamie
title	X-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound
title_short	X-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound
title_full	X-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound
title_fullStr	X-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound
title_full_unstemmed	X-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound
title_sort	x-ray crystal structures of carbonate and hydroxide bridged mnii/mgii heterobimetallic complexes formed by reduction of co2 or h2o by a mn0–mgii bonded compound
publisher	De Gruyter
publishDate	2021
url	https://doaj.org/article/59f18db3070a4860bb256032950db45d
work_keys_str_mv	AT hicksjamie xraycrystalstructuresofcarbonateandhydroxidebridgedmniimgiiheterobimetalliccomplexesformedbyreductionofco2orh2obyamn0mgiibondedcompound AT juckelmartin xraycrystalstructuresofcarbonateandhydroxidebridgedmniimgiiheterobimetalliccomplexesformedbyreductionofco2orh2obyamn0mgiibondedcompound AT jonescameron xraycrystalstructuresofcarbonateandhydroxidebridgedmniimgiiheterobimetalliccomplexesformedbyreductionofco2orh2obyamn0mgiibondedcompound
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X-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound

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