Bipolar Resistive Switching Behavior of PVP-GQD/HfOx/ITO/Graphene Hybrid Flexible Resistive Random Access Memory

We have investigated highly flexible memristive devices using reduced graphene oxide (RGO) nanosheet nanocomposites with an embedded GQD Layer. Resistive switching behavior of poly (4-vinylphenol):graphene quantum dot (PVP:GQD) composite and HfOx hybrid bilayer was explored for developing flexible r...

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Autores principales: Jin Mo Kim, Sung Won Hwang
Formato: article
Lenguaje:EN
Publicado: MDPI AG 2021
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Acceso en línea:https://doaj.org/article/5a2e12cbae9941f78629836c6eb01799
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spelling oai:doaj.org-article:5a2e12cbae9941f78629836c6eb017992021-11-25T18:27:01ZBipolar Resistive Switching Behavior of PVP-GQD/HfOx/ITO/Graphene Hybrid Flexible Resistive Random Access Memory10.3390/molecules262267581420-3049https://doaj.org/article/5a2e12cbae9941f78629836c6eb017992021-11-01T00:00:00Zhttps://www.mdpi.com/1420-3049/26/22/6758https://doaj.org/toc/1420-3049We have investigated highly flexible memristive devices using reduced graphene oxide (RGO) nanosheet nanocomposites with an embedded GQD Layer. Resistive switching behavior of poly (4-vinylphenol):graphene quantum dot (PVP:GQD) composite and HfOx hybrid bilayer was explored for developing flexible resistive random access memory (RRAM) devices. A composite active layer was designed based on graphene quantum dots, which is a low-dimensional structure, and a heterogeneous active layer of graphene quantum dots was applied to the interfacial defect structure to overcome the limitations. Increasing to 0.3–0.6 wt % PVP-GQD, V<sub>f</sub> changed from 2.27–2.74 V. When negative deflection is applied to the lower electrode, electrons travel through the HfOx/ITO interface. In addition, as the PVP-GQD concentration increased, the depth of the interfacial defect decreased, and confirmed the repetition of appropriate electrical properties through Al and HfOx/ITO. The low interfacial defects help electrophoresis of Al<sup>+</sup> ions to the PVP GQD layer and the HfOx thin film. A local electric field increase occurred, resulting in the breakage of the conductive filament in the defect.Jin Mo KimSung Won HwangMDPI AGarticleHfOxGQDRRAMmemristive devicesresistive switchingOrganic chemistryQD241-441ENMolecules, Vol 26, Iss 6758, p 6758 (2021)
institution DOAJ
collection DOAJ
language EN
topic HfOx
GQD
RRAM
memristive devices
resistive switching
Organic chemistry
QD241-441
spellingShingle HfOx
GQD
RRAM
memristive devices
resistive switching
Organic chemistry
QD241-441
Jin Mo Kim
Sung Won Hwang
Bipolar Resistive Switching Behavior of PVP-GQD/HfOx/ITO/Graphene Hybrid Flexible Resistive Random Access Memory
description We have investigated highly flexible memristive devices using reduced graphene oxide (RGO) nanosheet nanocomposites with an embedded GQD Layer. Resistive switching behavior of poly (4-vinylphenol):graphene quantum dot (PVP:GQD) composite and HfOx hybrid bilayer was explored for developing flexible resistive random access memory (RRAM) devices. A composite active layer was designed based on graphene quantum dots, which is a low-dimensional structure, and a heterogeneous active layer of graphene quantum dots was applied to the interfacial defect structure to overcome the limitations. Increasing to 0.3–0.6 wt % PVP-GQD, V<sub>f</sub> changed from 2.27–2.74 V. When negative deflection is applied to the lower electrode, electrons travel through the HfOx/ITO interface. In addition, as the PVP-GQD concentration increased, the depth of the interfacial defect decreased, and confirmed the repetition of appropriate electrical properties through Al and HfOx/ITO. The low interfacial defects help electrophoresis of Al<sup>+</sup> ions to the PVP GQD layer and the HfOx thin film. A local electric field increase occurred, resulting in the breakage of the conductive filament in the defect.
format article
author Jin Mo Kim
Sung Won Hwang
author_facet Jin Mo Kim
Sung Won Hwang
author_sort Jin Mo Kim
title Bipolar Resistive Switching Behavior of PVP-GQD/HfOx/ITO/Graphene Hybrid Flexible Resistive Random Access Memory
title_short Bipolar Resistive Switching Behavior of PVP-GQD/HfOx/ITO/Graphene Hybrid Flexible Resistive Random Access Memory
title_full Bipolar Resistive Switching Behavior of PVP-GQD/HfOx/ITO/Graphene Hybrid Flexible Resistive Random Access Memory
title_fullStr Bipolar Resistive Switching Behavior of PVP-GQD/HfOx/ITO/Graphene Hybrid Flexible Resistive Random Access Memory
title_full_unstemmed Bipolar Resistive Switching Behavior of PVP-GQD/HfOx/ITO/Graphene Hybrid Flexible Resistive Random Access Memory
title_sort bipolar resistive switching behavior of pvp-gqd/hfox/ito/graphene hybrid flexible resistive random access memory
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/5a2e12cbae9941f78629836c6eb01799
work_keys_str_mv AT jinmokim bipolarresistiveswitchingbehaviorofpvpgqdhfoxitographenehybridflexibleresistiverandomaccessmemory
AT sungwonhwang bipolarresistiveswitchingbehaviorofpvpgqdhfoxitographenehybridflexibleresistiverandomaccessmemory
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