X-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound

The previously reported Mn0–MgII bonded heterobimetallic compound [L†Mn–Mg(MesNacnac)] (L† = −N(Ar†)(SiPri3), Ar† = C6H2{C(H)Ph2}2Pri-2,6,4; MesNacnac = [(MesNCMe)2CH]−; Mes = mesityl) forms an adduct complex, [L†Mn–Mg(THF)(MesNacnac)], when dissolved in THF. Adventitious water is shown to be reduce...

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Autores principales: Hicks Jamie, Juckel Martin, Jones Cameron
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Lenguaje:EN
Publicado: De Gruyter 2021
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Acceso en línea:https://doaj.org/article/59f18db3070a4860bb256032950db45d
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spelling oai:doaj.org-article:59f18db3070a4860bb256032950db45d2021-12-05T14:10:56ZX-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound0792-12412191-021910.1515/mgmc-2021-0027https://doaj.org/article/59f18db3070a4860bb256032950db45d2021-10-01T00:00:00Zhttps://doi.org/10.1515/mgmc-2021-0027https://doaj.org/toc/0792-1241https://doaj.org/toc/2191-0219The previously reported Mn0–MgII bonded heterobimetallic compound [L†Mn–Mg(MesNacnac)] (L† = −N(Ar†)(SiPri3), Ar† = C6H2{C(H)Ph2}2Pri-2,6,4; MesNacnac = [(MesNCMe)2CH]−; Mes = mesityl) forms an adduct complex, [L†Mn–Mg(THF)(MesNacnac)], when dissolved in THF. Adventitious water is shown to be reduced by [L†Mn–Mg(MesNacnac)] to give the hydroxide bridged heterobimetallic, [L†Mn(μ-OH)2Mg(MesNacnac)]. The Mn0–MgII bonded heterobimtallic reductively disproportionates CO2, affording the carbonate bridged species, [{L†Mn(μ-CO3)Mg(THF) (MesNacnac)}2], in the presence of THF. The three new compounds have been crystallographically characterized.Hicks JamieJuckel MartinJones CameronDe Gruyterarticleheterobimetallicmagnesiummanganesemetal-metal bondcarbonateChemistryQD1-999ENMain Group Metal Chemistry, Vol 44, Iss 1, Pp 250-255 (2021)
institution DOAJ
collection DOAJ
language EN
topic heterobimetallic
magnesium
manganese
metal-metal bond
carbonate
Chemistry
QD1-999
spellingShingle heterobimetallic
magnesium
manganese
metal-metal bond
carbonate
Chemistry
QD1-999
Hicks Jamie
Juckel Martin
Jones Cameron
X-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound
description The previously reported Mn0–MgII bonded heterobimetallic compound [L†Mn–Mg(MesNacnac)] (L† = −N(Ar†)(SiPri3), Ar† = C6H2{C(H)Ph2}2Pri-2,6,4; MesNacnac = [(MesNCMe)2CH]−; Mes = mesityl) forms an adduct complex, [L†Mn–Mg(THF)(MesNacnac)], when dissolved in THF. Adventitious water is shown to be reduced by [L†Mn–Mg(MesNacnac)] to give the hydroxide bridged heterobimetallic, [L†Mn(μ-OH)2Mg(MesNacnac)]. The Mn0–MgII bonded heterobimtallic reductively disproportionates CO2, affording the carbonate bridged species, [{L†Mn(μ-CO3)Mg(THF) (MesNacnac)}2], in the presence of THF. The three new compounds have been crystallographically characterized.
format article
author Hicks Jamie
Juckel Martin
Jones Cameron
author_facet Hicks Jamie
Juckel Martin
Jones Cameron
author_sort Hicks Jamie
title X-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound
title_short X-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound
title_full X-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound
title_fullStr X-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound
title_full_unstemmed X-ray crystal structures of carbonate and hydroxide bridged MnII/MgII heterobimetallic complexes formed by reduction of CO2 or H2O by a Mn0–MgII bonded compound
title_sort x-ray crystal structures of carbonate and hydroxide bridged mnii/mgii heterobimetallic complexes formed by reduction of co2 or h2o by a mn0–mgii bonded compound
publisher De Gruyter
publishDate 2021
url https://doaj.org/article/59f18db3070a4860bb256032950db45d
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AT juckelmartin xraycrystalstructuresofcarbonateandhydroxidebridgedmniimgiiheterobimetalliccomplexesformedbyreductionofco2orh2obyamn0mgiibondedcompound
AT jonescameron xraycrystalstructuresofcarbonateandhydroxidebridgedmniimgiiheterobimetalliccomplexesformedbyreductionofco2orh2obyamn0mgiibondedcompound
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