A merged copper(I/II) cluster isolated from Glaser coupling

Copper-oxygen species in organometallic complexes and enzymes are involved in many oxidation reactions. Here, the authors synthesize a macrocycle-protected mixed valence Cu(I/II) cluster with an unusually strong oxidation capacity and apply it to hydrogen atom transfer reactions with inert hydrocarb...

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Autores principales:	Siqi Zhang, Liang Zhao
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/5a1cbc0c6af747ab9fb6285b65e40712
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spelling	oai:doaj.org-article:5a1cbc0c6af747ab9fb6285b65e407122021-12-02T17:31:21ZA merged copper(I/II) cluster isolated from Glaser coupling10.1038/s41467-019-12889-w2041-1723https://doaj.org/article/5a1cbc0c6af747ab9fb6285b65e407122019-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-12889-whttps://doaj.org/toc/2041-1723Copper-oxygen species in organometallic complexes and enzymes are involved in many oxidation reactions. Here, the authors synthesize a macrocycle-protected mixed valence Cu(I/II) cluster with an unusually strong oxidation capacity and apply it to hydrogen atom transfer reactions with inert hydrocarbons.Siqi ZhangLiang ZhaoNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-10 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Siqi Zhang Liang Zhao A merged copper(I/II) cluster isolated from Glaser coupling
description	Copper-oxygen species in organometallic complexes and enzymes are involved in many oxidation reactions. Here, the authors synthesize a macrocycle-protected mixed valence Cu(I/II) cluster with an unusually strong oxidation capacity and apply it to hydrogen atom transfer reactions with inert hydrocarbons.
format	article
author	Siqi Zhang Liang Zhao
author_facet	Siqi Zhang Liang Zhao
author_sort	Siqi Zhang
title	A merged copper(I/II) cluster isolated from Glaser coupling
title_short	A merged copper(I/II) cluster isolated from Glaser coupling
title_full	A merged copper(I/II) cluster isolated from Glaser coupling
title_fullStr	A merged copper(I/II) cluster isolated from Glaser coupling
title_full_unstemmed	A merged copper(I/II) cluster isolated from Glaser coupling
title_sort	merged copper(i/ii) cluster isolated from glaser coupling
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/5a1cbc0c6af747ab9fb6285b65e40712
work_keys_str_mv	AT siqizhang amergedcopperiiiclusterisolatedfromglasercoupling AT liangzhao amergedcopperiiiclusterisolatedfromglasercoupling AT siqizhang mergedcopperiiiclusterisolatedfromglasercoupling AT liangzhao mergedcopperiiiclusterisolatedfromglasercoupling
_version_	1718380613934776320

A merged copper(I/II) cluster isolated from Glaser coupling

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